High-density, crack-free metallic parts
View Patent ↗In various embodiments, three-dimensional layered metallic parts are substantially free of gaps between successive layers, are substantially free of cracks, and have densities no less than 97% of the theoretical density of the metallic material.
1. A three-dimensional part manufactured by additive manufacturing using a feedstock material comprising molybdenum, the part (i) comprising a plurality of layers each comprising solidified molybdenum, (ii) being free of gaps between successive layers, and (iii) being free of cracks, wherein a density of the part is no less than 97% of a theoretical density of molybdenum, and wherein a concentration within the part of each of sodium, calcium, antimony, magnesium, phosphorous, and potassium is less than 1 ppm by weight and at least 0.001 ppm by weight.
2. The part of claim 1 , wherein the density of the part is no less than 99% of the theoretical density of molybdenum.
3. The part of claim 1 , wherein a concentration of oxygen within the part is less than 5 ppm by weight and at least 0.001 ppm by weight.
4. The part of claim 1 , wherein the feedstock material comprises wire.
5. The part of claim 1 , wherein the feedstock material comprises arc-melted wire.
6. The part of claim 1 , wherein the feedstock material comprises wire fabricated by a process comprising:
compacting powder to form a feed electrode, the powder comprising molybdenum;
arc-melting the feed electrode in a processing ambient comprising a vacuum or one or more inert gases, thereby forming a billet; and
mechanically deforming the billet into wire having a diameter less than a diameter of the billet.
7. The part of claim 1 , wherein the density of the part is no less than 99.5% of the theoretical density of molybdenum.
8. A three-dimensional part manufactured by additive manufacturing using a feedstock material comprising a metallic material comprising at least one of niobium, tantalum, rhenium, tungsten, or molybdenum, the part (i) comprising a plurality of layers each comprising solidified metallic material, (ii) being free of gaps between successive layers, and (iii) being free of cracks, wherein a density of the part is no less than 97% of a theoretical density of the metallic material, and wherein a concentration within the part of each of sodium, calcium, antimony, magnesium, phosphorous, and potassium is less than 1 ppm by weight and at least 0.001 ppm by weight.
9. The part of claim 8 , wherein the density of the part is no less than 99% of the theoretical density of the metallic material.
10. The part of claim 8 , wherein the feedstock material comprises wire.
11. The part of claim 8 , wherein the feedstock material comprises arc-melted wire.
12. The part of claim 8 , wherein the feedstock material comprises wire fabricated by a process comprising:
compacting powder to form a feed electrode, the powder comprising the metallic material;
arc-melting the feed electrode in a processing ambient comprising a vacuum or one or more inert gases, thereby forming a billet; and
mechanically deforming the billet into wire having a diameter less than a diameter of the billet.
13. The part of claim 8 , wherein the density of the part is no less than 99.5% of the theoretical density of the metallic material.
14. A three-dimensional part manufactured by additive manufacturing using a feedstock material comprising a metallic material comprising at least one of niobium, tantalum, rhenium, tungsten, or molybdenum, the part (i) comprising a plurality of layers each comprising solidified metallic material, (ii) being free of gaps between successive layers, and (iii) being free of cracks, wherein (a) a density of the part is no less than 97% of a theoretical density of the metallic material, (b) a concentration within the part of each of sodium, calcium, antimony, magnesium, phosphorous, and potassium is less than 1 ppm by weight and at least 0.001 ppm by weight, and (c) a concentration of oxygen within the part is less than 5 ppm by weight and at least 0.001 ppm by weight.
15. The part of claim 14 , wherein the density of the part is no less than 99% of the theoretical density of the metallic material.
16. The part of claim 14 , wherein the feedstock material comprises wire.
17. The part of claim 14 , wherein the feedstock material comprises arc-melted wire.
18. The part of claim 14 , wherein the feedstock material comprises wire fabricated by a process comprising:
compacting powder to form a feed electrode, the powder comprising the metallic material;
arc-melting the feed electrode in a processing ambient comprising a vacuum or one or more inert gases, thereby forming a billet; and
mechanically deforming the billet into wire having a diameter less than a diameter of the billet.
19. The part of claim 14 , wherein the density of the part is no less than 99.5% of the theoretical density of the metallic material.