Golf ball covers made from plasticized thermoplastic materials
Multi-layered golf balls containing a two or three-layered cover assembly are provided. In one embodiment, the cover assembly includes a relatively hard inner cover and relatively soft outer cover. Alternatively, the cover assembly may include a relatively soft inner cover with a relatively hard outer cover. Three-layered covers comprising an inner cover, intermediate cover, and outer cover layer also may be prepared. Preferably, at least one of the layers is formed from a thermoplastic composition that preferably comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. The cover assembly has good impact durability and helps provide the ball with relatively high resiliency at given compressions.
1. A golf ball, comprising:
i) a core having at least one layer;
ii) an inner cover layer comprising a thermoplastic material, the inner cover layer being disposed about the core and having a Shore D midpoint hardness in the range of about 55 to about 75, the thermoplastic material comprising:
a) an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid, optionally including a softening monomer selected from the group consisting of alkyl acrylates and methacrylates;
b) a plasticizer in an amount from about 3 to about 50% by weight, the plasticizer being an alkyl oleate selected from the group consisting of methyl oleate, ethyl oleate, propyl oleate, butyl oleate, and octyl oleate, and mixtures thereof; and
c) a cation source present in an amount sufficient to neutralize from about 0 to about 100% of all acid groups present in the material; and
iii) an outer cover layer disposed about the inner cover layer and having a Shore D surface hardness in the range of about 15 to about 60, wherein the hardness of the outer cover layer is less than the hardness of the inner cover layer.
2. The golf ball of claim 1 , wherein the thermoplastic material comprises an ethylene acid copolymer containing acid groups such that 70% or less of the acid groups are neutralized.
3. The golf ball of claim 1 , wherein the thermoplastic material comprises an ethylene acid copolymer containing acid groups such that greater than 70% of the acid groups are neutralized.
4. The golf ball of claim 3 , wherein 90% or greater of the acid groups are neutralized.
5. The golf ball of claim 1 , wherein the ethylene acid copolymer is selected from the group consisting of ethylene/(meth)acrylic acid/n-butyl acrylate; ethylene/(meth)acrylic acid/ethyl acrylate; ethylene/(meth)acrylic acid/methyl acrylate; ethylene/(meth)acrylic acid/n-butyl acrylate; and ethylene/(meth)acrylic acid/isobutyl acrylate copolymers.
6. A golf ball, comprising:
i) a core having at least one layer;
ii) an inner cover layer comprising a thermoplastic material, the inner cover layer being disposed about the core and having a Shore D midpoint hardness in the range of about 55 to about 75
iii) an outer cover layer comprising a second thermoplastic material, the outer cover disposed about the inner cover layer and having a Shore D surface hardness in the range of about 15 to about 60, wherein the hardness of the outer cover layer is less than the hardness of the inner cover layer, the second thermoplastic material comprising:
a) an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid, optionally including a softening monomer selected from the group consisting of alkyl acrylates and methacrylates;
b) plasticizer in an amount from about 3 to about 50% by weight, the plasticizer being an alkyl oleate selected from the group consisting of methyl oleate, ethyl oleate, propyl oleate, butyl oleate, and octyl oleate, and mixtures thereof; and
c) a cation source present in an amount sufficient to neutralize from about 0 to about 100% of all acid groups present in the material.