IP Library Granted Patent US 9,964,868
Granted Patent B2
US 9,964,868 · App. 15/429,558 · Granted May 8, 2018

Electrophotographic photoreceptor, electrophotographic photoreceptor cartridge, and image forming apparatus

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Quick Facts
Patent No.
US 9,964,868
App. No.
15/429,558
Granted
May 8, 2018
Kind
B2
Abstract

The invention relates to a multilayer type electrophotographic photoreceptor comprising: a conductive support; and, on the conductive support, a charge generation layer containing a hydroxygallium phthalocyanine pigment and a charge transport layer, wherein the content of α-chloronaphthalene in hydroxygallium phthalocyanine pigment in the charge generation layer is in a range of 0 ng/cm 2 to 0.1 ng/cm 2 , the charge transport layer contains a non-halogen organic solvent having a boiling point of 140° C. or more, and the content of the non-halogen organic solvent having a boiling point of 140° C. or more is in a range of 0.1 μg/cm 2 to 5 μg/cm 2 .

Claims (18)

1. A multilayer type electrophotographic photoreceptor comprising:

a conductive support; and

on the conductive support, a charge generation layer and a charge transport layer, the charge generation layer comprising a hydroxygallium phthalocyanine pigment,

wherein the content of α-chloronaphthalene in the hydroxygallium phthalocyanine pigment in the charge generation layer is in a range of 0 ng/cm 2 to 0.1 ng/cm 2 , the charge transport layer comprises a non-halogen organic solvent having a boiling point of 140° C. or more, the non-halogen organic solvent comprises o-xylene and methyl benzoate, and the content of the non-halogen organic solvent in the charge transport layer is in a range of 0.1 μg/cm 2 to 5 μg/cm 2 .

2. The multilayer type electrophotographic photoreceptor according to claim 1 , wherein the non-halogen organic solvent further comprises at least one selected from the group consisting of ethyl benzoate, benzyl acetate, ethyl 3-ethoxypropionate, diethylene glycol ethyl methyl ether, and 4-methoxy-4-methyl-2-pentanone.

3. The multilayer type electrophotographic photoreceptor according to claim 1 , wherein the charge generation layer comprises at least one compound selected from an amino compound, an amide compound, and a urea compound.

4. The multilayer type electrophotographic photoreceptor according to claim 1 , wherein the charge transport layer further comprises a polyarylate resin.

5. The multilayer type electrophotographic photoreceptor according to claim 1 , wherein the hydroxygallium phthalocyanine is hydroxygallium phthalocyanine crystal which represents an intense diffraction peak at Bragg angles (2θ±0.2) of 28.3° in an X-ray diffraction pattern with CuKα line.

6. An electrophotographic photoreceptor cartridge comprising the electrophotographic photoreceptor according to claim 1 .

7. An image forming apparatus comprising:

the electrophotographic photoreceptor according to claim 1 ;

a charging device;

an exposing device; and

a developer.

8. The multilayer type electrophotographic photoreceptor according to claim 1 , wherein the hydroxygallium phthalocyanine pigment in the charge generation layer does not contain α-chloronaphthalene.

9. The multilayer type electrophotographic photoreceptor according to claim 3 , wherein the content of the at least one compound selected from an amino compound, an amide compound, and a urea compound with respect to the amount of the hydroxygallium phthalocyanine pigment is in a range of 0.05 to 20 mass %.

10. The multilayer type electrophotographic photoreceptor according to claim 3 , wherein the content of the at least one compound selected from an amino compound, an amide compound, and a urea compound with respect to the amount of the hydroxygallium phthalocyanine pigment is in a range of 0.2 to 10 mass %.

11. The multilayer type electrophotographic photoreceptor according to claim 1 , wherein the content of the non-halogen organic solvent in the charge transport layer is in a range of 0.2 μg/cm 2 to 2 μg/cm 2 .

Assignments (3)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Sep 4, 2017
From: MITSUBISHI CHEMICAL CORPORATION
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043750/0207 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 10, 2017
From: FUJII, AKITERU
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 041224/0407 →