Ammonia slip catalyst
Provided is an ammonia slip catalyst article having supported palladium in a top or upstream layer for oxidation of carbon monoxide and/or hydrocarbons, an SCR catalyst either in the top layer or in a separate lower or downstream layer, and an ammonia oxidation catalyst in a bottom layer. Also provided are methods for treating an exhaust gas using the catalyst article, wherein the treatment involves reducing the concentrations of ammonia and optionally carbon monoxide and/or hydrocarbons in the exhaust gas.
1. A system for treating exhaust gas comprising:
a. an exhaust gas manifold;
b. a sub-system for introducing a nitrogenous-based reductant into the exhaust gas;
c. an SCR catalyst; and
d. a substrate having a first catalyst layer disposed on and/or within the substrate and a second catalyst layer coated over the first catalyst layer; wherein the first catalyst layer comprises a first oxidation catalyst, wherein the first oxidation catalyst comprises a supported noble metal, and the second catalyst layer contains a mixture of (i) a second oxidation catalyst consisting of supported palladium and (ii) a catalyst for selectively reducing NO x and/or storing NH 3 , wherein the catalyst for selectively reducing NO x and/or storing NH 3 is a Fe and/or Cu loaded zeolite; and wherein the first and second oxidation catalysts are different formulations;
wherein components (a)-(d) are in serial fluid communication and are, respectively, in consecutive order from upstream to downstream; and wherein the system is free of oxidation catalysts between the substrate and the exhaust gas manifold.
2. The system of claim 1 , wherein the second catalyst layer is essentially free of Ag, Au, Pt, Rh, Ru, Ir, and Os.
3. The system of claim 1 , wherein the first oxidation catalyst is Pt supported on metal oxide particles or a mixture of Pt and Pd supported on metal oxide particles.
4. The system of claim 1 , wherein the substrate is a flow-through honeycomb having a wall porosity of about 50-65%.
5. The system of claim 4 , wherein a majority of the first catalyst layer is disposed within the substrate walls and a majority of the second catalyst layer is disposed on the surface of the substrate walls.
6. The system of claim 1 , wherein the substrate further comprises a third catalyst layer disposed over the second catalyst layer, wherein the third catalyst layer comprises a third oxidation catalyst consisting of supported Pd.
7. The system of claim 1 , wherein the substrate further comprises a third catalyst layer disposed upstream of the first and second catalyst layers, wherein the third catalyst layer comprises a third oxidation catalyst consisting of supported Pd.
8. A system for treating exhaust gas comprising:
a. a first oxidation catalyst for producing an NO/NO 2 ratio of about 4:1 to about 1:3;
b. a sub-system for introducing a nitrogenous-based reductant into the exhaust gas;
c. an SCR catalyst;
d. an injector for introducing fuel into the exhaust gas;
e. a flow-through monolith substrate having a first catalyst layer disposed on and/or within the substrate and a second catalyst layer coated over at least a portion of the first catalyst layer, wherein the second catalyst layer contains a mixture of (i) a second oxidation catalyst consisting of palladium on a support and (ii) a catalyst for selectively reducing NO x and/or storing NH 3 , wherein the catalyst for selectively reducing NO x and/or storing NH 3 is a Fe and/or Cu loaded zeolite; and the first catalyst layer comprises a third oxidation catalyst, wherein the third oxidation catalyst comprises a supported noble metal; wherein the substrate is in fluid communication with the exhaust gas manifold; and
f. a diesel particulate filter;
wherein components (a)-(e) are, respectively, in consecutive order from upstream to downstream.
9. The system of claim 8 , wherein the second catalyst layer is essentially free of Ag, Au, Pt, Rh, Ru, Ir, and Os.
10. The system of claim 9 , wherein a majority of the first catalyst layer is disposed within the substrate walls and a majority of the second catalyst layer is disposed on the surface of the substrate walls.
11. The system of claim 8 , wherein the second oxidation catalyst is Pt supported on metal oxide particles or a mixture of Pt and Pd supported on metal oxide particles.
12. The system of claim 8 , wherein the substrate is a flow-through honeycomb having a wall porosity of about 50-65%.
13. The system of claim 8 , wherein the substrate further comprises a third catalyst layer disposed over the second catalyst layer, and the third catalyst layer comprises a fourth oxidation catalyst consisting of supported Pd.
14. The system of claim 8 , wherein the substrate further comprises a third catalyst layer disposed upstream of the first and second catalyst layers, and the third catalyst layer comprises a fourth oxidation catalyst consisting of supported Pd.