Porous separator for secondary battery and manufacturing method thereof
View Patent ↗Provided is a porous separator for a secondary battery including an inorganic oxide layer formed on a porous substrate by an atomic layer deposition process, such that a thin separator having excellent heat stability, permeability and electrolyte impregnability may be provided by controlling specific conditions in the process and thicknesses of the inorganic oxide layers on a surface and inside of the porous separator.
1. A porous separator comprising:
an inorganic oxide layer formed on a porous substrate having an average pore diameter of 30 to 45 nm by an atomic layer deposition process,
wherein a thickness of the inorganic oxide layer is decreased in a direction from a surface of the porous substrate to a center thereof, and the following Relational Equations I and II are satisfied:
8≤{(10 t s +t r )× C}/ 100 [Relational Equation I]
(t s is time (sec) for injecting a metal precursor, t r is time (sec) for injecting an oxidant, and C is the number of repetitions of the atomic layer deposition process)
T h /T s ≤0.80 [Relational Equation II]
(T s is a thickness (nm) of the inorganic oxide layer on a surface of the porous separator, T h is a thickness (nm) of the inorganic oxide layer formed in internal pores at a position corresponding to ½ of a total thickness of the porous separator in a direction from the surface of the porous separator to the center of the porous separator), and
wherein the thickness of the inorganic oxide layer on the surface is 15.25 nm≤T s ≤30.0 nm and wherein a gas permeability of the porous separator is less than or equal to 525 (sec/100 cc).
2. The porous separator of claim 1 , wherein the time (sec) for injecting a metal precursor is 0.1≤t s ≤20, and the time (sec) for injecting an oxidant is 0.5≤t r ≤30.
3. The porous separator of claim 2 , wherein the number of repetitions of the atomic layer deposition process is 35 to 160.
4. The porous separator of claim 1 , wherein the thickness (nm) of the inorganic oxide layer formed in internal pores at a position corresponding to ½ of a total thickness of the porous separator in a direction from the surface of the porous separator to the center of the porous separator is 1.0≤T b ≤15.
5. The porous separator of claim 1 , wherein the porous polymer substrate has a porosity of 50 to 70%.
6. The porous separator of claim 1 , wherein the inorganic oxide layer includes one or more selected from the group consisting of SrTiO 3 , SnO 2 , CeO 2 , MgO, NiO, CaO, ZnS, ZnOS, ZrO 2 , Y 2 O 3 , SiC, CeO 2 , MgO, WO 3 , Ta 2 O 5 , RuO 2 , NiO, BaTiO 3 , Pb(Zr, Ti)O 3 (PZT), HfO 2 , SrTiO 3 , NiO, ZrO 2 , Al 2 O 3 , SiO 2 , TiO 2 , and ZnO.
7. The porous separator of claim 1 , wherein the porous substrate has a thickness of 20 to 30 μm.