IP Library Granted Patent US 10,923,887
Granted Patent B2
US 10,923,887 · App. 15/459,753 · Granted Feb 16, 2021

Wire for an ignition coil assembly, ignition coil assembly, and methods of manufacturing the wire and ignition coil assembly

Inventors: Massimo Augusto Dal Re (Concordia Sulla Secchia, IT); Giovanni Betti Beneventi (Modena, IT); Stefano Papi (Modena, IT)
Assignee: Tenneco Inc.
H01T19/00H01B1/026H01F17/045H01F27/2823H01F27/32H01F41/12
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Quick Facts
Patent No.
US 10,923,887
App. No.
15/459,753
Granted
Feb 16, 2021
Kind
B2
Abstract

A wire for an ignition coil assembly and/or a corona ignition assembly is provided. The wire comprises a wire core including a copper-based material, and a coating applied to the wire core. The coating includes at least one of a carbon-based material and magnetic nanoparticles. The carbon-based material can include graphene and/or carbon nanotubes, and the magnetic nanoparticles can include graphene and iron oxide (Fe 3 O 4 ). Typically, the coating includes a plurality of layers. For example, the coating can include a layer of the graphene and/or carbon nanotubes, and/or a layer of the magnetic nanoparticles. The coating can also include a layer of insulating material, such as enamel. According to another embodiment, the coating includes iron, nickel, and/or cobalt plated onto the wire core.

Claims (42)

1. A corona igniter assembly, comprising:

an ignition coil assembly including a coil support formed of a magnetic material and at least one wire,

said at least one wire comprising a wire core including a copper-based material,

said at least one wire including a coating applied to said wire core, and

said coating including magnetic nanoparticles, and said magnetic nanoparticles including graphene and iron oxide (Fe 3 O 4 ).

2. The corona igniter assembly of claim 1 , wherein said coating includes a first layer including graphene and a second layer including said magnetic nanoparticles.

3. The corona igniter assembly of claim 1 , wherein said first layer is disposed on said wire core, and a third layer including an insulating material is disposed outwardly of said first layer.

4. The corona igniter assembly of claim 1 , wherein said coating comprises a third layer including an insulating material disposed on said wire core, and said second layer including said magnetic nanoparticles is disposed outwardly of said third layer.

5. The corona igniter assembly of claim 1 , wherein said second layer including said magnetic nanoparticles is disposed on said wire core, and said coating includes a third layer including an insulating material disposed outwardly of said second layer.

6. The corona igniter assembly of claim 1 , wherein said first layer is disposed on said wire core, a third layer including an insulating material is disposed outwardly of said first layer, and said second layer including said magnetic nanoparticles is disposed outwardly of said third layer.

7. The corona igniter assembly of claim 1 , wherein said first layer is disposed on said wire core, said second layer including said magnetic nanoparticles is disposed outwardly of said first layer, and a third layer including an insulating material is disposed outwardly of said second layer.

8. The corona igniter assembly of claim 1 , wherein said coating includes an insulating material.

9. The corona igniter assembly of claim 8 , wherein said insulating material includes enamel.

10. The corona igniter assembly of claim 1 , wherein said copper-based material of said wire core consists of a copper or copper alloy.

11. The corona igniter assembly of claim 1 , wherein said wire core has a diameter ranging from 1 μm to 10 mm.

12. The corona igniter assembly of claim 1 , wherein said layers each have a thickness ranging from 10 nm to 1 mm.

13. The corona igniter assembly of claim 1 , wherein said wire core consists of a copper-based material for receiving energy at a first voltage and transmitting the energy to a firing end assembly at a second voltage greater than said first voltage,

said copper-based material consists of copper or a copper alloy,

said wire core has a diameter ranging from 1 μm to 10 mm, and

each of said layers of said coating has a thickness ranging from 10 nm to 1 mm.

14. The corona igniter assembly of claim 1 , wherein said at least one wire of said ignition coil assembly surrounds a center axis,

said wire core consists of said copper-based material receiving energy at a first voltage and transmitting the energy to a firing end assembly at a second voltage greater than the first voltage,

said copper-based material consists of copper or a copper alloy,

said wire core has a diameter ranging from 1 μm to 10 mm,

said coating includes a plurality of layers including at least a first layer and a second layer,

said first layer of said coating includes graphene or said first layer of said coating includes said magnetic nanoparticles,

said second layer of said coating includes an insulating material,

said insulating material of said coating includes enamel,

each of said layers of said coating has a thickness ranging from 10 nm to 1 mm,

said wire is wound around said coil support,

said coil support optionally surrounds a magnetic core,

said ignition coil assembly includes a coil housing surrounding said wire that is wound around said coil support,

said housing is sealed and filled with an electrically insulating material,

said firing end assembly includes a center electrode extending along said center axis for receiving the energy from said ignition coil assembly and distributing the energy in the form of a radio frequency electric field to ignite a mixture of fuel and air,

said center electrode includes a firing tip having a plurality of prongs presenting a terminal end of said center electrode,

said firing end assembly includes an insulator formed of a ceramic material disposed around said center electrode,

said firing end assembly includes a shell formed of metal disposed around said insulator, and

a tube formed of metal connecting said shell of said firing end assembly to said coil housing of said ignition coil assembly.

15. The corona igniter assembly of claim 1 , wherein said coating further includes cobalt.

16. A method of manufacturing a corona igniter assembly, comprising the step of:

connecting an ignition coil assembly to a firing end assembly, the ignition coil assembly including a coil support formed of a magnetic material and at least one wire, the at least one wire comprising a wire core including a copper-based material, the at least one wire comprising a coating applied to the wire core, the coating including magnetic nanoparticles, and the magnetic nanoparticles including graphene and iron oxide (Fe 3 O 4 ).

17. The method of claim 16 , wherein a first layer includes said graphene and a second layer includes said magnetic nanoparticles.

Assignments (16)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 20, 2025
From: TENNECO INC.
To: FEDERAL-MOGUL IGNITION LLC
Reel/Frame 072065/0691 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 18, 2025
From: FEDERAL-MOGUL WORLD WIDE LLC
To: FEDERAL-MOGUL MOTORPARTS LLC
Reel/Frame 072041/0655 →
PATENT SECURITY AGREEMENT (ABL) Recorded Apr 7, 2023
From: TENNECO INC.; DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 063268/0506 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Nov 22, 2022
From: DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 061989/0689 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
Reel/Frame 061975/0218 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061975/0031 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061971/0156 →
SECURITY AGREEMENT Recorded Mar 17, 2021
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 055626/0065 →
MERGER Recorded Jan 5, 2021
From: FEDERAL-MOGUL LLC
To: TENNECO INC.
Reel/Frame 054900/0129 →
MERGER AND CHANGE OF NAME Recorded Dec 17, 2020
From: FEDERAL-MOGUL LLC; TENNECO INC.
To: TENNECO INC.
Reel/Frame 054683/0494 →
SECURITY AGREEMENT Recorded Dec 1, 2020
From: TENNECO INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 054555/0592 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT, JOINDER, ASSUMPTION AND DESIGNATION AGREEMENT Recorded Oct 26, 2018
From: BANK OF AMERICA, N.A., AS CO-COLLATERAL TRUSTEE AND RESIGNING COLLATERAL TRUSTEE
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS CO-COLLATERAL TRUSTEE, SUCCESSOR COLLATERAL TRUSTEE
Reel/Frame 047630/0661 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL MOGUL POWERTRAIN LLC
Reel/Frame 047276/0720 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Oct 9, 2018
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
Reel/Frame 047223/0001 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Apr 3, 2018
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY
To: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 045822/0454 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 16, 2017
From: DAL RE, MASSIMO AUGUSTO; BENEVENTI, GIOVANNI BETTI; PAPI, STEFANO
To: FEDERAL-MOGUL LLC
Reel/Frame 041592/0755 →
Cited By (1)
US 12,340,918