Lecithin-based spray adjuvant containing organosilicon wetting agents
An adjuvant composition contains lecithin and an organosilicon surfactant as defined herein.
1. An adjuvant composition comprising:
a) lecithin;
b) organosilicon surfactant of general formula (I):
R 1 —Si(R 2 )(R 3 )—Z (I)
wherein:
R 1 is a linear or branched monovalent hydrocarbon group of from 1 to 8 carbon atoms or a R 4 —Si(R 5 )(R 6 )—R 7 — group in which R 4 is a linear or branched monovalent hydrocarbon group of from 1 to 8 carbon atoms, R 5 and R 6 are independently a linear or branched monovalent hydrocarbon group of from 1 to 4 carbon atoms and R 7 is a linear or branched divalent hydrocarbon group of from 1 to 4 carbon atoms;
R 2 and R 3 are independently a linear or branched monovalent hydrocarbon group of from 1 to 4 carbon atoms; and,
Z is an alkylene oxide-containing group of up to 15 alkylene oxide units with each unit independently containing from 1 to 4 carbon atoms; a cationic group or a quaternary group free of alkyl halide;
c) at least one acidification agent; and
d) at least one wetting agent;
wherein the lecithin contains from 10 to 70 weight percent phosphatidylcholine with the balance being selected from phosphatidylethanolamine, phosphatidylinositol and phosphatidic acid and having an average acetone insoluble content of more than 60 weight percent.
2. The adjuvant composition of claim 1 wherein Z is an alkylene oxide-containing group represented by the general formula:
—R 8 O[(C 2 H 4 O) a (C 3 H 6 O) b (C 4 H 8 O) c ] d —R 9
wherein:
R 8 is a linear or branched divalent hydrocarbon group of from 3 to 8 carbon atoms; R 9 is hydrogen, a monovalent hydrocarbon radical of from 1 to 4 carbon atoms, R A —N ⊕ (R 10 )(R 11 )R 12 X ⊖ , R B —N ⊕ (R 13 )(R 14 )R 15 X ⊖ or R B —N ⊕ (R 13 )(R 14 )R 15 X ⊖ in which R A and R B are —CH 2 CH(OH)CH 2 —, R 10 , R 11 , R 13 and R 14 are independently a monovalent hydrocarbon group of 1 or 2 carbon atoms, R 12 and R 15 are independently a linear or branched monovalent hydrocarbon group of from 1 to 6 carbon atoms and optionally substituted with one or more hydroxyl groups, and X ⊖ is a ⊖ OC(═O)— containing group of from 2 to 22 carbon atoms; and subscript a is 1 to 15 and subscripts b and c each independently is 0 or 1 to 14 subject to the condition that a+b+c≤14, and subscript d is 0 to 1.
3. The adjuvant composition of claim 1 wherein X ⊖ is represented by the general formula:
⊖ OC(═O)C(R 16 )(R 17 )(R 18 )
in which R 16 and R 17 are independently hydrogen, hydroxyl or a monovalent hydrocarbon group of from 1 to 3 carbon atoms or hydroxymethyl, and R 18 is hydrogen, hydroxyl, a monovalent hydrocarbon group of 1 to 20 carbon atoms or a hydroxymethyl group.
4. The adjuvant composition of claim 1 wherein organosilicon surfactant (I) is present therein at 1 to 99 weight percent of the total weight of lecithin and organisilicon surfactant (I).
5. The adjuvant composition of claim 1 further comprising at least one component selected from the group consisting of foam control agent, organic solvent and water.
6. The adjuvant composition of claim 1 containing from 1 to 50 weight percent of organosilicon surfactant(s) (I) by total weight of lecithin and organosilicon surfactants (I).
7. The adjuvant composition of claim 1 containing from 1 to 10 weight percent of organosilicon surfactant(s) (I) by total weight of lecithin and organosilicon surfactants (I).
8. The adjuvant composition of claim 1 wherein the lecithin contains from 10 to 40 weight percent phosphalidylcholine.
9. An agrochemical formulation comprising an antidrift-effective amount of the adjuvant composition of claim 1 .
10. The agrochemical composition of claim 9 further comprising at least one bioactive selected from the group consisting of pesticide, defoliant, fertilizer, biological, nutritional, micronutrient, growth control agent or combination thereof.
11. A method of inhibiting drift of an agrochemical formulation applied to a target area which comprises spraying the agrochemical of claim 9 within the target area.
12. A method of enhancing or increasing deposition and/or retention of spray droplets of an agrochemical formulation upon external plant tissue surfaces which comprises spraying the agrochemical formulation of claim 9 upon external plant tissue surfaces.
13. A method of enhancing or increasing penetration and/or uptake of a bioactive component of an agrochemical formulation into internal plant structures which comprises spraying the agrochemical formulation of claim 9 upon external plant tissue surfaces.
14. A method of water conditioning a plant which comprises spraying the agrochemical formulation of claim 9 upon external surfaces of the plant to be water conditioned.
15. An adjuvant composition consisting essentially of:
a) lecithin;
b) organosilicon surfactant of general formula (I):
R 1 —Si(R 2 )(R 3 )—Z (I)
wherein:
R 1 is a linear or branched monovalent hydrocarbon group of from 1 to 8 carbon atoms or a R 4 —Si(R 5 )(R 6 )—R 7 — group in which R 4 is a linear or branched monovalent hydrocarbon group of from 1 to 8 carbon atoms, R 5 and R 6 are independently a linear or branched monovalent hydrocarbon group of from 1 to 4 carbon atoms and R 7 is a linear or branched divalent hydrocarbon group of from 1 to 4 carbon atoms;
R 2 and R 3 are independently a linear or branched monovalent hydrocarbon group of from 1 to 4 carbon atoms; and,
Z is an alkylene oxide-containing group of up to 15 alkylene oxide units with each unit independently containing from 1 to 4 carbon atoms; a cationic group or a quaternary group free of alkyl halide;
c) at least one acidification agent; and
d) at least one wetting agent;
wherein the lecithin contains from 10 to 70 weight percent phosphalidylcholine with the balance being selected from phosphatidylethanolamine, phosphatidylinositol and phosphatidic acid and having an average acetone insoluble content of more than 60 weight percent.
16. The adjuvant composition of claim 15 wherein the lecithin contains from 10 to 40 weight percent phosphalidylcholine.