Copper alloy and process for producing the same
View Patent ↗A copper alloy consisting of two or more of Cr, Ti and Zr, and the balance Cu and impurities, in which the relationship between the total number N and the diameter X satisfies the following formula (1). Ag, P, Mg or the like may be included instead of a part of Cu. This copper alloy is obtained by cooling a bloom, a slab, a billet, or a ingot in at least in a temperature range from the bloom, the slab, the billet, or the ingot temperature just after casting to 450° C., at a cooling rate of 0.5° C./s or more. After the cooling, working in a temperature range of 600° C. or lower and further heat treatment of holding for 30 seconds or more in a temperature range of 150 to 750° C. are desirably performed. The working and the heat treatment are desirably performed a plurality of times. log N ≤0.4742+17.629×exp(−0.1133× X ) (1)
1. A copper alloy consisting of, by mass %,
at least two elements selected from 0.01 to 5% of Cr, 0.01 to 5% of Ti and 0.01 to 5% of Zr;
at least one element selected from following (A) to (D):
(A) 0.01 to 5% of Ag;
(B) 5% or less in total of one or more elements selected from the following groups (b), (c) and (d):
group (b): 0.001 to 0.5% each of P, S, As, Pb and B;
group (c): 0.01 to 5% each of Sn, Mn, Fe, Co, Al, Si, Nb, Ta, Mo, V, W and Ge;
group (d): 0.01 to 3% each of Zn, Ni, Te, Cd and Se;
(C) 0.001 to 2% in total of one or more elements selected from Mg, Li, Ca and rare earth elements; and
(D) 0.001 to 0.3% in total of one or more elements selected from Bi, TI, Rb, Cs, Sr, Ba, Tc, Re, Os, Rh, In, Pd, Po, Sb, Hf, Au, Pt and Ga;
and the balance Cu and impurities;
wherein the relationship between the total number N of precipitates and intermetallics, having a diameter of not smaller than 1 μm, which are found in 1 mm 2 of the alloy, and the diameter X in μm of the precipitates and the intermetallics having a diameter of not smaller than 1 μm satisfies the following formula (1);
log N ≤0.4742+17.629×exp(−0.1133 ×X ) (1)
wherein X=1 when the measured value of the grain size of the precipitates and the intermetallics are 1.0 μm or more and less than 1.5 μm, and X=α(αis an integer of 2 or more) when the measured value is (α−0.5) μm or more and less than (α+0.5) μm.
2. The copper alloy according to claim 1 , wherein the ratio of the maximum value and the minimum value of an average content of at least one alloy element in a micro area is not less than 1.5.
3. The copper alloy according to claim 1 , wherein the grain size is 0.01 to 35 μm.
4. The copper alloy according to claim 2 , wherein the grain size is 0.01 to 35 μm.