IP Library Granted Patent US 10,920,368
Granted Patent B2
US 10,920,368 · App. 15/440,213 · Granted Feb 16, 2021

Systems and methods for coloring nanofibrous materials

Inventors: Peter L. Antoinette (Nashua, NH); Mark A. Banash (Bedford, NH); Ashley Hart (Manchester, NH)
Assignee: Nanocomp Technologies, Inc.
D06M15/19B05D1/002B05D1/007B05D1/04B05D1/22B05D1/28B05D3/065B05D3/108D06M2101/40
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Quick Facts
Patent No.
US 10,920,368
App. No.
15/440,213
Granted
Feb 16, 2021
Kind
B2
Abstract

A method for coloring a carbon nanotube (CNT) product is provided, including placing a CNT product in an electric circuit to ground the product, charging a plurality of pigment molecules with an opposite charge from the CNT product, applying a coating of the charged pigment molecules to a surface of the CNT product, and exposing the coating to a temperature sufficient to cure the coating, while allowing the coating to form a substantially conformal film on the surface of the CNT product.

Claims (24)

1. A method for coloring a carbon nanotube (CNT) product comprising:

placing a CNT product in an electric circuit to ground the product;

charging a plurality of pigment molecules with an opposite charge from the CNT product;

applying a powder coating of the charged pigment molecules to a surface of the CNT product; and

exposing the charged pigment molecules to a temperature sufficient to cure the coating, while allowing the coating to form a substantially conformal film on the surface of the CNT product wherein the coated CNT product comprises an extended network of interconnected and branching bundles of nanotubes.

2. The method of claim 1 , wherein the step of exposing the charged pigment molecules to heat is performed subsequent to the step of applying.

3. The method of claim 1 , wherein the step of exposing the charged pigment molecules to heat is at least partially performed simultaneous with the step of applying.

4. The method of claim 1 , wherein curing the coating further comprises heating the coating to a temperature of about 150° C. or higher.

5. The method of claim 4 , wherein curing the coating further comprises heating the coating to a temperature of about 150° C. to about 400° C.

6. The method of claim 5 , wherein curing the coating further comprises heating the coating to a temperature of about 200° C. to about 250° C.

7. The method of claim 1 , wherein the pigment molecules include one or more of polymers, monomers, finely divided polymers, acrylates, acrylonitrile butadiene styrene, polyamides, polyesters, polyurethanes, fusion bonded epoxies, polyethylene, polypropylene, polyphenylene sulfide, polyphenylene oxide, polystyrene, azos, anthraquinones, quinolones, perinones, perylenes, indigoids, xanthenes, phthalocyanines, methines, triarylmethanes, aminoketones, azines, or combinations thereof.

8. The method of claim 1 , wherein the step of exposing the coating to heat includes exposing at least one of the coating or the CNT product to one or more of convection energy, infrared energy, microwave energy, laser energy, or combinations thereof.

9. The method of claim 1 , wherein the step of exposing the coating to heat further comprises flowing electricity through at least a portion of the CNT product to resistively heat the at least a portion of the CNT product.

10. The method of claim 1 , wherein the CNT product is in the form of a CNT sheet, CNT strip, CNT tape, bulk-collected CNTs, or CNT yarn.

11. A method for coloring a carbon nanotube (CNT) product comprising:

heating a CNT product;

placing the CNT product in an electric circuit to ground the product;

charging a plurality of pigment molecules with an opposite charge from the CNT product;

applying a powder coating of the charged pigment molecules to a surface of the CNT product, wherein contact between the heated CNT product and the charged pigment molecules of the coating heats the coating to a temperature sufficient to cure the coating, while allowing the coating to form a substantially conformal film on the surface of the CNT product wherein the coated CNT product comprises an extended network of interconnected and branching bundles of nanotubes.

12. The method of claim 11 , wherein curing the coating further comprises heating the coating to a temperature of about 150° C. or higher.

13. The method of claim 11 , wherein the pigment molecules include one or more of polymers, monomers, finely divided polymers, acrylates, acrylonitrile butadiene styrene, polyamides, polyesters, polyurethanes, fusion bonded epoxies, polyethylene, polypropylene, polyphenylene sulfide, polyphenylene oxide, polystyrene, azos, anthraquinones, quinolones, perinones, perylenes, indigoids, xanthenes, phthalocyanines, methines, triarylmethanes, aminoketones, azines, or combinations thereof.

14. The method of claim 11 , wherein the step of heating the CNT product includes exposing the CNT product to one or more of convection energy, infrared energy, microwave energy, laser energy, or combinations thereof.

15. The method of claim 11 , wherein the step of heating the CNT product further comprises flowing electricity through at least a portion of the CNT product to resistively heat the at least a portion of the CNT product.

16. The method of claim 11 , wherein the CNT product is in the form of a CNT sheet, CNT strip, CNT tape, bulk-collected CNTs, or CNT yarn.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Jul 28, 2026
From: SECTOR CAPITAL GROUP, LLC
To: HUNTSMAN NANOCOMP LLC
Reel/Frame 075425/0284 →
RELEASE OF SECURITY INTEREST Recorded Jul 28, 2026
From: PIVOTAL CAPITAL FUND, LP
To: HUNTSMAN NANOCOMP LLC
Reel/Frame 075425/0272 →
SECURITY INTEREST Recorded May 4, 2026
From: HUNTSMAN INTERNATIONAL LLC; HUNTSMAN ADVANCED MATERIALS AMERICAS LLC; HUNTSMAN NANOCOMP LLC; HUNTSMAN PETROCHEMICAL LLC
To: CITIBANK N.A.
Reel/Frame 075498/0663 →
PATENT SECURITY AGREEMENT Recorded Mar 10, 2026
From: HUNTSMAN INTERNATIONAL LLC; HUNTSMAN ADVANCED MATERIALS AMERICAS LLC; HUNTSMAN NANOCAMP LLC; HUNTSMAN PETROCHEMICAL LLC
To: CITIBANK, N.A.
Reel/Frame 075106/0238 →
SECURITY INTEREST Recorded Jan 21, 2018
From: NANOCOMP TECHNOLOGIES, INC.
To: SECTOR CAPITAL GROUP, LLC
Reel/Frame 044683/0242 →
SECURITY INTEREST Recorded May 12, 2017
From: NANOCOMP TECHNOLOGIES, INC.
To: PIVOTAL CAPITAL FUND, LP
Reel/Frame 042364/0279 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2017
From: ANTOINETTE, PETER L.; BANASH, MARK A.; HART, ASHLEY
To: NANOCOMP TECHNOLOGIES, INC.
Reel/Frame 041885/0974 →