Corrosion inhibiting compositions to mitigate corrosion in environments containing elemental sulfur and/or polysulfides
A corrosion inhibiting composition is provided which comprises a salt of a fatty acid-amine condensate and an aromatic solvent. The composition can be used in reducing, inhibiting or preventing corrosion of a metal surface used in recovery, transportation, refining or storage of a hydrocarbon fluid containing elemental sulfur or polysulfide.
1. A corrosion inhibiting composition comprising a salt of a fatty acid-amine condensate and an aromatic solvent, wherein the salt of the fatty acid-amine condensate comprises a reaction product of (1) a polyunsaturated fatty acid dimer, (2) a sulfonic acid compound, and (3) a reaction product of a polyalkylene polyamine, a tall oil fatty acid, and a polyunsaturated fatty acid dimer.
2. The composition of claim 1 comprising:
from about 2 to about 30 wt. % of the salt of the fatty acid-amine condensate;
from about 1 to about 40 wt. % cationic surfactant;
from about 1 to about 40 wt. % substituted aromatic amine;
from about 1 to about 30 wt. % phosphoric acid ester;
from 0 to about 20 wt. % solvent stabilizer compound;
from 0 to about 5 wt. % demulsifier;
from 0 to about 15 wt. % organic sulfur compound; and
from about 40 to about 80 wt. % of the aromatic solvent.
3. The composition of claim 1 , wherein the sulfonic acid compound comprises a linear alkyl benzene sulfonic acid.
4. The composition of claim 1 , wherein the polyunsaturated fatty acid dimer comprises a linoleic acid dimer.
5. The composition of claim 1 , wherein the composition further comprises a cationic surfactant, a solvent stabilizer, a phosphoric acid ester, an organic sulfur compound, a demulsifier, a substituted aromatic amine, or a combination thereof.
6. The composition of claim 5 , wherein the composition further comprises the cationic surfactant, and the cationic surfactant comprises an alkoxylated alkyl amine, a quaternary ammonium compound, or a combination thereof.
7. The composition of claim 5 , wherein the composition further comprises the solvent stabilizer, and the solvent stabilizer comprises a glycol ether.
8. The composition of claim 7 , wherein the glycol ether comprises 2-butoxyethanol.
9. The composition of claim 5 , wherein the composition further comprises the phosphoric acid ester, and the phosphoric acid ester comprises an alkoxylated alkylphenol phosphate ester.
10. The composition of claim 5 , wherein the composition further comprises the organic sulfur compound, and the organic sulfur compound comprises a mercaptoalkyl alcohol.
11. The composition of claim 5 , wherein the composition further comprises the demulsifier, and the demulsifier comprises an oxyalkylate polymer.
12. The composition of claim 11 , wherein the oxyalkylate polymer comprises a polyalkylene glycol.
13. The composition of claim 1 , wherein the solvent comprises xylene, heavy aromatic naphtha, toluene, or a combination thereof.
14. The composition of claim 5 , wherein the composition further comprises the substituted aromatic amine, and either: the substituted aromatic amine comprises an alkyl pyridine; or the substituted aromatic amine comprises 3,5-diethyl-2-methylpyridine, 3-ethyl-4-methylpyridine, (E)-5-ethyl-2-(prop-1-en-1-yl)pyridine, (E)-5-(but-2-en-1-yl)-2-methylpyridine, N-ethyl-2-(6-methylpyridin-3-yl)ethanamine, or a combination thereof.
15. The composition of claim 2 comprising
from about 3 to about 20 wt. % of the salt of the fatty acid-amine condensate;
from about 1 to about 20 wt. % of the cationic surfactant;
from about 1 to about 20 wt. % of the substituted aromatic amine;
from about 1 to about 20 wt. % of the phosphoric acid ester;
from about 1 to about 15 wt. % of the solvent stabilizer compound;
from about 0.5 to about 5 wt. % of the demulsifier;
from 1 to about 10 wt. % of the organic sulfur compound; and
from about 50 to about 80 wt. % of the aromatic solvent.
16. The composition of claim 2 comprising
from about 4 to about 10 wt. % of the salt of the fatty acid-amine condensate;
from about 1 to about 10 wt. % of the cationic surfactant;
from about 1 to about 10 wt. % of the substituted aromatic amine;
from about 1 to about 10 wt. % of the phosphoric acid ester;
from about 1 to about 10 wt. % of the solvent stabilizer compound;
from about 0.5 to about 5 wt. % of the demulsifier;
from 1 to about 5 wt. % of the organic sulfur compound; and
from about 65 to about 80 wt. % of the aromatic solvent.
17. A method of reducing, inhibiting or preventing corrosion of a metal surface used in recovery, transportation, refining or storage of a hydrocarbon fluid containing elemental sulfur or polysulfide, the method comprising contacting the composition of claim 1 with the metal surface to reduce, inhibit or prevent corrosion of the metal surface.
18. The method of claim 17 , wherein either: the composition is added to the hydrocarbon fluid before the hydrocarbon fluid contacts the metal surface; the hydrocarbon fluid contains at least 500 ppm elemental sulfur; the composition is added to the hydrocarbon fluid at a concentration of about 100 to about 1,000,000 ppm; or the metal surface comprises a carbon steel conduit or pipeline.
19. The method of claim 18 , wherein the composition is added to the hydrocarbon fluid at a concentration of about 500 to about 100,000 ppm.
20. A method of reducing, inhibiting or preventing corrosion of a metal surface used in recovery, transportation, refining or storage of a hydrocarbon fluid containing elemental sulfur or polysulfide, the method comprising contacting the composition of claim 2 with the metal surface to reduce, inhibit or prevent corrosion of the metal surface.