Paper composite, packaging material, and production method of paper composite
The paper composite contains: a paper substrate having an air permeation resistance of 1,000 sec or less and bulk density of from 0.5 to 1.0 g/cm 3 ; and a greaseproof layer on at least one side thereof, the greaseproof layer containing an ethylene-vinyl alcohol polymer (A) and a cationic fluorine-containing polymer (B) having two specific constitutional units. A content of the copolymer (B) in the greaseproof layer is from 5 to 50 parts by mass with respect to 100 parts by mass of the polymer (A), an amount of the greaseproof layer on dry mass basis is from 0.1 to 3.0 g/m 2 , and a water vapor permeability of the paper composite is 1,000 g/m 2 ·24 h or greater.
1. A paper composite comprising: a paper substrate having an air permeation resistance of 1,000 sec or less and a bulk density of 0.5 g/cm 3 or greater and 1.0 g/cm 3 or less; and a greaseproof layer formed on at least one surface side of the paper substrate, wherein
the greaseproof layer comprises:
a vinyl alcohol polymer (A) having a content of an ethylene unit of 2 mol % or greater and 10 mol % or less, a viscosity average degree of polymerization of 300 or greater and 2,000 or less, and a degree of saponification of 91.5 mol % or greater and 99.5 mol % or less; and
a cationic fluorine-containing copolymer (B) having: a constitutional unit derived from a monomer (a) being a (meth)acrylate having a polyfluoroalkyl group having 1 to 6 carbon atoms; and a constitutional unit derived from a monomer (b) being a compound represented by formula (1):
CH 2 ═C(R 1 )COO-Q-N(R 2 )(R 3 ),
wherein R 1 represents a hydrogen atom or a methyl group; Q represents: an alkylene group having 2 to 3 carbon atoms in which a part or all of hydrogen atoms are substituted with a hydroxyl group, or an alkylene group having 2 to 4 carbon atoms; and R 2 and R 3 each independently represent a benzyl group or an alkyl group having 1 to 8 carbon atoms, or R 2 and R 3 taken together represent a morpholino group, a piperidino group or a pyrrolidinyl group together with the nitrogen atom,
a content of the cationic fluorine-containing copolymer (B) is 5 parts by mass or greater and 50 parts by mass or less with respect to 100 parts by mass of the vinyl alcohol polymer (A),
an amount of the greaseproof layer being overlaid on dry mass basis is 0.1 g/m 2 or greater and 3.0 g/m 2 or less, and
a water vapor permeability of the paper composite is 1,000 g/m 2 ·24 h or greater.
2. The paper composite according to claim 1 , wherein the cationic fluorine-containing copolymer (B) has: a content of the constitutional unit derived from the monomer (a) of 50% by mass or greater and 98% by mass or less; and a content of the constitutional unit derived from the monomer (b) of 2% by mass or greater and 50% by mass or less.
3. A packaging material comprising the paper composite according to claim 1 .
4. A production method of a paper composite, the production method comprising:
coating the at least one surface side of a paper substrate with a composition for forming a greaseproof layer,
the paper substrate having an air permeation resistance of 1,000 sec or less and a bulk density of 0.5 g/cm 3 or greater and 1.0 g/cm 3 or less, and
the composition for forming a greaseproof layer comprising:
a vinyl alcohol polymer (A) having a content of an ethylene unit of 2 mol % or greater and 10 mol % or less, a viscosity average degree of polymerization of 300 or greater and 2,000 or less, and a degree of saponification of 91.5 mol % or greater and 99.5 mol % or less; and
a cationic fluorine-containing copolymer (B) having: a constitutional unit derived from a monomer (a) being a (meth)acrylate having a polyfluoroalkyl group having 1 to 6 carbon atoms; and a constitutional unit derived from a monomer (b) being a compound represented by formula (1):
CH 2 ═C(R 1 )COO-Q-N(R 2 )(R 3 ),
wherein R 1 represents a hydrogen atom or a methyl group; Q represents: an alkylene group having 2 to 3 carbon atoms in which a part or all of hydrogen atoms are substituted with a hydroxyl group, or an alkylene group having 2 to 4 carbon atoms; and R 2 and R 3 each independently represent a benzyl group or an alkyl group having 1 to 8 carbon atoms, or R 2 and R 3 taken together represent a morpholino group, a piperidino group or a pyrrolidinyl group together with the nitrogen atom; and
drying the paper substrate having been subjected to the coating, to obtain a paper composite comprising: the paper substrate; and a greaseproof layer formed on the at least one surface side of the paper substrate, wherein
a content of the cationic fluorine-containing copolymer (B) is 5 parts by mass or greater and 50 parts by mass or less with respect to 100 parts by mass of the vinyl alcohol polymer (A),
an amount of the greaseproof layer being overlaid on dry mass basis is 0.1 g/m 2 or greater and 3.0 g/m 2 or less, and
a water vapor permeability of the paper composite is 1,000 g/m 2 ·24 h or greater.