IP Library Granted Patent US 10,487,226
Granted Patent B2
US 10,487,226 · App. 15/472,630 · Granted Nov 26, 2019

Low odor radiation curable ink compositions

Inventors: Joshua Samuel (Ann Arbor, MI); Huilei Zhang (Ypsilanti, MI)
Assignee: ELECTRONICS FOR IMAGING, INC.
C09D11/101C09D11/102C09D11/107C09D11/322D21H19/58
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Quick Facts
Patent No.
US 10,487,226
App. No.
15/472,630
Granted
Nov 26, 2019
Kind
B2
Abstract

The present invention relates to low odor radiation curable ink compositions. The composition comprises 10-40% w/w of 4-hydrobutylacrylate, 5-25% of a urethane (math)acrylate oligomer, 10-55% of diacrylates, one or more photoinitiators, one or more additives, and one or more pigments. The composition excludes many monofunctional monomers that have distinct odor and are commonly used in an ink jet composition.

Claims (13)

1. A paper-based corrugated stock having a low odor radiation curable ink composition printed and cured on its surface, wherein the low odor radiation ink composition comprises:

25% w/w of 4-hydrobutylacrylate,

41.5% w/w of dipropylene glycol diacrylate,

8% w/w of propoxylated neopentyl glycol diacrylate,

10% w/w of aliphatic urethane diacrylate,

5% w/w of diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TPO),

5% w/w of ethyl (2,4,6-trimethylbenzoyl)phenylphosphinate (TPO-L),

2% w/w of phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide,

0.5% w/w of polyacrylate leveling agent

0.5% w/w of silicone-containing surface additive,

2% w/w pigment, and

0.5% w/w stabilizer.

2. The paper-based corrugated stock of claim 1 , wherein the ink viscosity is 8-14 cP at 45° C. or less than 30 cp at 25° C.

Assignments (9)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS Recorded Feb 3, 2025
From: ROYAL BANK OF CANADA [RESIGNING COLLATERAL AGENT]
To: GLAS USA LLC [SUCCESSOR COLLATERAL AGENT]
Reel/Frame 070097/0810 →
RELEASE OF PATENT SECURITY INTEREST Recorded Dec 3, 2024
From: CERBERUS BUSINESS FINANCE AGENCY, LLC
To: ELECTRONICS FOR IMAGING, INC.; FIERY, LLC
Reel/Frame 069477/0479 →
SECURITY INTEREST Recorded Mar 12, 2024
From: ELECTRONICS FOR IMAGING, INC.; FIERY, LLC
To: CERBERUS BUSINESS FINANCE AGENCY, LLC
Reel/Frame 066794/0315 →
RELEASE OF SECURITY INTEREST Recorded Mar 11, 2024
From: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS AGENT
To: ELECTRONICS FOR IMAGING, INC.
Reel/Frame 066793/0001 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jul 23, 2019
From: CITIBANK, N.A., AS ADMINISTRATIVE AGENT
To: ELECTRONICS FOR IMAGING, INC.
Reel/Frame 049840/0316 →
SECURITY INTEREST Recorded Jul 23, 2019
From: ELECTRONICS FOR IMAGING, INC.
To: ROYAL BANK OF CANADA
Reel/Frame 049840/0799 →
SECOND LIEN SECURITY INTEREST IN PATENT RIGHTS Recorded Jul 23, 2019
From: ELECTRONICS FOR IMAGING, INC.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS
Reel/Frame 049841/0115 →
GRANT OF SECURITY INTEREST IN PATENTS Recorded Jan 3, 2019
From: ELECTRONICS FOR IMAGING, INC.
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 048002/0135 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 3, 2017
From: SAMUEL, JOSHUA; ZHANG, HUILEI
To: ELECTRONICS FOR IMAGING, INC.
Reel/Frame 041827/0306 →
Continuity (2)
Provisional Application 62341303 · May 25, 2016
Related Publication 20170342281A1 · Nov 30, 2017