Well service fluid composition and method of using microemulsions as flowback aids
The present invention relates to a new Winsor type IV microemulsion system for faster return of well service fluid and enhanced production of hydrocarbon-containing fluids in fractured tight subterranean formations, where the microemulsion system includes a surfactant subsystem including at least one glucamide sugar surfactant, a solvent subsystem and a co-solvent subsystem and to methods for making and using same.
1. A microemulsion comprising
water,
2-15 wt.-% of at least one organic solvent with flash point above 37.8° C. and pour point of 10° C. or lower,
1-6 wt.-% of at least one co-solvent that includes at least one alcohol, and
12-30 wt.-% of at least one N-Alkyl-N-acylglucamine surfactant,
wherein the microemulsion is a Winsor type IV microemulsion.
2. The microemulsion according to claim 1 , wherein the glucamide surfactant is a compound of formula (I)
wherein
Ra is a C 5 -C 21 -hydrocarbon residue, and
Rb is a C 1 -C 4 -alkyl group.
3. The microemulsion according to claim 2 , wherein Ra is C 7 to C 15 hydrocarbon.
4. The microemulsion according to claim 2 , wherein Ra is an aliphatic group.
5. The microemulsion according to claim 2 , wherein Ra is alkyl or alkenyl.
6. The microemulsion according to claim 2 , wherein Rb is methyl.
7. The microemulsion according to claim 2 , wherein in at least 50 wt.-% of the total amount of compounds according to formula (I) Ra is C 7 to C 9 alkyl and in up to 50 wt.-% Ra is C 11 to C 13 alkyl.
8. The microemulsion according to claim 1 , wherein the at least one organic solvent is selected from the group consisting of naphthalene depleted alkyl arenes, terpenes, paraffinic solvents, fatty acid alkyl esters and butyl glycol ethers.
9. The microemulsion according to claim 1 , wherein the at least one co-solvent is selected from the group consisting of primary, secondary or tertiary monoalcohols having from 1-20 carbon atoms, and diols having from 1-20 carbon atoms.
10. The microemulsion according to claim 1 , wherein the at least one co-solvent is selected from the group consisting of propylene glycol, isopropanol, t-butanol, n-butanol, n-pentanol, n-hexanol, n-octanol and pentane-diol.
11. The microemulsion according to claim 1 , further comprising a mutual solvent selected from the group consisting of 2-ethylhexanol, ethers of 2-ethylhexanol with ethylene glycol, polyethylene glycols, propylene glycol, and mixtures thereof.
12. The microemulsion according to claim 1 , comprising 14-25 wt.-% of the at least one N-Alkyl-N-acylglucamine surfactant.
13. The microemulsion according to claim 1 , comprising 3-5 wt.-% of the at least one co-solvent.
14. The microemulsion according to claim 1 , comprising 5-10 wt.-% of the at least one organic solvent.
15. The microemulsion according to claim 1 , further comprising up to 10 wt.-% of a mutual solvent.
16. The microemulsion according to claim 1 , comprising water as the balance to 100 wt. %.
17. A process for recovering fluids during fracturing operations, the process comprising injecting a microemulsion comprising
water,
2-15 wt.-% of at least one organic solvent with flash point above 37.8° C. and pour point of 10° C. or lower,
1-6 wt.-% of at least one co-solvent that includes at least one alcohol, and
12-30 wt.-% of at least one N-Alkyl-N-acylglucamine surfactant,
wherein the microemulsion is a Winsor type IV microemulsion into the fractured formation.
18. The process according to claim 17 , wherein the amount of microemulsion is 0.1 to 10 gallons of microemulsion per thousand gallons of fracturing fluid.
19. A process for stimulating an oil or gas well, comprising injection of water and a microemulsion comprising
water,
2-15 wt.-% of at least one organic solvent with flash point above 37.8° C. and pour point of 10° C. or lower,
1-6 wt.-% of at least one co-solvent that includes at least one alcohol, and
12-30 wt.-% of at least one N-Alkyl-N-acylglucamine surfactant,
wherein the microemulsion is a Winsor type IV microemulsion, into the oil or gas well.
20. The process according to claim 19 , wherein 0.1 to 10 gallons of microemulsion are used per 1000 gallons of water (0.01-1% by volume).