IP Library Granted Patent US 10,017,624
Granted Patent B2
US 10,017,624 · App. 15/490,120 · Granted Jul 10, 2018

Rheology modifying agents for slurries

Inventors: Jasbir S. Gill (Naperville, IL); Tzu Y. Chen (Wheaton, IL); Reagan Faith (Cold Lake, CA); Adam Coulterman (Cold Lake, CA)
Assignee: ECOLAB USA INC.
C08K3/22C02F5/12C04B2/00C02F2101/10C02F2103/02C02F2103/10C08K2003/222
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Quick Facts
Patent No.
US 10,017,624
App. No.
15/490,120
Granted
Jul 10, 2018
Kind
B2
Abstract

Rheology modifying agents and methods of modifying the rheology of a slurry are disclosed, in addition to methods for the prevention of fouling. The slurry can be a lime slurry or a magnesium oxide slurry. The rheology modifying agent can be a low molecular weight anionic polymer, a high molecular weight polymer, a mixture of a low molecular weight anionic polymer and a high molecular weight polymer, a mixture of a high molecular weight polymer and a chelating agent, and a mixture of a chelating agent, a high molecular weight polymer, and a low molecular weight anionic polymer.

Claims (23)

1. A method of modifying rheology of a magnesium oxide slurry comprising:

adding a rheology modifying agent to the magnesium oxide slurry,

wherein the rheology modifying agent is a composition comprising a high molecular weight polymer having a number average molecular weight of greater than about 200,000 comprising hydrolyzed polyacrylamide, a chelating agent, polymaleic acid, and a copolymer comprising acrylic acid (AA) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS).

2. The method of claim 1 , wherein the rheology modifying agent is added to the magnesium oxide slurry in an amount that is selected from the group consisting of about 10 ppm to about 300 ppm and about 30 ppm to about 250 ppm.

3. The method of claim 1 , wherein the high molecular weight polymer has a number average molecular weight of greater than 1,000,000.

4. The method of claim 1 , wherein the composition comprises about 2% of the hydrolyzed polyacrylamide and about 0.5% ethylenediaminetetraacetic acid.

5. The method of claim 1 , wherein the chelating agent is selected from the group consisting of ethylenediaminetetraacetic acid, citric acid, a ligno sulfonate, dimercaprol (2,3-dimercapto-1-propanol), porphine, and any combination thereof.

6. A method of modifying rheology of a magnesium oxide slurry, comprising:

adding a rheology modifying agent to the magnesium oxide slurry, wherein the rheology modifying agent comprises:

a high molecular weight polymer and

a low molecular weight anionic polymer

wherein the low molecular weight anionic polymer has a number average molecular weight of less than about 20,000, and the high molecular weight polymer has a number average molecular weight of greater than about 200,000,

wherein the low molecular weight anionic polymer is a copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid.

7. The method of claim 6 , wherein the high molecular weight polymer comprises acrylamide.

8. The method of claim 6 , wherein the high molecular weight polymer is selected from a copolymer of acrylic acid and acrylamide, a polymer of hydrolyzed polyacrylamide, and any combination thereof.

9. The method of claim 8 , wherein the high molecular weight polymer comprises a copolymer of from about 1 mol % to about 15 mol % acrylic acid and about 99 mol % to about 85 mol % acrylamide.

10. The method of claim 6 , wherein the rheology modifying agent is added to the magnesium oxide slurry in an amount that is selected from the group consisting of about 10 ppm to about 300 ppm and about 30 ppm to about 250 ppm.

11. A method of modifying rheology of a magnesium oxide slurry, comprising:

adding a rheology modifying agent to the magnesium oxide slurry, wherein the rheology modifying agent comprises a low molecular weight anionic polymer selected from polymaleic acid; a copolymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid; a terpolymer of acrylic acid, acrylamide, and sulfonated acrylamide; and any combination thereof, wherein the low molecular weight anionic polymer has a number average molecular weight of less than about 20,000.

12. The method of claim 11 , wherein the rheology modifying agent is added to the magnesium oxide slurry in an amount that is selected from the group consisting of about 10 ppm to about 300 ppm and about 30 ppm to about 250 ppm.

13. The method of claim 11 , wherein the low molecular weight anionic polymer is a terpolymer comprising about 40% acrylic acid, about 20% acrylamide, and about 40% sulfonated acrylamide.

14. A method of modifying rheology of a magnesium oxide slurry comprising:

adding a rheology modifying agent to the magnesium oxide slurry, wherein the rheology modifying agent is a composition comprising about 2% hydrolyzed polyacrylamide and about 0.5% ethylenediaminetetraacetic acid.

Assignments (8)
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jul 17, 2025
From: JPMORGAN CHASE BANK, N.A.
To: CHAMPIONX LLC; APERGY ESP SYSTEMS, LLC; APERGY BMCS ACQUISITION CORP; HARBISON-FISCHER, INC.; NORRIS RODS, INC.,; NORRIS RODS, INC.,; NORRISEAL-WELLMARK, INC.; PCS FERGUSON, INC.; QUARTZDYNE, INC.; US SYNTHETIC CORPORATION
Reel/Frame 072004/0019 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 7, 2023
From: CHAMPIONX USA INC.
To: CHAMPIONX LLC
Reel/Frame 065799/0403 →
RELEASE OF SECURITY INTEREST Recorded Jun 7, 2022
From: BANK OF AMERICA, N.A.
To: CHAMPIONX USA INC.
Reel/Frame 060304/0267 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 28, 2021
From: ECOLAB USA INC.
To: CHAMPIONX USA INC.
Reel/Frame 055143/0832 →
SECURITY INTEREST Recorded Jun 5, 2020
From: CHAMPIONX USA INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 053250/0001 →
SECURITY INTEREST Recorded Jun 5, 2020
From: CHAMPIONX USA INC.
To: BANK OF AMERICA, N.A.
Reel/Frame 052848/0368 →
ANNUAL RENEWAL SHOWING ADDRESS CHANGE Recorded May 30, 2018
From: ECOLAB USA INC.
To: ECOLAB USA INC.
Reel/Frame 046269/0675 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 8, 2017
From: GILL, JASBIR S.; CHEN, TZU Y.; FAITH, REAGAN; COULTERMAN, ADAM
To: ECOLAB USA INC.
Reel/Frame 042656/0335 →
Continuity (2)
Division 13875061 · May 1, 2013
Related Publication 20170218169A1 · Aug 3, 2017