IP Library Granted Patent US 11,031,145
Granted Patent B2
US 11,031,145 · App. 15/450,167 · Granted Jun 8, 2021

Method of manufacturing a reinforced nuclear fuel cladding using an intermediate thermal deposition layer

Inventors: Edward J. Lahoda (Edgewood, PA); Andrew J. Mueller (Elizabeth, PA)
Assignee: Westinghouse Electric Company LLC
G21C21/02G21C3/042G21C3/10G21C3/20B22F3/04C04B35/622C04B2235/604C23C24/04F05D2230/31G21C3/045G21C3/047G21C3/06Y02E30/30
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Quick Facts
Patent No.
US 11,031,145
App. No.
15/450,167
Granted
Jun 8, 2021
Kind
B2
Abstract

A method is described that includes the steps of making a thin walled Zr alloy tube, loading nuclear fuel pellets into the tube, compressing the tube onto the fuel pellets to substantially reduce free space around the fuel pellets, positioning end plugs at each of two ends of the tube, filling the tube with a heat transferring gas, and coating the compressed tube with a corrosion resistant material using a thermal deposition process, such as cold spray, before inserting the tube into a pre-formed SiC composite cover having at least one closed end.

Claims (52)

1. A method for making a fuel rod comprising:

loading a tube having a first open end and a second open end with nuclear fuel, then

compressing the fuel-loaded tube around the fuel to reduce free space in the tube, then

closing at least one of the first and second ends of the tube, then

filling the fuel-loaded compressed tube with a gas suitable for transferring heat, and then

covering the compressed tube with a pre-formed protective cover such that a gap sized to allow tube swelling is defined between the protective cover and the compressed tube.

2. The method recited in claim 1 further comprising closing each of the first and second open ends of the tube with a first and second end plug, respectively, wherein at least one of the first and second end plugs has a gas port.

3. The method recited in claim 2 wherein each open end is closed prior to filling the fuel-loaded tube with gas through the gas port.

4. The method recited in claim 1 wherein compressing the tube comprises placing the tube into a chamber, and pressurizing the chamber with a fluid to exert sufficient force against the tube to press the tube against the fuel residing in the tube.

5. The method recited in claim 4 wherein the fluid is one of a liquid or a compressed gas.

6. The method recited in claim 4 wherein the chamber is a cold isostatic press.

7. The method recited in claim 6 wherein the chamber is a dry bag cold isostatic press wherein a flexible membrane separates the fluid from the tube.

8. The method recited in claim 6 wherein the chamber is a wet bag cold isostatic press wherein the fluid contacts the tube.

9. The method recited in claim 4 wherein the inwardly directed pressure is applied with a roller around at least a portion of the tube.

10. The method recited in claim 1 further comprising applying a corrosion resistant coating on the compressed tube before covering the compressed tube with the pre-formed cover.

11. The method recited in claim 10 wherein the corrosion resistant coating is applied with a thermal deposition process.

12. The method recited in claim 11 wherein the thermal deposition process is a cold spray process.

13. The method recited in claim 12 wherein the cold spray process comprises:

heating a pressurized carrier gas to a temperature between 100° C. and 1200° C.;

adding particles to the heated carrier gas; and

spraying the carrier gas and entrained particles at a velocity of 800 to 4000 ft./sec. (about 243.84 to 1219.20 meters/sec.).

14. The method recited in claim 13 wherein the carrier gas is selected from the group consisting of nitrogen (N 2 ), hydrogen (H 2 ), argon (Ar), carbon dioxide (CO 2 ), and helium (He) and combinations thereof.

15. The method recited in claim 13 wherein the particles are selected from the group consisting of chromium, chromium alloys, and combinations thereof.

16. The method recited in claim 10 wherein the corrosion resistant coating comprises applying dual layer.

17. The method recited in claim 16 wherein applying the dual layer comprises applying an interlayer using a first cold spray process and applying an outer layer using a second cold spray process, wherein the particles used to form the interlayer are transition metal particles selected from the group consisting of molybdenum (Mo), niobium (Nb), tantalum (Ta), tungsten (W) and combinations thereof, and the particles used to form the outer layer are selected from the group consisting of chromium, chromium alloys, and combinations thereof.

18. The method recited in claim 1 wherein the tube is made of a Zr alloy.

19. The method recited in claim 1 wherein the pre-formed protective cover is made of a SiC composite material.

20. The method recited in claim 1 wherein the gas is selected from the group consisting of H 2 , He, and combinations thereof.

21. The method recited in claim 1 wherein the fuel comprises stacked pellets of fissile material.

22. The method recited in claim 21 wherein the diameter of the end plugs are about the same diameter as that of the pellets.

23. A method for making a fuel rod comprising:

providing a hollow tube having top and bottom open ends and inner and outer surfaces, then

stacking fissile material into the hollow tube, then

compressing the tube against the stacked fissile material to reduce available free space between the fissile material and the inner surface of the tube using a cold isostatic pressing process, then

closing at least one of the top and bottom ends of the tube with an end plug, at least one end plug having a gas port therethrough, then

adding a gas suitable for heat transfer to the tube through the gas port in the end plug, then

closing the port, then

applying a corrosion resistant coating to the outer surface of the compressed tube, then

providing a pre-formed cover, and then

placing the coated compressed tube into the pre-formed cover, such that a gap sized to allow tube swelling is defined between the protective cover and the compressed tube.

24. The method recited in claim 23 wherein compressing the tube comprises placing the tube into a chamber, and pressurizing the chamber with a fluid to exert sufficient force against the tube to press the tube against the fissile material residing in the tube.

25. The method recited in claim 24 wherein the fluid is one of a liquid or a compressed gas.

26. The method recited in claim 25 wherein the chamber is a cold isostatic press.

27. The method recited in claim 26 wherein the chamber is a dry bag cold isostatic press wherein a flexible membrane separates the fluid from the tube.

28. The method recited in claim 26 wherein the chamber is a wet bag cold isostatic press wherein the fluid contacts the tube.

29. The method recited in claim 24 wherein the inwardly directed pressure is applied with a roller around at least a portion of the tube.

30. The method recited in claim 23 wherein the corrosion resistant coating is applied by a thermal deposition process.

31. The method recited in claim 30 wherein the thermal deposition process is a cold spray process comprising:

heating a pressurized carrier gas selected from the group consisting of nitrogen (N 2 ), hydrogen (H 2 ), argon (Ar), carbon dioxide (CO 2 ), and helium (He) and combinations thereof to a temperature between 100° C. and 1200° C.;

adding particles for forming an outer layer, the outer layer particles selected from the group consisting of chromium, chromium alloys, and combinations thereof to the heated carrier gas; and

spraying the carrier gas and entrained particles at a velocity of 800 to 4000 ft./sec. (about 243.84 to 1219.20 meters/sec.).

32. The method recited in claim 31 wherein the corrosion resistant coating comprises applying dual layers, the dual layers comprised of an interlayer applied by a cold spray process before application of the outer layer, wherein the particles of the interlayer are transition metal particles selected from the group consisting of molybdenum (Mo), niobium (Nb), tantalum (Ta), tungsten (W) and combinations thereof.

Assignments (5)
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jan 30, 2024
From: BANK OF MONTREAL, AS COLLATERAL AGENT
To: WESTINGHOUSE ELECTRIC COMPANY LLC; BHI ENERGY I SPECIALTY SERVICES LLC
Reel/Frame 066380/0599 →
SECURITY INTEREST Recorded Jan 26, 2024
From: WESTINGHOUSE ELECTRIC COMPANY LLC; BHI ENERGY I SPECIALTY SERVICES LLC; STONE & WEBSTER, L.L.C. (FORMERLY STONE & WEBSTER, INC.)
To: DEUTSCHE BANK AG NEW YORK BRANCH, AS COLLATERAL AGENT
Reel/Frame 066373/0604 →
PATENT SECURITY AGREEMENT Recorded May 27, 2022
From: WESTINGHOUSE ELECTRIC COMPANY LLC; BHI ENERGY I SPECIALTY SERVICES LLC
To: BANK OF MONTREAL, AS COLLATERAL AGENT
Reel/Frame 060791/0372 →
CONFIRMATORY LICENSE Recorded Jul 11, 2018
From: WESTINGHOUSE ELECTRIC COMPANY, LLC
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 047245/0638 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 6, 2017
From: LAHODA, EDWARD J.; MUELLER, ANDREW J.
To: WESTINGHOUSE ELECTRIC COMPANY LLC
Reel/Frame 041472/0230 →