IP Library Granted Patent US 10,669,401
Granted Patent B2
US 10,669,401 · App. 15/503,238 · Granted Jun 2, 2020

Plastic-coated mercaptosilane/wax mixture

Inventors: Caren Röben (Köln, DE); Andrea Korch (Köln, DE); Sabine Leick (Bruchköbel, DE); Kathrin Kunowa (Joplin, MO); Juri Tschernjaew (Aschaffenburg, DE)
Assignee: EVONIK OPERATIONS GMBH
C08K5/54B60C1/00B60C1/0016C08J3/20C08K5/548C08L9/06C08L21/00C08L23/06C08J2391/06C08K5/37C08K5/3725C08K5/5415C08K5/5419C08L9/00C08L23/04C08L23/0853C08L23/10C08L23/12C08L2207/06C08L2666/02C08L2666/44
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Quick Facts
Patent No.
US 10,669,401
App. No.
15/503,238
Granted
Jun 2, 2020
Kind
B2
Abstract

The invention relates to a plastics-covered mercaptosilane-wax mixture, where the plastic of the plastics covering is selected from the group of polypropylene, polyethylene, ethylene-vinyl acetate copolymer and mixtures of the abovementioned plastics with melting point from 70 to 170° C., and the mercaptosilane-wax mixture comprises at least one mercaptosilane of the general formula I and at least one wax with congealing point from 30 to 160° C. The plastics-covered mercaptosilane-wax mixture can be used in rubber mixtures.

Claims (17)

1. A sealed plastics-covered mercaptosilane-wax mixture, comprising a plastics covering, selected from the group consisting of polypropylene, polyethylene, ethylene-vinyl acetate copolymer, and mixtures of the above mentioned plastics with melting point from 70 to 170° C., and mercaptosilane-wax mixture comprises at least one mercaptosilane, a monomer, of the general formula I

where R 1 is an alkyl polyether group —O—(R 5 —O) m —R 6 , where R 5 is identical or different and is a branched or unbranched, saturated or unsaturated, aliphatic divalent C1-C30 hydrocarbon group, m is on average from 1 to 30, and R 6 is composed of at least 1 C atom and is an unsubstituted or substituted, branched or unbranched monovalent alkyl, alkenyl, aryl or aralkyl group,

R 2 is identical or different and is an R 1 , C1-C12-alkyl or R 7 O group, where R 7 is H, methyl, ethyl, propyl, C9-C30 branched or unbranched monovalent alkyl, alkenyl, aryl, or aralkyl group or (R 8 ) 3 Si group, where R 8 is C1-C30 branched or unbranched alkyl or alkenyl group,

R 3 is a branched or unbranched, saturated or unsaturated, aliphatic, aromatic or mixed aliphatic/aromatic divalent C1-C30 hydrocarbon group and

R 4 is H, CN or (C═O)—R 9 , where R 9 is a branched or unbranched, saturated or unsaturated, aliphatic, aromatic or mixed aliphatic/aromatic monovalent C1-C30 hydrocarbon group, and at least one wax with congealing point from 30 to 160° C.,

wherein the plastics-covering has a thickness of the plastics covering is from 10 to 3000 μm and is a sachet and the mercaptosilane-wax mixture has a ratio by weight of mercaptosilane of general formula I to wax from 10:90 to 95:5 and, wherein the plastic has an average molar mass of the plastic of the plastics covering is from 50 000 to 1 000 000 g/mol.

2. The plastics-covered mercaptosilane-wax mixture according to claim 1 , wherein the mercaptosilane-wax mixture comprises a mixture of mercaptosilanes of the general formula I.

3. The plastics-covered mercaptosilane-wax mixture according to claim 2 , wherein the mixture of mercaptosilanes of the general formula (I) comprises and,

4. A process for the production of the sealed plastics-covered mercaptosilane-wax mixture according to claim 1 , comprising mixing of at least one mercaptosilane of the general formula I with at least one wax with congealing point from 30 to 160° C. to form a mercaptosilane-wax mixture having a ratio by weight of mercaptosilane of general formula I to wax from 55:45 to 90:10, and charging the mercaptosilane-wax mixture to a plastics sachet, where the plastic of the sachet is selected from the group of polypropylene, polyethylene, ethylene-vinyl acetate copolymer and mixtures of the abovementioned plastics with melting point from 70 to 170° C., and sealing the plastics sachet.

5. The process according to claim 4 , wherein mixing includes a process involving a temperature-controllable kneading, stirring, or mixing assembly.

6. The process according to claim 4 , wherein mixing occurs at temperatures of from 30 to 160° C.

7. The process according to claim 4 , wherein charging takes place at temperatures of from 30 to 160° C.

8. A method for the production of rubber mixtures comprising: introducing the plastics-covered mercaptosilane-wax mixture according to claim 1 to a mixture having at least one rubber.

9. A rubber mixture comprising:

(A) at least one rubber,

(B) at least one filler, and

(C) at least one sealed plastics-covered mercaptosilane-wax mixture according to claim 1 .

Assignments (2)
CHANGE OF NAME Recorded Mar 29, 2020
From: EVONIK DEGUSSA GMBH
To: EVONIK OPERATIONS GMBH
Reel/Frame 052254/0052 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 22, 2017
From: RÖBEN, CAREN; KORCH, ANDREA; LEICK, SABINE; KUNOWA, KATHRIN; TSCHERNJAEW, JURI
To: EVONIK DEGUSSA GMBH
Reel/Frame 042942/0574 →
Priority Claims (1)
EP 14180912 · Aug 14, 2014 · regional
Continuity (1)
Related Publication 20170233552A1 · Aug 17, 2017