Organic electroluminescent compounds and organic electroluminescent devices comprising the same
View Patent ↗The present invention relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. By using the organic electroluminescent compound of the present invention, it is possible to produce an organic electroluminescent device having low driving voltage and excellent luminous efficiency such as current efficiency and power efficiency, emitting color of high purity, and having improved lifespan.
1. An organic electroluminescent compound represented by the following formula 1:
wherein
W represents O or S;
X represents O, S or NR 11 ;
R 1 to R 11 each independently represent hydrogen, deuterium, a halogen, a cyano group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C6-C30)aryl group, a substituted or unsubstituted 3- to 30-membered heteroaryl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C1-C30)alkoxy group, a substituted or unsubstituted tri(C1-C30)alkylsilyl group, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl group, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl group, a substituted or unsubstituted tri(C6-C30)arylsilyl group, a substituted or unsubstituted mono- or di-(C1-C30)alkylamino group, a substituted or unsubstituted mono- or di-(C6-C30)arylamino group, or a substituted or unsubstituted (C1-C30)alkyl(C6-C30)arylamino group; or are linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or polycyclic, (C3-C30) alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one hetero atom selected from nitrogen, oxygen, and sulfur; and
the heteroaryl group contains at least one hetero atom selected from B, N, O, S, Si, and P.
2. The organic electroluminescent compound according to claim 1 , wherein the substituents of the substituted alkyl group, the substituted aryl group, the substituted heteroaryl group, the substituted cycloalkyl group, the substituted alkoxy group, the substituted trialkylsilyl group, the substituted dialkylarylsilyl group, the substituted alkyldiarylsilyl group, the substituted triarylsilyl group, the substituted mono- or di-alkylamino group, the substituted mono- or di-arylamino group, the substituted alkylarylamino group, and the substituted mono- or polycyclic, alicyclic or aromatic ring in R 1 to R 11 each independently are at least one selected from the group consisting of deuterium, a halogen, a cyano, a carboxyl, a nitro, a hydroxyl, a (C1-C30)alkyl, a halo(C1-C30)alkyl, a (C1-C30)alkoxy, a (C1-C30)alkylthio, a (C3-C30)cycloalkyl, a 3- to 7-membered heterocycloalkyl, a (C6-C30)aryloxy, a (C6-C30)arylthio, a 3- to 30-membered heteroaryl unsubstituted or substituted with a (C6-C30)aryl, a (C6-C30)aryl unsubstituted or substituted with a 3- to 30-membered heteroaryl, a tri(C1-C30)alkylsilyl, a tri(C6-C30)arylsilyl, a di(C1-C30)alkyl(C6-C30)arylsilyl, a (C1-C30)alkyldi(C6-C30)arylsilyl, an amino, a mono- or di-(C1-C30)alkylamino, a mono- or di-(C6-C30)arylamino, a (C1-C30)alkyl(C6-C30)arylamino, a (C1-C30)alkylcarbonyl, a (C1-C30)alkoxycarbonyl, a (C6-C30)arylcarbonyl, a di(C6-C30)arylboronyl, a di(C1-C30)alkylboronyl, a (C1-C30)alkyl(C6-C30)arylboronyl, a (C6-C30)aryl(C1-C30)alkyl, and a (C1-C30)alkyl(C6-C30)aryl.
3. The organic electroluminescent compound according to claim 1 , wherein
W represents O or S;
X represents O, S or NR 11 ;
R 1 to R 10 each independently represent hydrogen, or a substituted or unsubstituted (C6-C18)aryl group; or are linked to an adjacent substituent(s) to form a substituted or unsubstituted, mono- or polycyclic (C6-C20) alicyclic or aromatic ring; and
R 11 represents a substituted or unsubstituted (C6-C18)aryl group, or a substituted or unsubstituted 5- to 20-membered heteroaryl group.
4. The organic electroluminescent compound according to claim 1 , wherein
W represents O or S;
X represents O, S or NR 11 ;
R 1 to R 10 each independently represent hydrogen, or a (C6-C18)aryl unsubstituted or substituted with a (C6-C18)aryl group or a 5- to 20-membered heteroaryl group; or are linked to an adjacent substituent(s) to form a mono- or polycyclic (C6-C20) aromatic ring unsubstituted or substituted with a (C6-C12)aryl group; and
R 11 represents a (C6-C18)aryl group which is unsubstituted or substituted with a (C6-C18)aryl group or a 5- to 20-membered heteroaryl group, or a 5- to 20-membered heteroaryl group which is unsubstituted or substituted with a (C6-C18)aryl group or a 5- to 20-membered heteroaryl group.
5. The organic electroluminescent compound according to claim 1 , wherein the compound represented by formula 1 is selected from the group consisting of:
6. An organic electroluminescent device comprising the compound according to claim 1 .