IP Library Patent Application 15477178
Patent Application
App. No. 15/477,178

ELECTRODE FOR ELECTROCHEMCAL DEVICE, METHOD FOR MANUFACTURING THE SAME, AND ELECTROCHEMCAL DEVICE INCLUDING THE SAME

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Patent No.
US None
App. No.
15/477,178
Abstract

Provided are an electrode capable of maintaining electrical conductivity during elongation and shrinkage, a method for manufacturing the same, and electrochemical device including the same.

Claims (42)

1 . An electrode for an electrochemical device, comprising

a composite film including an elastic polymer matrix and a first conductive material embedded in the elastic polymer matrix;

a conductive film disposed on the composite film and including a second conductive material; and

an electrode active material layer disposed on the conductive film,

wherein each of the first conductive material and the second conductive material are a gold nanosheet.

2 . The electrode for an electrochemical device of claim 1 , wherein the gold nanosheet has a diameter of about 10 μm to about 20 μm.

3 . The electrode for an electrochemical device of claim 1 , wherein the gold nanosheet has a thickness of about 2 nm to about 5 nm.

4 . The electrode for an electrochemical device of claim 1 , wherein the elastic polymer matrix includes one of block copolymers represented by Chemical Formulae 1 to 4:

A-block-B  [Chemical Formula 1]

A-block-B-block-C  [Chemical Formula 2]

A-block-B-block-C-block-D  [Chemical Formula 3]

wherein, in Chemical Formulae 1 to 3, A, B, C, and D are the same or different and are independently one of polystyrene, polybutadiene, polybutylene, polyethylene, polyurethane, polyisoprene, or a derivative thereof.

5 . The electrode for an electrochemical device of claim 1 , wherein the first conductive material is uniformly dispersed and embedded inside the polymer matrix.

6 . The electrode for an electrochemical device of claim 1 , wherein a weight ratio of the first conductive material/the polymer matrix in the composite film ranges from about 10/100 to about 20/100.

7 . The electrode for an electrochemical device of claim 1 , wherein the conductive film is disposed on one surface or both surfaces of the composite film.

8 . The electrode for an electrochemical device of claim 7 , wherein the electrode active material layer is disposed on one surface of the conductive film.

9 . The electrode for an electrochemical device of claim 1 , wherein the electrode active material layer includes an electrode active material having a particle diameter of about 100 nm to about 200 nm.

10 . The electrode for an electrochemical device of claim 1 , wherein the composite film has a thickness of about 20 μm to about 40 μm.

11 . The electrode for an electrochemical device of claim 1 , wherein the conductive film has a thickness of about 1 μm to about 10 μm.

12 . The electrode for an electrochemical device of claim 1 , wherein the active material layer has a thickness of about 1 μm to about 5 μm.

13 . The electrode for an electrochemical device of claim 1 , wherein the first conductive material is included in an amount of about 10 wt % to about 20 wt %, the second conductive material is included in an amount of about 30 wt % to about 40 wt %, the electrode active material layer is included in an amount of about 10 wt % to about 15 wt %, and the polymer matrix is included in a balance based on a total amount, 100 wt % of the electrode.

14 . A method for manufacturing an electrode for an electrochemical device, comprising

transferring a first conductive material on a substrate to form a first conductive film;

spin-coating an elastic polymer solution on the first conductive film to disperse the elastic polymer solution inside and outside the first conductive film;

drying the dispersed elastic polymer solution to form an elastic polymer matrix and to obtain a composite film including a first conductive material embedded inside the elastic polymer matrix;

transferring a second conductive material on the composite film to form a second conductive film; and

forming an active material layer on the second conductive film,

wherein each of the first conductive material and the second conductive material are a gold nanosheet,

15 . The method of claim 14 , wherein the spin-coating of an elastic polymer solution on the first conductive film to disperse the elastic polymer solution inside and outside the first conductive film is performed at a rotation speed of about 1000 rpm to about 2000 rpm.

16 . The method of claim 14 , wherein the drying of the dispersed elastic polymer solution to form an elastic polymer matrix and to obtain a composite film including a first conductive material embedded inside the elastic polymer matrix is performed at a temperature range of about 70° C. to about 80° C.

17 . The method of claim 14 , wherein the transferring of the second conductive material on the composite film to form a second conductive film is transferring the second conductive material on one surface or both surfaces of the composite film twice or more.

18 . The method of claim 14 , wherein the forming of the active material layer on the second conductive film is performed by spin coating, transferring, spraying, electro-spinning, a hydrothermal synthesis method, a polyol synthesis method, or a solid-phase method.

19 . The method of claim 14 , wherein the transferring of the first conductive material on a substrate to form a first conductive film is transferring the first conductive material on one surface of the substrate twice or more.

20 . An electrochemical device, comprising

a positive electrode;

a negative electrode; and

an electrolyte between the positive electrode and the negative electrode,

wherein at least one electrode of the positive electrode and the negative electrode is the electrode of claim 1 .

21 . The electrochemical device of claim 20 , wherein the electrolyte is a gel polymer electrolyte.

22 . The electrochemical device of claim 20 , wherein the electrochemical device is packed with PDMS (polydimethlysiloxane).

23 . The electrochemical device of claim 20 , wherein the electrochemical device is a rechargeable lithium battery, a sodium rechargeable battery, or a super capacitor.

24 . The electrochemical device of claim 20 , wherein the electrochemical device is applied to a driving power of a wearable apparatus or a flexible apparatus.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 3, 2017
From: PARK, SOO JIN; SONG, WOO JIN; BAE, SO HYEON; JEONG, UN YONG; SONG, JUN HYUK
To: UNIST(ULSAN NATIONAL INSTITUTE OF SCIENCE AND TECHNOLOGY); POSTECH ACADEMY-INDUSTRY FOUNDATION
Reel/Frame 041823/0405 →