IP Library Granted Patent US 11,208,585
Granted Patent B2
US 11,208,585 · App. 15/468,842 · Granted Dec 28, 2021

High density, low TCT divalent brines and uses thereof

Inventor: Arthur G. Mack (Conroe, TX)
Assignee: TETRA TECHNOLOGIES, INC.
C09K8/035C09K8/03C09K8/62E21B37/06
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,208,585
App. No.
15/468,842
Granted
Dec 28, 2021
Kind
B2
Abstract

A method of using a suppression factor fluid during a well activity is provided. The method comprising the steps of introducing a suppression factor fluid into a wellbore, the suppression factor fluid comprising an untreated divalent brine, and a suppression sugar alcohol, the suppression sugar alcohol in an amount operable to achieve a suppression factor of at least 0.1, wherein a density upper limitation of the suppression factor fluid is greater than the density upper limitation of the divalent brine; wherein the suppression factor fluid is in the absence of zinc; and completing the well activity in the wellbore, such that the suppression sugar alcohol inhibits crystallization during the well activity.

Claims (9)

1. A composition for use as a suppression factor fluid, the composition comprising:

an untreated divalent brine;

greater than 5% by weight on a dry weight basis of a suppression sugar alcohol, the suppression sugar alcohol in an amount operable to achieve a suppression factor of at least 1, wherein the suppression sugar alcohol is selected from the group consisting of sorbitol, xylitol, and combinations thereof; and,

a stabilization compound comprising an amine base, the stabilization compound operable to inhibit degradation of the suppression sugar alcohol,

wherein the suppression factor fluid has a density upper limitation that is greater than the density upper limitation of the untreated divalent brine,

wherein a density of the suppression factor fluid is on the salt side of a solubility curve of the untreated divalent brine, wherein the suppression factor fluid is thermally stable.

2. The composition of claim 1 , wherein the untreated divalent brine is selected from the group consisting of calcium bromide brine, calcium chloride brine, magnesium bromide brine, magnesium chloride brine, a strontium bromide brine and combinations thereof.

3. The composition of claim 1 , wherein the composition is in the absence of zinc.

4. The composition of claim 1 further comprising a polyol, wherein the polyol is selected from the group consisting of glycerol, triglycerol, polypropylene glycol triol, polyether triols, trimethylopropane, trimethylolethane, combinations of the same.

Assignments (7)
SECURITY INTEREST Recorded May 16, 2024
From: TETRA TECHNOLOGIES, INC.; TETRA PRODUCTION TESTING SERVICES, LLC
To: BANK OF AMERICA, N.A. (AS SUCCESSOR ADMINISTRATIVE AGENT TO JPMORGAN CHASE BANK, N.A.)
Reel/Frame 067454/0317 →
RELEASE OF SECURITY INTEREST Recorded Jan 18, 2024
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TETRA TECHNOLOGIES, INC.; TETRA PRODUCTION TESTING SERVICES, LLC
Reel/Frame 066349/0878 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jan 12, 2024
From: TETRA TECHNOLOGIES, INC.
To: SILVER POINT FINANCE, LLC
Reel/Frame 066295/0384 →
RELEASE OF SECURITY INTEREST Recorded Sep 19, 2018
From: JPMORGAN CHASE BANK, NATIONAL ASSOCIATION
To: TETRA TECHNOLOGIES, INC.
Reel/Frame 047112/0478 →
SECURITY INTEREST Recorded Sep 14, 2018
From: TETRA TECHNOLOGIES, INC.; TETRA PRODUCTION TESTING SERVICES, LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 047526/0436 →
SECURITY INTEREST Recorded Sep 11, 2018
From: TETRA TECHNOLOGIES, INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 046837/0040 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 1, 2017
From: MACK, ARTHUR G.
To: TETRA TECHNOLOGIES, INC.
Reel/Frame 043153/0307 →