Titanium cast product for hot rolling unlikely to exhibit surface defects and method of manufacturing the same
Provided is a titanium cast product for hot rolling made of commercially pure titanium, the titanium cast product including a melted and resolidified layer in a range of more than or equal to 1 mm in depth on a surface serving as a rolling surface, the melted and resolidified layer being obtained by adding one or more elements out of any one of or both of at least one α stabilizer element and at least one neutral element to the surface, and melting and resolidifying the surface. An average value of a total concentration of the at least one α stabilizer element and the at least one neutral element in the range of more than or equal to 1 mm in depth is higher than a total concentration of the at least one α stabilizer element and the at least one neutral element in a base metal by, in mass %, more than or equal to 0.1% and less than 2.0%.
1. A method of manufacturing a titanium cast product, the method comprising:
melting a surface of a base metal of a titanium ingot consisting of 0.1 mass % or less C, 0.015 mass % or less H, 0.4 mass % or less O, 0.07 mass % or less N, 0.5 mass % or less Fe, and a balance of Ti and impurities together with a material, in contact with the surface, containing one or more elements out of any one of or both of at least one α stabilizer element and at least one neutral element,
then solidifying the surface with the material to make a layer in a range of 1 mm or more on the surface to form a titanium cast product, and
performing hot rolling on the titanium cast product,
wherein a total concentration of a total of at least one a stabilizer element and at least one neutral element within 1 mm in depth of the surface of the titanium cast product is made higher than a total concentration of a total of at least one α stabilizer element and at least one neutral element in the base metal by, in mass %, 0.1% to 1.499%,
wherein the layer within 1 mm in depth of the surface further contains, in mass %, 0% to 1.5% of one or more β stabilizer elements,
wherein the at least one α stabilizer element includes Al and wherein the at least one neutral element includes one of Sn and Zr.
2. The method of manufacturing a titanium cast product according to claim 1 ,
wherein the material containing one or more elements out of any one of or both of at least one a stabilizer element and at least one neutral element includes one or more of powder, chips, a wire, a thin film, and swarf.
3. The method of manufacturing a titanium cast product according to claim 1 ,
wherein the surface of the base metal of the titanium ingot is melted by using one or more of electron beam heating, arc heating, laser heating, plasma heating, and induction heating.
4. The method of manufacturing a titanium cast product according to claim 1 ,
wherein the surface of the base metal of the titanium ingot is melted in a vacuum atmosphere or an inert gas atmosphere.