Organic light-emitting diode
The invention relates to an organic light-emitting diode ( 1000 ) with an organic layer sequence ( 100 ). The organic layer sequence ( 100 ) comprises a first organic emitter layer ( 1 ) for generating electromagnetic radiation of a first wavelength range ( 10 ) and a second organic emitter layer ( 2 ) for generating electromagnetic radiation of a second wavelength range ( 20 ). A charge carrier generation layer sequence ( 33 ), CGL for short, is arranged between the first ( 1 ) and the second ( 2 ) emitter layer, and the first emitter layer ( 1 ) and the second emitter layer ( 2 ) are electrically connected in series via said CGL. The CGL ( 33 ) additionally has a converter material which converts the radiation of the first ( 10 ) and/or the second ( 20 ) wavelength range at least partially into radiation of a third wavelength range ( 30 ). In this manner, the organic light-emitting diode ( 1000 ) can emit mixed light with components of the first ( 10 ), second ( 20 ), and third ( 30 ) wavelength range.
1. An organic light-emitting diode comprising an organic layer sequence, with: a first organic emitter layer for generating electromagnetic radiation of a first wavelength range, a second organic emitter layer for generating electromagnetic radiation of a second wavelength range, a charge carrier generation layer sequence arranged between the first and the second organic emitter layers, via which the first emitter layer and the second emitter layer are electrically connected in series, wherein
the charge carrier generation layer sequence comprises a converter material, which converts radiation of the first and/or the second wavelength range at least partially into radiation of a third wavelength range, so that the organic light-emitting diode emits mixed light with portions of the first, second and the third wavelength range.
2. The organic light-emitting diode according to claim 1 ,
wherein the charge carrier generation layer sequence comprises at least one n-conducting organic layer, at least one p-conducting organic layer and a conversion layer, wherein the converter material is introduced into the conversion layer,
wherein the conversion layer is arranged between the n-conducting layer and the p-conducting layer and separates the n-conducting layer and the p-conducting layer from one another.
3. The organic light-emitting diode according to claim 1 ,
wherein
the converter material in the conversion layer is embedded in a matrix material and
the concentration of the converter material in the conversion layer for thicknesses of the conversion layer of at least 1 nm ranges from between including 50/d %·nm and 90/d %·nm , d being the thickness of the conversion layer in the unit of nanometers.
4. The organic light-emitting diode according to claim 2 ,
wherein the conversion layer is completely formed from the converter material.
5. The organic light-emitting diode according to claim 1 ,
wherein the charge carrier generation layer sequence is adapted to convert at least 10% of the electromagnetic radiation of the first and/or second wavelength range impinging on it into radiation of the third wavelength range.
6. The organic light-emitting diode according to claim 1 ,
wherein the first organic emitter layer emits light in the blue spectral range, the second organic emitter layer emits light in the green spectral range and the converter material converts the blue light and/or the green light at least partially into red light during operation.
7. The organic light-emitting diode according to claim 1 , wherein the charge carrier generation layer sequence per se and the converter material contained therein are not electroluminescent.
8. The organic light-emitting diode according to claim 1 ,
wherein the converter material is formed of or comprises one of the following materials:
fluoresceins, cumarines, rhodamines, stilbene derivatives, porphyrine derivatives, phthalocyanine derivatives.
9. The organic light-emitting diode according to claim 1 ,
wherein molecules of the converter material have a preferred direction or preferred plane during light emission, and wherein the molecules of the converter material are introduced into the organic layer sequence in a rectified manner, so that a preferred emission direction of the converter material is set in a targeted manner.
10. The organic light-emitting diode according to claim 1 ,
wherein the converter material comprises quantum dots comprising GaAs and/or GaP and/or GaN and/or sulfides and/or selenides.
11. The organic light-emitting diode according to claim 2 ,
wherein the conversion layer has a layer thickness d between including 1 nm and 20 nm.
12. The organic light-emitting diode according to claim 1 ,
wherein the converter material for the conversion of light is a singlet emitter, which generates radiation of the third wavelength range by a transition from a singlet state into an assigned electric basic state.
13. The organic light-emitting diode according to claim 1 ,
wherein the organic light-emitting diode is a bi-directionally differently-emitting light-emitting diode, which emits radiation in both directions perpendicular to a main extension plane of the charge carrier generation layer sequence,
wherein in the one direction, warm-white light with a color temperature of at most 3,500 K is emitted and wherein in the other, opposite direction, cold-white light with a color temperature of at least 4,000 K is emitted.
14. The organic light-emitting diode according to claim 1 ,
wherein one or more organic layers in the layer sequence or layers bordering the layer sequence comprise scattering particles, which comprise at least one of the following materials or are formed thereof: titanium oxide, aluminum oxide, yttrium oxide, silicon oxide.
15. The organic light-emitting diode according to claim 1 ,
wherein at least one transparent electrode bordering the organic layer sequence comprises scattering particles and/or surface structures for improved light out-coupling.
16. The organic light-emitting diode according to claim 1 , wherein no complete interruptions of the organic layer sequence are arranged between the first organic emitter layer and the second emitter layer.