Grey colored heat treatable coated article having low solar factor value
View Patent ↗There are provided coated articles that include two or more infrared (IR) reflecting layers (e.g., of or including NbZr, Nb, NiCr, NiCrMo, and/or a nitride thereof) sandwiched between at least dielectric layers, and/or a method of making the same. The coating may be designed so that the coated articles realize grey (including black) glass side reflective coloration in combination with a low solar factor (SF) and/or a low solar heat gain coefficient (SHGC). Such coated articles may be used in the context of monolithic windows, insulating glass (IG) window units, laminated windows, and/or other suitable applications, and may optionally be heat treated (e.g., thermally tempered) in certain instances.
1. A coated article having grey glass side reflective coloration and including a layer system supported by a glass substrate, the layer system comprising:
a first dielectric layer comprising silicon nitride;
a first infrared (IR) reflecting layer comprising NbZr on the glass substrate over at least the first dielectric layer comprising silicon nitride;
a second dielectric layer comprising silicon nitride on the glass substrate over at least the first dielectric layer comprising silicon nitride and the first IR reflecting layer comprising NbZr;
a second layer IR reflecting layer comprising NbZr on the glass substrate over at least the second dielectric layer comprising silicon nitride;
wherein the second dielectric layer comprising silicon nitride is located directly between and contacting the first and second IR reflecting layers comprising NbZr;
a third dielectric layer comprising silicon nitride on the glass substrate over at least the second IR reflecting layer comprising NbZr;
wherein the coated article has no metallic infrared (IR) reflecting layer based on Ag and/or Au;
wherein the coated article has: glass side/exterior reflective grey coloration comprising a glass side/exterior reflective a* value of from −3.0 to +5.0, a glass side/exterior reflective b* value of from −10.0 to +2.0, a glass side/exterior reflective L* value of from 20-42, and a visible transmission of no greater than 16%, and
wherein the coated article (i) if measured monolithically has an SF value of no greater than 0.33 and an SHGC value of no greater than 0.39, and/or (ii) if an insulating glass (IG) window unit having two glass substrates has an SF value of no greater than 0.23 and an SHGC value of no greater than 0.27.
2. The coated article of claim 1 , wherein the coated article has a glass side/exterior a* value of from −2.0 to +4.0.
3. The coated article of claim 1 , wherein the coated article has a glass side/exterior b* value of from −9.0 to −1.0.
4. The coated article of claim 1 , wherein the coated article has a glass side/exterior b* value of from −8.0 to −4.0.
5. The coated article of claim 1 , wherein at least one of the first and second IR reflecting layers comprising NbZr are nitrided.
6. The coated article of claim 1 , wherein each of the first and second IR reflecting layers comprising NbZr includes more Nb than Zr based on an atomic percentage.
7. The coated article of claim 1 , wherein the coated article is heat treated and has a ΔE* value (glass side reflective) of no greater than 3.0 after and/or due to heat treatment.
8. The coated article of claim 1 , wherein the coated article has a visible transmission of from 6-16%.
9. The coated article of claim 1 , wherein at least one of the first and second layers IR reflecting layers is/are substantially free of oxygen.
10. The coated article of claim 1 , wherein the coating further comprising an overcoat layer comprising an oxide of zirconium.
11. The coated article of claim 1 , wherein the coated article has a glass side visible reflection of no greater than 8%.
12. The coated article of claim 1 , wherein the coated article has a film side/interior reflective a* value of from −4.0 to +4.0.
13. The coated article of claim 1 , wherein the coating includes only two IR reflecting layers and consists essentially of the first dielectric layer comprising silicon nitride, the first infrared (IR) reflecting layer comprising NbZr, the second dielectric layer comprising silicon nitride, the second layer IR reflecting layer comprising NbZr, and third dielectric layer comprising silicon nitride, and optionally an overcoat layer comprising an oxide of zirconium.
14. The coated article of claim 1 , wherein the first and second IR reflecting layers are of substantially the same thickness, which means that they are the same thickness plus/minus 15 Å.
15. The coated article of claim 1 , wherein a thickness ratio of the first dielectric layer/third dielectric layer is at least 1.5.
16. The coated article of claim 1 , wherein a thickness ratio of the second dielectric layer/third dielectric layer is at least 1.4.
17. The coated article of claim 1 , wherein the coating further comprises:
a third IR reflecting layer comprising NbZr on the glass substrate over at least the third dielectric layer comprising silicon nitride; and
a fourth dielectric layer comprising silicon nitride on the glass substrate over at least the third IR reflecting layer comprising NbZr.
18. The coated article of claim 1 , wherein the coated article (i) if measured monolithically has an SF value of no greater than 0.32 and an SHGC value of no greater than 0.37, and/or (ii) if an insulating glass (IG) window unit having two glass substrates has an SF value of no greater than 0.22 and an SHGC value of no greater than 0.25.
19. The coated article of claim 1 , wherein a thickness ratio of the first dielectric layer/third dielectric layer is at least 2.0.
20. The coated article of claim 1 , wherein a thickness ratio of the second dielectric layer/third dielectric layer is at least 1.7.
21. A coated article having grey glass side reflective coloration and including a layer system supported by a glass substrate, the layer system comprising:
a first dielectric layer comprising nitrogen;
a first infrared (IR) reflecting layer on the glass substrate over at least the first dielectric layer;
a second dielectric layer comprising nitrogen on the glass substrate over at least the first dielectric layer and the first IR reflecting layer;
a second layer IR reflecting layer on the glass substrate over at least the second dielectric layer;
a third dielectric layer comprising nitrogen on the glass substrate over at least the second IR reflecting layer;
wherein each of the first and second IR reflecting layers comprises one or more of: NbZr, NbZrN x , NiCr, NiCrN x , NiCrMo, NiCrMoN x , NbCr, NbCrN x , Nb and NbN x ;
wherein the coated article has no metallic infrared (IR) reflecting layer based on Ag and/or Au;
wherein the coated article has: glass side visible reflection of no greater than 8%, glass side/exterior reflective grey coloration comprising a glass side/exterior reflective a* value of from −3.0 to +5.0, a glass side/exterior reflective b* value of from −10.0 to +2.0, a glass side/exterior reflective L* value of from 20-42, and a visible transmission of no greater than 16%, and
wherein the coated article (i) if measured monolithically has an SF value of no greater than 0.33 and an SHGC value of no greater than 0.39, and/or (ii) if an insulating glass (IG) window unit having two glass substrates has an SF value of no greater than 0.23 and an SHGC value of no greater than 0.27.