Method and device for discharging a hydrogen storage system in parabolic trough receivers
The present disclosure describes a method for discharging a hydrogen storage system, which is found in the annular space of a receiver tube, in particular for solar collectors, wherein the annular space is formed between an outer-lying tubular jacket and an inner-lying absorber tube of the receiver tube, and the outer-lying tubular jacket is connected via a wall to the absorber tube in a gas-tight manner. The method is hereby characterized in that an opening penetrating the tubular jacket or the wall is produced, free hydrogen in the annular space is pumped out through the opening, and the opening is subsequently sealed. The disclosure further describes a device for implementing the method.
1. A method for discharging a hydrogen storage system, wherein the hydrogen storage system is in the annular space of a receiver tube, wherein the annular space is defined at least by an outer-lying tubular jacket and an inner-lying absorber tube of the receiver tube, and wherein the outer-lying tubular jacket is connected by a wall to the absorber tube, the method comprising the steps of:
producing an opening penetrating through the tubular jacket or the wall;
pumping free hydrogen in the annular space out through the opening; and
subsequently sealing the opening.
2. The method according to claim 1 , wherein the opening is produced via laser drilling.
3. The method according to claim 1 , wherein the opening is sealed by via laser welding.
4. The method according to claim 1 , wherein the opening is produced via laser drilling with a laser beam diameter d L 1 , and the opening is sealed via laser welding with a laser beam diameter d L 2 , wherein the following applies: d L 2 >d L 1 .
5. The method according to claim 1 , wherein the opening is sealed with a closure material.
6. The method according to claim 5 , further comprising the step of applying the closure material to a site of the opening prior to the producing step.
7. The method according to claim 5 , wherein the closure materials comprises a material with hydrogen permeability.
8. The method according to claim 5 , wherein the closure material is selected from the group consisting of palladium, a palladium alloy, pure iron, and niobium.
9. The method according to claim 1 , further comprising the step of, prior to the producing step, arranging a process chamber at the tubular jacket and/or the wall in a gas-tight manner over a site of the opening for pumping out the hydrogen.
10. The method according to claim 1 , wherein the hydrogen storage system contains getter material.
11. The method according to claim 1 , wherein the hydrogen storage system is thermally discharged.
12. The method according to claim 11 , further comprising the step of heating the receiver tube prior to or during the pumping step.
13. The method according to claim 9 , wherein the free hydrogen enters the process chamber during the pumping step, and is bound by an external getter material, and wherein the getter material is in a tank coupled to the process chamber in a gas-tight manner.
14. The method according to claim 13 , wherein the external getter material is discharged after reaching a specific degree of loading.
15. The method according to claim 13 , wherein the external getter material is cyclically loaded and discharged during the pumping step.
16. A device for discharging a hydrogen storage system, wherein the hydrogen storage system is in the annular space of a receiver tube, wherein the annular space is defined at least by an outer-lying tubular jacket and an inner-lying absorber tube of the receiver tube, and wherein the outer-lying tubular jacket is connected with a wall to the absorber tube, the device comprising:
a process chamber;
a laser driller for producing an opening through the tubular jacket or the wall;
a pump for pumping out hydrogen from the annular space; and
a sealer for sealing the opening.
17. The device according to claim 16 , wherein the process chamber has at least one outlet opening for evacuating and/or pumping out the hydrogen from the process chamber and at least one through-opening for the laser driller and/or the sealer through the tubular jacket or the wall.
18. The device according to claim 16 , wherein sealer is a laser system.
19. The device according to claim 16 , further comprising a heater for inducing thermal discharge of the hydrogen storage system.
20. The device according to claim 19 , wherein the heater is on the outside of the receiver tube.
21. The device according to claim 16 , further wherein the pump is a mechanical and/or chemical pump.
22. The device according to claim 21 , wherein the chemical pump is a getter pump.