Method for producing a hydrophobic heat-insulating molded body
View Patent ↗Process for the production of a hydrophobic thermal-insulation moulding, where a hydrophilic thermal-insulation moulding is brought into contact with a hydrophobizing agent in vapour form with formation of a thermal-insulation moulding coated with hydrophobizing agent, and this is then subjected to a press process and during the press process and/or after the press process is reacted with the hydrophobizing agent with formation of the hydrophobic thermal-insulation moulding, where a) the density of the hydrophobic thermal-insulation moulding after the press process and after the reaction with the hydrophobizing agent is from 100 to 250 kg/m 3 , and b) the density of the hydrophilic thermal-insulation moulding on contact with the hydrophobizing agent is from 50% to less than 100% of the density of the hydrophobic thermal-insulation moulding.
1. A process for producing a hydrophobic thermal-insulation molding, comprising:
contacting a hydrophilic thermal-insulation molding
with a hydrophobizing agent in the form of vapor, thereby forming a thermal-insulation molding coated with the hydrophobizing agent;
pressing the thermal-insulation molding coated with the hydrophobizing agent; and
during and/or after the pressing, heating the thermal-insulation molding coated with the hydrophobizing agent, thereby forming the hydrophobic thermal-insulation moulding molding,
wherein
the hydrophilic thermal-insulation molding comprises a thermal-insulation mixture comprising a fine-particle silica, IR opacifier and fiber material,
the contacting, the pressing, and the heating take place between two gas-permeable moving belts of a press,
a density of the hydrophobic thermal-insulation molding the heating is from 100 to 250 kg/m 3 , and
a density of the hydrophilic thermal-insulation molding contacted with the hydrophobizing agent is from 50% to less than 100% of the density of the hydrophobic thermal-insulation molding.
2. The process according to claim 1 , wherein in the contacting, a contact temperature T contact is from −30° C. to 150° C.
3. The process according to claim 1 , wherein in the heating, a reaction temperature T reaction is from 50° C. to 500° C.
4. The process according to claim 1 , wherein a contact time during the contacting and a heating time during the heating are in each case from 1 minute to 1 hour.
5. The process according to claim 1 , wherein the contacting and the heating take place in a chamber, and
wherein the hydrophobizing agent is introduced into the chamber until a pressure difference Δp is ≥20 mbar, wherein Δp=p 2 −p 1 , and p 1 =pressure in the chamber before the introduction of the hydrophobizing agent, and p 2 =pressure in the chamber at which the introduction of the hydrophobizing agent is stopped.
6. The process according to claim 1 , wherein the fine-particle silica is a fumed silica.
7. The process according to claim 1 , wherein a proportion of the fine-particle silica, based on the thermal-insulation mixture, is from 70 to 95% by weight.
8. The process according to claim 1 , wherein a proportion of the IR opacifier, based on the thermal-insulation mixture, is from 2 to 20% by weight.
9. The process according to claim 1 , wherein a proportion of the fiber material, based on the thermal-insulation mixture, is from 3 to 10% by weight.
10. The process according to claim 1 , wherein the hydrophobizing agent is at least one organosilicon compound selected from the group consisting of R n —Si—X 4-n and R 3 Si—Y—SiR 3 , wherein n=from 1 to 3; R═—CH 3 or —C 2 H 5 ; X═—Cl, —Br, —OCH 3 , —OC 2 H 5 , or —OC 3 H 8 ; and Y═NH or O.
11. The process according to claim 1 , wherein a proportion of the hydrophobizing agent, based on the hydrophilic thermal-insulation molding, is from 0.5 to 10% by weight.
12. The process according to claim 1 , which is carried out continuously.
13. The process according to claim 2 , wherein in the heating, a reaction temperature T reaction is from 50° C. to 500° C.
14. The process according to claim 2 , wherein a contact time during the contacting and a heating time during the heating are in each case from 1 minute to 1 hour.
15. The process according to claim 3 , wherein a contact time during the contacting and a heating time during the heating are in each case from 1 minute to 1 hour.
16. The process according to claim 2 , wherein the contacting and the heating takes place in a chamber, and
wherein the hydrophobizing agent is introduced into the chamber until a pressure difference Δp is ≥20 mbar, wherein Δp=p 2 −p 1 , and p 1 =pressure in the chamber before the introduction of the hydrophobizing agent, p 2 =pressure in the chamber at which the introduction of the hydrophobizing agent is stopped.
17. The process according to claim 3 , wherein the contacting and the heating takes place in a chamber, and
wherein the hydrophobizing agent is introduced into the chamber until a pressure difference Δp is ≥20 mbar, wherein Δp=p 2 −p 1 , and p 1 =pressure in the chamber before the introduction of the hydrophobizing agent, p 2 =pressure in the chamber at which the introduction of the hydrophobizing agent is stopped.
18. The process according to claim 13 , wherein the contacting and the heating takes place in a chamber, and
wherein the hydrophobizing agent is introduced into the chamber until a pressure difference Δp is ≥20 mbar, wherein Δp=p 2 −p 1 , and p 1 =pressure in the chamber before the introduction of the hydrophobizing agent, p 2 =pressure in the chamber at which the introduction of the hydrophobizing agent is stopped.
19. The process according to claim 2 , wherein the fine-particle silica is a fumed silica.
20. The process according to claim 3 , wherein the fine-particle silica is a fumed silica.