Processes for the selective separation of iron and aluminium
This disclosure relates to a process for selectively extracting Fe(III) ions from an aqueous feedstock containing Fe(III) ions and non-ferric ions. The process comprises contacting the feedstock with an organic phase comprising a phosphonium salt or ammonium salt ionic liquid under liquid-liquid extraction conditions for a time sufficient to allow transfer of at least some of the Fe(III) ions from the feedstock to the organic phase to provide an Fe(III) ion laden organic phase and an Fe(III) depleted feedstock, and separating the Fe(III) ion laden organic phase from the Fe(III) depleted feedstock.
1. A process for selectively removing Fe(III) ions from a coal gangue leachate, the process comprising contacting the leachate with an organic phase comprising a phosphonium salt or ammonium salt ionic liquid under liquid-liquid extraction conditions for a time sufficient to allow transfer of at least some of the Fe(III) ions from the leachate to the organic phase to provide a Fe(III) ion laden organic phase and an Fe(III) depleted leachate, and separating the Fe(III) ion laden organic phase from the Fe(III) depleted leachate.
2. The process according to claim 1 , wherein the organic phase is free of an extraneous organic extractant.
3. The process according to claim 1 , wherein the organic phase is free of a solvent other than the phosphonium salt or ammonium salt ionic liquid.
4. The process according to claim 1 , wherein the organic phase consists essentially of the phosphonium salt or ammonium salt ionic liquid.
5. The process according to claim 1 , wherein the process further comprises treating the coal gangue leachate to increase the concentration of inorganic anions therein prior to contact with the organic phase.
6. The process according to claim 5 , wherein the inorganic anion is a halide ion.
7. The process according to claim 6 , wherein the halide ion is selected from the group consisting of iodide, bromide, chloride, and fluoride.
8. The process according to claim 7 , wherein the halide ion is chloride.
9. The process according to claim 5 , wherein the step of treating the coal gangue leachate to increase the concentration of inorganic anions comprises adding a source of inorganic anions to the aqueous feedstock.
10. The process according to claim 1 , wherein the coal gangue leachate comprises non-ferric ions selected from one or more of the group of ions consisting of aluminium, magnesium, calcium and potassium ions and the Fe(III) ions are selectively removed from the coal gangue leachate in the process.
11. A process for recovering high purity aluminium chloride from coal gangue, the process comprising leaching the coal gangue to provide a coal gangue leachate, contacting the leachate with an organic phase comprising a phosphonium salt or ammonium salt ionic liquid under liquid-liquid extraction conditions for a time sufficient to allow selective transfer of at least some of Fe(III) ions from the leachate to the organic phase to provide a Fe(III) ion laden organic phase and an Fe(III) depleted leachate, separating the Fe(III) ion laden organic phase from the Fe(III) depleted leachate, and recovering aluminium chloride from the Fe(III) depleted leachate.
12. The process according to claim 11 , wherein the organic phase is free of an extraneous organic extractant.
13. The process according to claim 11 , wherein the organic phase is free of a solvent other than the phosphonium salt or ammonium salt ionic liquid.
14. The process according to claim 11 , wherein the organic phase consists essentially of the phosphonium salt or ammonium salt ionic liquid.
15. The process according to claim 11 , wherein the process further comprises treating the coal gangue leachate to increase the concentration of inorganic anions therein prior to contact with the organic phase.
16. The process according to claim 15 , wherein the inorganic anion is a halide ion.
17. The process according to claim 16 , wherein the halide ion is selected from the group consisting of iodide, bromide, chloride, and fluoride.
18. The process according to claim 17 , wherein the halide ion is chloride.
19. The process according to claim 15 , wherein the step of treating coal gangue leachate to increase the concentration of inorganic anions comprises adding a source of inorganic anions to the aqueous feedstock.
20. The process according to claim 11 , wherein the coal gangue leachate comprises non-ferric ions selected from one or more of the group of ions consisting of aluminium, magnesium, calcium and potassium ions and the Fe(III) ions are selectively removed from the coal gangue leachate in the process.