Multi-layer structured lithium metal electrode and method for manufacturing same
View Patent ↗The present invention relates to a multi-layer structured lithium metal electrode and a method for manufacturing the same and, specifically, to a multi-layer structured lithium metal electrode comprising: a buffer layer of lithium nitride (Li3N) formed on a lithium metal plate; and a protective layer of LiBON formed on the buffer layer, and to a method for manufacturing a multi-layer structured lithium metal electrode by continuously forming a lithium nitride buffer layer and a LiBON protective layer on a lithium metal plate through continuous reactive sputtering multi-layer structured lithium metal electrode multi-layer structured lithium metal electrode lithium metal plate multi-layer structured lithium metal electrode lithium metal plate. The multi-layer structured lithium metal electrode of the present invention can protect the reactivity of the lithium metal from moisture or an environment within a battery, and prevent the formation of dendrites, by forming the protective layer.
1. A multi-layer structured lithium metal electrode comprising:
a lithium metal plate;
a buffer layer formed on the lithium metal plate and including lithium nitride (Li 3 N); and
a protective layer formed on the buffer layer and including LiBON having a composition represented by the following Formula 1:
Li x BO y N z [Formula 1]
wherein x is 0.9 to 3.51, y is 0.6 to 3.2 and z is 0.5 to 1.0.
2. The multi-layer structured lithium metal electrode according to claim 1 , wherein the buffer layer is formed on a surface facing an electrolyte of the lithium metal plate.
3. The multi-layer structured lithium metal electrode according to claim 1 , wherein the LiBON having a composition represented by the Formula 1 is any one selected from the group consisting of Li 3.09 BO 2.53 N 0.52 , Li 0.90 BO 0.66 N 0.98 , and Li 3.51 BO 3.03 N 0.52 .
4. The multi-layer structured lithium metal electrode according to claim 1 , wherein the LiBON having a composition represented by the Formula 1 is Li 3.09 BO 2.53 N 0.52 .
5. The multi-layer structured lithium metal electrode according to claim 1 , wherein the lithium metal plate has a thickness of 30 to 500 μm.
6. The multi-layer structured lithium metal electrode according to claim 2 , wherein the lithium metal plate has a thickness of 30 to 500 μm.
7. The multi-layer structured lithium metal electrode according to claim 1 , wherein the lithium nitride layer, as the buffer layer, has a thickness of 0.01 to 5 μm.
8. The multi-layer structured lithium metal electrode according to claim 2 , wherein the lithium nitride layer, as the buffer layer, has a thickness of 0.01 to 5 μm.
9. The multi-layer structured lithium metal electrode according to claim 1 , wherein the LiBON layer, as the protective layer, has a thickness of 0.1 to 10 μm.
10. The multi-layer structured lithium metal electrode according to claim 2 , wherein the LiBON layer, as the protective layer, has a thickness of 0.1 to 10 μm.
11. The multi-layer structured lithium metal electrode according to claim 1 , wherein the lithium nitride buffer layer or the LiBON protective layer is formed by a method selected from electron beam evaporation, metal-organic chemical vapor deposition, reactive sputtering, high frequency sputtering and magnetron sputtering.
12. The multi-layer structured lithium metal electrode according to claim 1 , wherein the multi-layer structured lithium metal electrode is a negative electrode for lithium secondary battery.
13. A method of producing a multi-layer structured lithium metal electrode comprising:
feeding a lithium metal plate into a vacuum chamber;
forming a lithium nitride (Li 3 N) thin film on one or both surfaces of the lithium metal plate by nitrogen (N 2 ) gas reactive sputtering; and
continuously forming a LiBON thin film having a composition represented by the following Formula 1 on the lithium nitride thin film by nitrogen (N 2 ) gas reactive sputtering:
Li x BO y N z [Formula 1]
wherein x is 0.9 to 3.51, y is 0.6 to 3.2 and z is 0.5 to 1.0.
14. A lithium secondary battery comprising:
a negative electrode;
a positive electrode; and
an electrolyte interposed between the positive electrode and the negative electrode,
wherein the negative electrode is the multi-layer structured lithium metal electrode according to claim 1 .