Lithium secondary batteries
View Patent ↗Provided is a lithium secondary battery including an anode containing agglomerate artificial graphite having pores with an average diameter of 80 to 150 nm; and an electrolyte solution having a viscosity of 5.0 cP or less at 25° C. The lithium secondary battery according to the present invention may have excellent life characteristics, high temperature storage characteristics and output characteristics.
1. A lithium secondary battery comprising: an anode containing agglomerate artificial graphite having pores with an average diameter of 80 to 150 nm; and an electrolyte solution having a viscosity of 5.0 cP or less at 25° C.,
wherein the agglomerate artificial graphite satisfies the following Equation 1:
0.1≤Δ H A /H A ≤0.4
wherein H A is an average particle diameter (μm) of the agglomerate artificial graphite; and ΔH A is an average particle diameter variation (μm) of the agglomerate artificial graphite when applying a pressure of 4 mN/cm 2 ,
wherein the electrolyte solution contains a first solvent including ethylmethyl carbonate, diethyl carbonate or a mixed solution thereof and a second solvent including at least one selected from dimethyl carbonate (DMC), dipropyl carbonate (DPC), methylpropyl carbonate (MPC), ethylpropyl carbonate (EPC), ethylene carbonate (EC), propylene carbonate (PC), and butylene carbonate (BC).
2. The lithium secondary battery of claim 1 , wherein the agglomerate artificial graphite has a true density of 2 to 2.5 g/cm 3 , and a specific surface area of 0.5 to 5 m 2 /g.
3. The lithium secondary battery of claim 1 , wherein the agglomerate artificial graphite has Lc(002) of 3.355 to 3.361 in which Lc(002) is a crystallite size in a C-axis direction when measuring an X-ray diffraction pattern.
4. The lithium secondary battery of claim 1 , wherein the first solvent contains 55 to 80 vol % of ethylmethyl carbonate based on a total volume of the electrolyte solution.
5. A lithium secondary battery comprising: an anode containing agglomerate artificial graphite having pores with an average diameter of 80 to 150 nm; and an electrolyte solution having a viscosity of 5.0 cP or less at 25° C.,
wherein the agglomerate artificial graphite has a true density of 2 to 2.5 g/cm 3 , and a specific surface area of 0.5 to 5 m 2 /g,
wherein the electrolyte solution contains a first solvent including ethylmethyl carbonate, diethyl carbonate or a mixed solution thereof, and a second solvent including at least one selected from dimethyl carbonate (DMC), dipropyl carbonate (DPC), methylpropyl carbonate (MPC), ethylpropyl carbonate (EPC), ethylene carbonate (EC), propylene carbonate (PC), and butylene carbonate (BC).
6. The lithium secondary battery of claim 5 , wherein the agglomerate artificial graphite has Lc(002) of 3.355 to 3.361 in which Lc(002) is a crystallite size in a C-axis direction when measuring an X-ray diffraction pattern.
7. The lithium secondary battery of claim 5 , wherein the first solvent contains 55 to 80 vol % of ethylmethyl carbonate based on a total volume of the electrolyte solution.