IP Library Granted Patent US 10,597,603
Granted Patent B2
US 10,597,603 · App. 15/446,556 · Granted Mar 24, 2020

Oil recovery aid

Inventors: Christopher B. Murphy (Burr Ridge, IL); David A Fowlie (Concord, NC)
Assignees: POLYMER VENTURES, INC.; Phibro Animal Health Corp
C11B3/16B01D11/0492B01D21/01C08G65/02C08L71/02C11B1/10C11B1/108C11B13/00C08G2650/58C08L2205/025
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Quick Facts
Patent No.
US 10,597,603
App. No.
15/446,556
Granted
Mar 24, 2020
Kind
B2
Abstract

Compositions for increasing corn oil recovery and embodiments of methods for using the composition for corn oil separation are described. The composition(s) incorporate an admixture that includes a polymer selected from a polyglycol ester, a polyethyleneoxide-polypropyleneoxide block copolymer, a poloxamine, or a mixture thereof. The methods include admixing the compositions with a process stream for, for example, the extraction of oil from milled corn and residues from a fermentation step, including stillage (e.g., thin stillage or mid stillage), distiller's wet grain, distiller's dry grain and distiller's dry grains with solubles.

Claims (11)

1. A method comprising:

adding an oil recovery aid that consists essentially of a polymer selected from a polyethyleneoxide-polypropyleneoxide block copolymer, a poloxamine, and a mixture or aqueous composition thereof to a corn-to-ethanol process stream,

wherein the oil recovery aid provides an Oil Separation Rating of 3 by Separation Testing at a polymer dosage of 150 ppm.

2. The method of claim 1 , wherein the polymer includes a polyethyleneoxide-polypropyleneoxide block copolymer.

3. The method of claim 2 , wherein the polymer includes a mixture of polyethyleneoxide-polypropyleneoxide block copolymers.

4. A method comprising:

adding a polymer selected from a poloxamine and a mixture of the poloxamine and a polyethyleneoxide-polypropyleneoxide block copolymer to a corn-to-ethanol process stream,

wherein the polymer provides an Oil Separation Rating of at least 2 by Separation Testing via direct addition of a polymer dosage of 150 ppm to 350 ppm,

wherein the a poloxamine has a formula (R 1 ) 2 N[(CH 2 ) m NR 1 ] p R 1 , wherein each R 1 is, independently, selected from a hydrogen atom, a hydroxyethyl group, a hydroxypropyl group, a polyethyleneoxide group, a polypropyleneoxide group, a polyethyleneoxide-polypropyleneoxide group, a polypropyleneoxide-polyethyleneoxide group, a glycol, a glycol ester, a polyglycol, or a polyglycol ester; m ranges from 1 to 10; and p ranges from 1 to 10.

5. The method of claim 4 , wherein the polymer includes a mixture of poloxamines.

6. The method of claim 4 , wherein the polymer includes a poloxamine and a polyethyleneoxide-polypropyleneoxide block copolymer.

Assignments (5)
RELEASE OF SECURITY INTEREST IN PATENTS AT REEL 056139, FRAME 0578 Recorded Jul 17, 2024
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: PHIBRO ANIMAL HEALTH CORPORATION; OMNIGEN RESEARCH, LLC
Reel/Frame 068404/0557 →
SECURITY INTEREST Recorded Jul 15, 2024
From: PHIBRO ANIMAL HEALTH CORPORATION; PRINCE AGRI PRODUCTS, INC.; OMNIGEN RESEARCH, LLC
To: COÖPERATIEVE RABOBANK U.A., NEW YORK BRANCH, AS COLLATERAL AGENT
Reel/Frame 068370/0043 →
SECURITY INTEREST Recorded May 5, 2021
From: PHIBRO ANIMAL HEALTH CORPORATION; OMNIGEN RESEARCH, LLC
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 056139/0578 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 6, 2018
From: FOWLIE, DAVID A.
To: PHIBRO ANIMAL HEALTH CORPORATION
Reel/Frame 047693/0354 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 13, 2018
From: MURPHY, CHRISTOPHER B
To: POLYMER VENTURES INC
Reel/Frame 047481/0921 →