Reactive hot melt adhesive composition

1. A process for preparing a reactive hotmelt adhesive composition, the process comprising:

reacting a NCO-terminated prepolymer with a mixture of:

(a) a monofunctional compound (M) having a molecular weight of less than 400 g/mol and having one functional group selected from the group consisting of primary, secondary or tertiary hydroxyl; primary, secondary or tertiary amine; primary, secondary or tertiary thiol; and carboxylic acid; and

(b) a multifunctional compound (D) having a molecular weight of less than 400 g/mol and having at least two functional groups, wherein each functional group is independently selected from the group consisting of primary, secondary or tertiary hydroxyl; primary or secondary amine; primary, secondary or tertiary thiol; and carboxylic acid; and

wherein the mixture of monofunctional compound (M) and multifunctional compound (D) is present in an amount of 0.1 to 10% by weight, based on the total weight of the composition, and

wherein the weight ratio M/D of monofunctional compound (M) to multifunctional compound (D) is in the range of 0.5 to 10.

2. The process according to claim 1 , wherein the step of reacting a NCO-terminated prepolymer with a mixture of monofunctional compound (M) and multifunctional compound (D) is carried out by

(a) adding a premixed mixture of monofunctional compound (M) and multifunctional compound (D); or

(b) simultaneously adding monofunctional compound (M) and multifunctional compound (D); or

(c) sequentially adding monofunctional compound (M) and multifunctional compound (D), wherein monofunctional compound (M) and multifunctional compound (D) are added within 20 min.

3. The process according to claim 1 , further comprising at least one:

wherein the mixture of monofunctional compound (M) and multifunctional compound (D) is present in an amount of 0.5 to 5% by weight based on the total weight of the composition and

wherein the weight ratio M/D of monofunctional compound (M) to multifunctional compound (D) is in the range of 0.5 to 8.

4. The process according to claim 1 , wherein the monofunctional compound (M) is an alcohol, has a molecular weight of 300 g/mol or less, or a combination thereof.

5. The process according to claim 1 , wherein the multifunctional compound (D) comprises at least one of:

the at least two functional groups are independently selected from the group consisting of primary, secondary and tertiary hydroxyl; and

has a total of two functional groups; and

has a molecular weight of 300 g/mol.

6. The process according to claim 1 , wherein the reaction of NCO-terminated prepolymer with the mixture of monofunctional compound (M) and multifunctional compound (D) is carried out at a reaction temperature of 80° C. to 150° C.

7. The process according to claim 1 , wherein the NCO-terminated prepolymer is obtained by reacting at least one polymer or prepolymer (P) having end groups, the end groups independently selected from the group consisting of hydroxyl, primary amine, secondary amine, thiol, and carboxylic acid, with monomeric diisocyanate, wherein the polymer or prepolymer (P) is present in an amount of 15 to 95% by weight, based on the total weight of the composition.

8. The process according to claim 7 , wherein the polymer or prepolymer (P) comprises at least one of:

is a polyol; and

is present in an amount of 50 to 93% by weight; and

has a molecular weight of 200 to 100000 g/mol.

9. The process according to claim 1 further comprising, after the step of reacting the NCO-terminated prepolymer with the mixture of monofunctional compound (M) and multifunctional compound (D), a step of adding a multifunctional isocyanate agent.

10. A reactive hotmelt adhesive composition obtained by the process according to claim 1 .

11. The adhesive composition according to claim 10 , wherein the adhesive composition has at least one of:

a residual content of monomeric diisocyanate of less than 1% by weight; and

a viscosity measured at 150° C. of 10,000 to 100,000 mPas; and

a viscosity stability of 15%/h or lower.

12. The adhesive composition according to claim 10 further comprising a non-reactive material in an amount of up to 50% by weight.

13. The adhesive composition of claim 12 wherein the non-reactive material is selected from the group consisting of ethylene vinyl acetate (EVA), thermoplastic polyurethane (TPU), amorphous poly-alpha-olefin (APAO), thermoplastic elastomer (TPE), resin, wax, tackifiying resin, talcum, calcium carbonate and pigment.

14. A reactive hot melt adhesive composition derived from a mixture of:

(a) a NCO-terminated prepolymer derived from a polyfunctional isocyanate having a functionality of about 2 or more and a polyol,

(b) a monofunctional compound (M) having a molecular weight of less than 400 g/mol and having one functional group, selected from the group consisting of primary, secondary or tertiary hydroxyl; primary, secondary or tertiary amine; primary, secondary or tertiary thiol; and carboxylic acid; and

(c) a multifunctional compound (D) having a molecular weight of less than 400 g/mol and having at least two functional groups, wherein each functional group is independently selected from the group consisting of primary, secondary or tertiary hydroxyl; primary or secondary amine; primary, secondary or tertiary thiol; and carboxylic acid;

wherein the total amount of monofunctional compound (M) in combination with the multifunctional compound (D) is present in an amount of 0.1 to 10% by weight, based on the total weight of the composition, and

wherein the weight ratio M/D of monofunctional compound (M) to multifunctional compound (D) is in the range of 0.5 to 10.

15. The process according to claim 2 , wherein the step of reacting a NCO-terminated prepolymer with a mixture of monofunctional compound (M) and multifunctional compound (D) is carried out by sequentially adding monofunctional compound (M) and multifunctional compound (D), wherein monofunctional compound (M) and multifunctional compound (D) are added within 10 min of each other.

16. The process according to claim 2 , wherein the step of reacting a NCO-terminated prepolymer with a mixture of monofunctional compound (M) and multifunctional compound (D) is carried out by sequentially adding monofunctional compound (M) and multifunctional compound (D), wherein monofunctional compound (M) and multifunctional compound (D) are added within 5 min of each other.

17. The process according to claim 5 , wherein the hydroxyl functional group comprises primary hydroxyl.

18. The process according to claim 8 , wherein the polyol comprises at least one of polyester polyol, polyether polyol, and polyester-polyether polyol.

19. The adhesive composition of claim 11 , wherein the adhesive composition has a viscosity stability of 10%/h or lower.