Method for manufacturing polyamide-based water-treatment separator having excellent permeation flux characteristics and water-treatment separator manufactured by same
The present invention relates to a method for manufacturing a water treatment separation membrane, the method including: forming an aqueous solution layer including an amine compound on a porous support; and bringing an organic solution including an acyl halide compound into contact with on the aqueous solution layer to form a polyamide active layer, in which the organic solution includes a non-polar solvent and an amphiphilic solvent having a boiling point of 120° C. or more, thereby improving a permeation flux, and a water treatment separation membrane manufactured by the manufacturing method.
1. A method for manufacturing a water treatment separation membrane, the method comprising:
forming an aqueous solution layer comprising an amine compound on a porous support; and
bringing an organic solution comprising an acyl halide compound into contact with on the aqueous solution layer to form a polyamide active layer,
wherein the organic solution comprises a non-polar solvent and an amphiphilic solvent having a boiling point of 120° C. or more,
wherein the amphiphilic solvent comprises one or more selected from the group consisting of propylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, and 1,3-butanediol diacetate, and
wherein the amphiphilic solvent is comprised in an amount of 0.05 vol % to 10 vol % based on a total volume of the organic solution.
2. The method of claim 1 , wherein the non-polar solvent is a hydrocarbon solvent having 6 to 13 carbon atoms.