Packaging for adhesive compositions

1. A package system suitable for sterilizing cyanoacrylate compositions, wherein the package system comprises:

a container comprising

a chamber containing a cyanoacrylate monomer, wherein the chamber is defined by an opening and sidewalls, wherein the container comprises a material comprising a first cyclic olefin copolymer;

a multilayer foil seal sealing the opening of the container, the multilayer foil seal comprising

an inner-most layer consisting of

a second cyclic olefin copolymer consisting of a first unsaturated cyclic monomer and a first unsaturated linear monomer,

wherein the first unsaturated cyclic monomer is selected from the group consisting of norbornene, and

wherein the first unsaturated linear monomer is selected from the group consisting of ethylene, propylene, and tetracyclododecene,

an outer layer, and

at least one middle layer comprising aluminum; and

a secondary package housing the container;

wherein the package system is sterilized by radiation, and the cyanoacrylate monomer contained in the package system does not cure upon radiation exposure and for at least 24 months of shelf storage thereafter.

2. The package system of claim 1 wherein the first cyclic olefin copolymer is a copolymer of a second unsaturated cyclic monomer and at least one second unsaturated linear monomer.

3. The package system of claim 2 wherein the at least one second unsaturated linear monomer is an alpha-olefin having from 1 to 20 carbon atoms.

4. The package system of claim 3 wherein the second unsaturated linear monomeris an alpha-olefin having from 1 to 12 carbon atoms.

5. The package system of claim 2 wherein the first cyclic olefin copolymer is selected from the group consisting of norbornene-ethylene copolymer and norbornene-propylene copolymer.

6. The package system of claim 1 wherein the second cyclic olefin copolymer is selected from the group consisting of norbornene-ethylene copolymer and norbornene-propylene copolymer.

7. The package system of claim 1 , wherein the package system is produced by a process comprising the following steps:

(a) inserting a stabilized cyanoacrylate monomer composition into the chamber of the container;

(b) sealing the opening of the chamber with the multilayer foil seal, thereby containing the composition within the chamber;

(c) sterilizing the container containing the composition by irradiation;

(d) surrounding the sterilized container with the secondary package, wherein the secondary package comprises a front wrapper and a back wrapper and sealing the front wrapper and back wrapper together to form the secondary package; and,

(e) sterilizing the secondary package containing the container containing the composition by chemical sterilization.

8. The package system of claim 7 , wherein the chemical sterilization of step (e) comprises ethylene oxide sterilization.