Two-stage catalyst for removal of NO
A co-catalyst system for the removal of NO x from an exhaust gas stream has a layered oxide and a spinel of formula Ni 0.15 Co 0.85 CoAlO 4 . The system converts to nitric oxide to nitrogen gas with high product specificity. The layered oxide is configured to convert NO x in the exhaust gas stream to an N 2 O intermediate, and the spinel is configured to convert the N 2 O intermediate to N 2 .
1. A catalytic converter for the removal of NO x from an exhaust gas stream operating between 350 and 550° C., the catalytic converter comprising:
an inlet configured to receive the exhaust gas stream into an enclosure;
an outlet configured to allow the exhaust gas stream to exit the enclosure; and
a co-catalyst system contained inside the enclosure, the co-catalyst system having:
a layered oxide configured for catalyzing a reduction reaction of at least one of NO and NO 2 to generate N 2 O, the layered oxide selected from the group consisting of:
LaBaCoO 4 ; and
LaBaFeO 4 ; and
a spinel having a formula, Ni x Co 1-x CoAlO 4 , configured for catalyzing a decomposition reaction of N 2 O to N 2 .
2. The catalytic converter according to claim 1 , wherein the co-catalyst system is configured as a sequential co-catalyst and the exhaust gas stream moves in a flow direction, with the layered oxide being positioned upstream of the spinel structure relative to the flow direction.
3. The catalytic converter according to claim 2 , wherein the enclosure defines first and second adjacent chambers, wherein the first chamber comprises the layered oxide and receives the exhaust gas from an upstream portion of the catalytic converter, and the second chamber comprises the spinel structure and receives the exhaust gas after passing through the first chamber.
4. The catalytic converter according to claim 3 , further comprising a separation space between the first chamber and the second chamber.
5. The catalytic converter according to claim 1 , wherein the co-catalyst system is configured as a mixed co-catalyst.
6. The catalytic converter according to claim 5 , wherein the layered oxide and the spinel occupy the same space.
7. The catalytic converter according to claim 5 , wherein the layered oxide and the spinel occupy partially overlapping regions.
8. The catalytic converter according to claim 1 , wherein the layered oxide is in a nanoparticle form, of 2 to 50 nm in diameter.
9. The catalytic converter according to claim 1 , wherein the spinel has a formula, Ni 0.15 Co 0.85 CoAlO 4 .
10. The catalytic converter according to claim 1 , wherein the spinel is in nanoparticle form, of 2 to 50 nm in diameter.