Oil field treatment fluids
View Patent ↗A method of servicing a well is disclosed. The method comprises mixing ingredients to form a well servicing fluid. The ingredients comprise (i) at least one surfactant chosen from alcohol ethoxylates, C 4 to C 12 primary alcohols and ethoxylated propoxylated alcohols, (ii) a zwitterionic polymer prepared by inverse emulsion polymerization of at least one monomer A b comprising a betaine group and optionally one or more nonionic monomers B a , and (iii) a saline based aqueous solution. The well servicing fluid is introduced into a hydrocarbon well.
1. A surfactant preblend, comprising:
a first surfactant chosen from alcohol ethoxylates;
a second surfactant chosen from C 4 to C 12 primary alcohols; and
a third surfactant chosen from ethoxylated propoxylated alcohols, the first, second, and third surfactants being different from each other.
2. The preblend of claim 1 , wherein the alcohol ethoxylates are compounds of the general formula: R(OC 2 H 4 ) n OH, where R is a alkyl group and n is an integer ranging from 1 to 10.
3. The preblend of claim 1 , wherein the primary alcohols comprise a linear C 6 alcohol.
4. The preblend of claim 1 , wherein ethoxylated propoxylated alcohols are linear ethoxylated propoxylated C 8 -C 10 alcohols.
5. The preblend of claim 1 , further comprising water.
6. The preblend of claim 1 , further comprising ferric chloride.
7. The preblend of claim 1 , wherein the alcohol ethoxylates are compounds of the general formula: R(OC 2 H 4 ) n OH, where R is a alkyl group and n ranges from 1 to 10, the primary alcohols comprise a linear C 6 alcohol, and the ethoxylated propoxylated alcohols are linear ethoxylated propoxylated C 8 -C 10 alcohols.
8. The preblend of claim 1 , comprising 2-20% by weight of the first surfactant, 2-20% by weight of the second surfactant, and 50-90% by weight of the third surfactant.
9. A well servicing fluid formed from ingredients comprising:
a first surfactant chosen from alcohol ethoxylates;
a second surfactant chosen from C 4 to C 12 primary alcohols;
a third surfactant chosen from ethoxylated propoxylated alcohols, the first, second, and third surfactants being different from each other;
wherein the ingredients comprise a surfactant preblend containing the first surfactant, the second surfactant, and the third surfactant blended prior to mixing of the ingredients that form the well servicing fluid, and wherein the surfactant preblend comprises 2-20% by weight of the first surfactant, 2-20% by weight of the second surfactant, and 50-90% by weight of the third surfactant;
a zwitterionic polymer containing at least one monomer A b comprising a betaine group and optionally one or more nonionic monomers B a , wherein the ingredients comprise an inverse emulsion with an aqueous phase containing the zwitterionic polymer, the aqueous phase being dispersed in the form of droplets in a hydrophobic external phase, and wherein the ingredients comprise 0.033 to 33 weight % of the inverse emulsion; and
a saline based aqueous solution.
10. The fluid of claim 9 , wherein the alcohol ethoxylates are compounds of the general formula: R(OC 2 H 4 ) n OH, where R is a alkyl group and n ranges from about 1 to about 10.
11. The fluid of claim 9 , wherein the primary alcohols comprise a linear C 6 alcohol.
12. The fluid of claim 9 , wherein the ethoxylated propoxylated alcohols are linear ethoxylated propoxylated C 8 -C 10 alcohols.
13. The fluid of claim 9 , wherein the alcohol ethoxylates are compounds of the general formula: R(OC 2 H 4 ) n OH, where R is a alkyl group and n ranges from 1 to 10, the primary alcohols comprise a linear C 6 alcohol, and the ethoxylated propoxylated alcohols are linear ethoxylated propoxylated C 8 -C 10 alcohols.
14. The fluid of claim 9 , wherein the zwitterionic polymer exhibits an intrinsic viscosity of about 320 ml/g or greater in a 20% by weight aqueous NaCl solution.
15. The fluid of claim 9 , wherein the saline based aqueous solution exhibits a density of at least 10.5 ppg.