Method of making sulfur extended asphalt modified with crumb rubber
The present invention relates to asphalt compositions. The present invention provides for a sulfur rubber asphalt binder composition that includes a base asphalt having a softening point, elemental sulfur, and a crumb rubber material. The crumb rubber material is combined with the base asphalt and the elemental sulfur to create the sulfur rubber asphalt binder composition. The crumb rubber material is present in the sulfur rubber asphalt binder in an amount effective to increase the softening point as compared to the softening point of the base asphalt.
1. A method of making a sulfur rubber asphalt binder composition comprising the steps of:
mixing a crumb rubber material with a base asphalt at a first predetermined temperature in a shear blender for first predetermined amount of time to create an asphalt crumb rubber mixture;
placing the asphalt crumb rubber mixture in a sealed container in an oven at the first predetermined temperature for a second predetermined amount of time to create an aged asphalt crumb rubber mixture, wherein the asphalt crumb rubber mixture is cured and reacted in the sealed container free of external mixing for the second predetermined amount of time;
adding elemental sulfur to the aged asphalt crumb rubber mixture and mixing for a third predetermined amount of time at a second predetermined temperature such that intimate mixing of the elemental sulfur and the asphalt crumb mixture is achieved.
2. The method of claim 1 , wherein the elemental sulfur is in powder form.
3. The method of claim 1 , where the elemental sulfur is in liquid form.
4. The method of claim 1 , where the first predetermined temperature is about 180° C.
5. The method of claim 1 , where the second predetermined temperature is about 145° C.
6. The method of claim 1 , where the first predetermined amount of time is about 2 minutes.
7. The method of claim 1 , where the second predetermined amount of time is about 2 hours.
8. The method of claim 1 , where the third predetermined amount of time is about 20 minutes.
9. The method of claim 1 , wherein the first predetermined amount of time is in a range of about 1 minutes to about 5 minutes, the second predetermined amount of time is in a range of about 90 minutes to about 150 minutes and the third predetermined amount of time is in a range of about 15 minutes to about 25 minutes.
10. A method of making a sulfur rubber asphalt binder composition comprising the steps of:
mixing a crumb rubber material with a base asphalt at a first predetermined temperature in a shear blender for first predetermined amount of time to create an asphalt crumb rubber mixture;
placing the asphalt crumb rubber mixture in a sealed container in an oven at the first predetermined temperature for a second predetermined amount of time to create an aged asphalt crumb rubber mixture; and
adding elemental sulfur to the aged asphalt crumb rubber mixture and mixing for a third predetermined amount of time at a second predetermined temperature such that intimate mixing of the elemental sulfur and the asphalt crumb mixture is achieved; where
the asphalt is about 54 weight percent, the elemental sulfur is about 40 weight percent and the crumb rubber material is about 6 weight percent, each by weight of the sulfur rubber asphalt binder composition.
11. A method of making a sulfur rubber asphalt binder composition comprising the steps of:
mixing a crumb rubber material with a base asphalt at a first temperature in a shear blender for first amount of time to create an asphalt crumb rubber mixture;
maintaining the asphalt crumb rubber mixture in a sealed container in an oven at the first temperature for a second amount of time to create an aged asphalt crumb rubber mixture wherein the asphalt crumb rubber mixture is cured and reacted in the sealed container free of external mixing for the second amount of time; and
introducing elemental sulfur to the aged asphalt crumb rubber mixture and mixing for a third amount of time at a second temperature such that the sulfur rubber asphalt binder composition forms;
where the elemental sulfur is in a range of from about 30 to about 50 weight percent and the crumb rubber material is in a range of from about 1 to about 6 weight percent, each by weight of the sulfur rubber asphalt binder composition.
12. The method of claim 11 , where the sulfur rubber asphalt binder composition and the base asphalt each have a softening point temperature, and the softening point temperature for the sulfur rubber asphalt binder composition is greater than that of the base asphalt.
13. The method of claim 11 , where:
the elemental sulfur is in an amount of about 40 weight percent and the crumb rubber material is in a an amount selected from the group consisting of 1 or 2 weight percent, each by weight of the sulfur rubber asphalt binder composition; and
the sulfur rubber asphalt binder composition and the base asphalt each have a penetration grade value, and the penetration grade value for the sulfur rubber asphalt binder composition is less than that of the base asphalt.
14. The method of claim 11 , where:
the elemental sulfur is in a an amount selected from the group consisting of 30, 40 and 50 weight percent by weight of the sulfur rubber asphalt binder composition;
the crumb rubber material is in in an amount selected from the group consisting of 1, 2, 4 and 6 weight percent by weight of the sulfur rubber asphalt binder composition;
the base asphalt is an amount so that the sum of the elemental sulfur, the crumb rubber, and the base asphalt totals 100 weight percent by weight of the sulfur rubber asphalt binder composition; and
the sulfur rubber asphalt binder composition and the base asphalt each have a Performance Grade temperature range, and the Performance Grade temperature range for the sulfur rubber asphalt binder composition is broader than that of the base asphalt.
15. The method of claim 11 , where:
the elemental sulfur is in a an amount selected from the group consisting of 30, 40 and 50 weight percent by weight of the sulfur rubber asphalt binder composition;
the crumb rubber material is in in an amount selected from the group consisting of 1, 2, 4 and 6 weight percent by weight of the sulfur rubber asphalt binder composition;
the base asphalt is an amount so that the sum of the elemental sulfur, the crumb rubber, and the base asphalt totals 100 weight percent by weight of the sulfur rubber asphalt binder composition; and
the Performance Grade of the sulfur rubber asphalt binder composition is selected from the group consisting of 70-10, 76-10, 82-10 and 88-10.
16. The method of claim 11 , where:
the elemental sulfur is in a an amount of about 30 weight percent by weight of the sulfur rubber asphalt binder composition;
the crumb rubber material is in in an amount selected from the group consisting of 1, 2, 4 and 6 weight percent by weight of the sulfur rubber asphalt binder composition;
the base asphalt is an amount so that the sum of the elemental sulfur, the crumb rubber, and the base asphalt totals 100 weight percent by weight of the sulfur rubber asphalt binder composition; and
the sulfur rubber asphalt binder composition and the base asphalt each have a set of complex modulus (G*) values associated with a range of temperature values in a range from 64° C. to 76° C., and where each G* value for the sulfur rubber asphalt binder composition is greater at each temperature value within the range of temperature than that of the base asphalt.