Method for reducing or preventing the degradation of an antifouling layer or an optical article
The invention concerns a method for producing an optical article suitable for edging comprising an antifouling layer on which there is deposited a temporary overlayer for assisting with edging, comprising: depositing, on an optical substrate, an organic antifouling layer comprising at least a fluorinated polymer compound comprising hydrolysable functions; and depositing, on the antifouling layer, an overlayer for assisting with edging, of mineral nature, comprising one or more metal fluorides and/or one or more metal oxides or hydroxides; method characterised in that it further comprises a step of accelerated grafting of the antifouling layer chosen from: (a) a treatment of the deposited antifouling layer in a humid atmosphere of the deposited antifouling layer and (b) a catalytic treatment in the acidic or basic vapour phase of the deposited antifouling layer.
1. A process for manufacturing an optical article fit for edging, comprising an antifouling layer on which is deposited a temporary top coat that facilitates edging, comprising:
(a) the deposition, on an optical substrate, of a single organic antifouling layer comprising at least one fluoropolymer compound comprising hydrolyzable functions; and
(b) the deposition, on the antifouling layer, of a top coat that facilitates edging, of mineral nature, comprising one or more metal fluorides and/or one or more metal oxides or hydroxides;
the process further comprising, after the deposition of the antifouling layer and prior to the deposition of the top coat that facilitates edging, a step of accelerated grafting of the antifouling layer selected from:
(a) a treatment in a wet atmosphere of the antifouling layer;
(b) a catalytic treatment in acidic or basic vapor phase of the deposited antifouling layer.
2. The process of claim 1 , wherein the accelerated grafting treatment is a treatment in a wet atmosphere that is carried out in an air atmosphere at atmospheric pressure.
3. The process of claim 2 , wherein the treatment in an air atmosphere at atmospheric pressure is carried out at a degree of relative humidity of from 45% to 95% and a temperature of from 15° C. to 75° C.
4. The process of claim 2 , wherein the duration of the air atmosphere treatment is from 1 to 7 days.
5. The process of claim 4 , wherein the duration of the air atmosphere treatment is from 3 to 5 days.
6. The process of claim 1 , wherein the depositions of the antifouling layer and of the top coat that facilitates edging are carried out under vacuum and the step of accelerated grafting of the antifouling layer is a treatment in a wet atmosphere of the antifouling layer carried out by a step of returning to an air atmosphere at atmospheric pressure between the deposition of the antifouling layer and the deposition of the top coat that facilitates edging.
7. The process of claim 1 , wherein the depositions of the antifouling layer and of the top coat that facilitates edging are carried out under vacuum in a vacuum chamber and the step of accelerated grafting of the antifouling layer is a treatment in a wet atmosphere of the antifouling layer carried out by release of water into the vacuum chamber, without a step of returning to atmospheric pressure between the deposition of the antifouling layer and the deposition of the top coat that facilitates edging.
8. The process of claim 7 , wherein the vacuum chamber comprises a cryogenic trap and the release of water is carried out by de-icing said cryogenic trap.
9. The process of claim 1 , wherein the hydrolyzable functions are alkoxysilane functions.
10. The process of claim 1 , wherein the hydrolyzable functions are present at only one end of the chain of the fluoropolymer compound.
11. The process of claim 1 , wherein the acid or basic vapor phase is air saturated with HCl or NH 3 with its liquid phase in aqueous solution at atmospheric pressure and at ambient temperature (18-25° C.).
12. The process of claim 11 , wherein the acidic aqueous solution is a 37% saturated HCl aqueous solution.
13. The process of claim 1 , wherein the temporary top coat consists of a metal fluoride.
14. The process of claim 13 , wherein the temporary top coat consists of MgF 2 .