Coated article having low-E coating with IR reflecting layer(s) and high index nitrided dielectric layers
A coated article includes a low emissivity (low-E) coating having at least one infrared (IR) reflecting layer of a material such as silver, gold, or the like, and a plurality of high refractive index dielectric layers of or including a nitride of Zr and Al. In certain example embodiments, the high refractive index dielectric layers of or including a nitride of Zr and Al may be amorphous or substantially amorphous so as to allow the low-E coating to better withstand optional heat treatment (HT) such as thermal tempering. In certain example embodiments, the low-E coating may be used in applications such as monolithic or insulating glass (IG) window unit, vehicle windows, of the like.
1. A coated article including a coating supported by a glass substrate, the coating comprising:
a first high index dielectric layer comprising a nitride of Zr and Al on the glass substrate, wherein the first high index dielectric layer comprising the nitride of Zr and Al contains more Zr than Al;
a first dielectric layer comprising zinc oxide on the glass substrate located over and directly contacting the first high index layer comprising the nitride of Zr and Al;
a first infrared (IR) reflecting layer on the glass substrate, located over and directly contacting the first dielectric layer comprising zinc oxide;
a first contact layer on the glass substrate located over and directly contacting the first IR reflecting layer;
a second dielectric layer comprising zinc oxide on the glass substrate located over and directly contacting the first contact layer;
a second high index dielectric layer comprising a nitride of Zr and Al on the glass substrate located over and directly contacting the second dielectric layer comprising zinc oxide, wherein the second high index dielectric layer comprising the nitride of Zr and Al contains more Zr than Al; and
another dielectric layer on the glass substrate located over at least the first and second high index dielectric layers and the first IR reflecting layer, and wherein at least one of the first and second high dielectric layers further comprises Si.
2. The coated article of claim 1 , wherein each of the first and second high index dielectric layers has a refractive index (n) of at least 2.21 at 550 nm.
3. The coated article of claim 1 , wherein each of the first and second high index dielectric layers has a refractive index (n) of at least 2.25 at 550 nm.
4. The coated article of claim 1 , wherein metal content of each of the first and second high index dielectric layers comprises from 30-80% Zr and from 10-60% Al (atomic %).
5. The coated article of claim 1 , wherein metal content of each of the first and second high index dielectric layers comprises from 35-75% Zr and from 15-50% Al (atomic %).
6. The coated article of claim 1 , wherein metal content of each of the first and second high index dielectric layers comprises from 55-70% Zr and from 20-40% Al (atomic %).
7. The coated article of claim 1 , wherein metal content of at least one of the first and second high index dielectric layers comprises from 3-25% Si (atomic %).
8. The coated article of claim 1 , wherein metal content of at least one of the first and second high index dielectric layers comprises from 3-15% Si (atomic %).
9. The coated article of claim 1 , wherein metal content of each of the first and second high index dielectric layers comprises at least twice as much Zr as Si.
10. The coated article of claim 1 , wherein metal content of each of the first and second high index dielectric layers comprises at least four times as much Zr as Si.
11. The coated article of claim 1 , wherein metal content of each of the first and second high index dielectric layers comprises at least 1.2 times as much Zr as Al (atomic %).
12. The coated article of claim 1 , wherein metal content of each of the first and second high index dielectric layers comprises at least 1.4 times as much Zr as Al.
13. The coated article of claim 1 , wherein the coating is a low-E coating and has a normal emissivity (En) of no greater than 0.2.
14. The coated article of claim 1 , wherein the coating is a low-E coating and has a normal emissivity (En) of no greater than 0.10.
15. The coated article of claim 1 , wherein each of the first and second high index dielectric layers is amorphous or substantially amorphous.
16. The coated article of claim 1 , wherein the first IR reflecting layer comprises silver.
17. The coated article of claim 1 , wherein the coating further comprises a layer comprising silicon nitride located between the glass substrate and the first high index dielectric layer.
18. The coated article of claim 1 , wherein the coated article is thermally tempered.
19. The coated article of claim 1 , wherein the coated article has a visible transmission of at least 50%.
20. The coated article of claim 1 , wherein the first contact layer comprises Ni and Cr.
21. The coated article of claim 1 , wherein the coating further comprises:
a third dielectric layer comprising zinc oxide on the glass substrate located over at least the a second high index dielectric layer comprising a nitride of Zr and Al;
a second infrared (IR) reflecting layer on the glass substrate, located over and directly contacting the third dielectric layer comprising zinc oxide;
a second contact layer on the glass substrate located over and directly contacting the second IR reflecting layer;
a fourth dielectric layer comprising zinc oxide on the glass substrate located over and directly contacting the second contact layer;
a third high index dielectric layer comprising a nitride of Zr and Al on the glass substrate located over and directly contacting the fourth dielectric layer comprising zinc oxide, wherein the third high index dielectric layer comprising the nitride of Zr and Al contains more Zr than Al; and
wherein said another dielectric layer is located over at least the third high index dielectric layer.