Production method and production apparatus of α-olefin oligomer
View Patent ↗The present invention relates to a production method of an α-olefin oligomer for producing an α-olefin by performing an oligomerization reaction of an α-olefin in a reaction solvent in the presence of a catalyst in a reactor, which is a production method of an α-olefin oligomer, comprising circulating and feeding, to the reactor, a condensate liquid obtained by introducing part of gas of the gas phase part inside the reactor into a heat exchanger and cooling the gas, wherein the condensate liquid circulated and fed to the reactor is dispersed in the gas phase part inside the reactor; and a production apparatus of an α-olefin oligomer.
1. A method for producing an α-olefin oligomer and reducing fouling in one or more downstream process equipment, comprising:
oligomerizing an α-olefin in a reaction solvent in the presence of a catalyst in a reactor to produce the α-olefin oligomer comprising 1-hexene, wherein said reactor comprises a liquid phase and a gas phase;
introducing a portion of the gas phase into a heat exchanger;
cooling the portion of the gas phase in said heat exchanger to obtain a condensate liquid; and
dispersing the condensate liquid as droplets in the gas phase inside said reactor by an atomizer of a rotating disk spray system;
wherein said gas phase comprises a mist comprising a component of the catalyst and/or a portion of the α-olefin, wherein the mist is generated by vaporization of the liquid phase, and wherein the mist is absorbed onto the condensate droplets thereby reducing fouling in the downstream process equipment caused by the mist.
2. The method of claim 1 , wherein said heat exchanger is arranged outside of said reactor.
3. The method of claim 1 , wherein the gas outlet temperature of the gas phase of said reactor is lower by 8° C. or more than the liquid phase temperature of said reactor.
4. The method of claim 1 , wherein the inlet temperature of said heat exchanger is lower by 8° C. or more than the liquid phase temperature of said reactor.
5. The method of claim 1 , wherein an uncondensed gas obtained from said heat exchanger is fed to the liquid phase of said reactor.
6. The method of claim 1 , wherein said catalyst comprises a combination of a chromium-containing compound, a nitrogen-containing compound (b), and an aluminum-containing compound (c).
7. The method of claim 6 , wherein said catalyst further comprises a halogen-containing compound (d).
8. The method of claim 1 , wherein said α-olefin is ethylene.
9. The method of claim 1 , wherein a ratio of the diameter of the rotating disk of the atomizer to the diameter of the reactor is in a range from 0.1 to 0.8.
10. The method of claim 1 , wherein the condensate droplets have a diameter of 0.05 to 5 mm.