Photocrosslinkable transparent adhesive material, transparent adhesive material layered body, and layered body for constituting optical device
Provided is a novel transparent adhesive material having low relative permittivity as well as excellent adhesive characteristics, whereby an olefinic polymer resin layer and an acrylic polymer adhesive layer can be suitably integrated. Suggested is a transparent adhesive material provided with an outermost surface layer containing an acrylic polymer (B) and a photocrosslinking initiator, and an intermediate layer containing an olefinic polymer (A), a crosslinking agent, and a photocrosslinking initiator, in which the intermediate layer contains a (meth)acrylate monomer as the crosslinking agent.
1. A photocrosslinkable transparent adhesive material comprising:
an outermost surface layer comprising an acrylic polymer (B) and a photocrosslinking initiator; and
an intermediate layer comprising an olefinic polymer (A), a crosslinking agent, and a photocrosslinking initiator,
wherein the intermediate layer comprises the crosslinking agent within a range of 1 to 50 parts by mass relative to 100 parts by mass of the olefinic polymer, and a (meth)acrylate monomer as the crosslinking agent.
2. The photocrosslinkable transparent adhesive material according to claim 1 , wherein each of 130° C. melt viscosity η a , of a resin composition which constitutes the outermost surface layer and 130° C. melt viscosity η b of a resin composition which constitutes the intermediate layer is 5×10 1 to 5×10 3 Pa·s and a ratio η a /η b is 0.05 to 20.
3. The photocrosslinkable transparent adhesive material according to claim 1 , wherein a concentration of the (meth)acrylate monomer in the intermediate layer is higher than a concentration of the (meth)acrylate monomer in the outermost surface layer.
4. The photocrosslinkable transparent adhesive material according to claim 1 , wherein an weight average molecular weight (Mw) of the acrylic polymer (B) is 100,000 to 800,000 and an weight average molecular weight (Mw) of the olefinic polymer (A) is 50,000 to 400,000.
5. The photocrosslinkable transparent adhesive material according to claim 1 , wherein the olefinic polymer (A) is selected from the group consisting of an ethylene-α-olefin copolymer, a styrene-based elastomer, a polyisobutylene resin, and a mixture resin of two or more types thereof.
6. The photocrosslinkable transparent adhesive material according to claim 1 , wherein the intermediate layer has relative permittivity of 3.0 or less at a frequency of from 100 kHz to 1 MHz.
7. The photocrosslinkable transparent adhesive material according to claim 2 , wherein a concentration of the (meth)acrylate monomer in the intermediate layer is higher than a concentration of the (meth)acrylate monomer in the outermost surface layer.
8. The photocrosslinkable transparent adhesive material according to claim 2 , wherein an weight average molecular weight (Mw) of the acrylic polymer (B) is 100,000 to 800,000 and an weight average molecular weight (Mw) of the olefinic polymer (A) is 50,000 to 400,000.
9. The photocrosslinkable transparent adhesive material according to claim 2 , wherein the olefinic polymer (A) is selected from the group consisting of an ethylene-α-olefin copolymer, a styrene-based elastomer, a polyisobutylene resin, and a mixture resin of two or more types thereof.
10. The photocrosslinkable transparent adhesive material according to claim 2 , wherein the intermediate layer has relative permittivity of 3.0 or less at a frequency of from 100 kHz to 1 MHz.
11. The photocrosslinkable transparent adhesive material according to claim 3 , wherein an weight average molecular weight (Mw) of the acrylic polymer (B) is 100,000 to 800,000 and an weight average molecular weight (Mw) of the olefinic polymer (A) is 50000 to 400,000.
12. The photocrosslinkable transparent adhesive material according to claim 3 , wherein the olefinic polymer (A) is selected from the group consisting of an ethylene-α-olefin copolymer, a styrene-based elastomer, a polyisobutylene resin, and a mixture resin of two or more types thereof.
13. A transparent adhesive material layered body comprising:
a release film; and
the photocrosslinkable transparent adhesive material according to claim 1 provided on the release film.
14. A layered body for an optical device, comprising:
a member Which constitutes an optical device: and
the photocrosslinkable transparent adhesive material according to claim 1 provided on the member.
15. A method for producing a layered body for an optical device, the method comprising:
preliminarily irradiating the photocrosslinkable transparent adhesive material according to claim 1 to preliminary cure the photocrosslinkable transparent adhesive material;
attaching the transparent adhesive material after the preliminary irradiating to a member which constitutes an optical device; and
irradiating the photocrosslinkable transparent adhesive material with light over the member to cure the photocrosslinkable transparent adhesive material.