Adhesive composition and adhesive film for touch panel
Provided are: an adhesive composition for a touch panel, including an acrylic resin, a first curing agent having one to three functional groups, a second curing agent having four to six functional groups, and an ultraviolet blocking agent containing a benzotriazole group; and an adhesive film for a touch panel, including a cured product of the composition.
1. An adhesive composition for a touch panel, comprising:
an acrylic resin;
a first curing agent which is hexamethylene diisocyanate (HDI) derivative having two to three isocyanate groups;
a second curing agent which is hexamethylene diisocyanate (HDI) derivative having four to six isocyanate groups; and
an ultraviolet blocking agent containing a benzotriazole group.
2. The adhesive composition of claim 1 , wherein a weight ratio of the first curing agent: the second curing agent is 2:1 to 4:1.
3. The adhesive composition of claim 1 , wherein the acrylic resin is formed by polymerizing a monomer component including: a (meth)acrylic acid ester-based monomer; and a hydrophilic functional group-containing monomer.
4. The adhesive composition of claim 3 , wherein the monomer component comprises the hydrophilic functional group-containing monomer in an amount of 5 to 15 parts by weight based on 100 parts by weight of the (meth)acrylic acid ester-based monomer.
5. The adhesive composition of claim 3 , wherein the hydrophilic functional group-containing monomer comprises at least one selected from the group consisting of a hydroxyl group-containing monomer, an amino group-containing monomer, a carboxyl group-containing monomer, a sulfone group-containing monomer, a morpholine group-containing monomer, a glycidyl group-containing monomer, and a combination thereof.
6. The adhesive composition of claim 3 , wherein the (meth)acrylic acid ester-based monomer is a linear or branched alkyl (meth)acrylate having 1 to 14 carbon atoms.
7. The adhesive composition of claim 1 , wherein a total content of the first curing agent and the second curing agent is 0.4 to 1.5 parts by weight based on 100 parts by weight of the acrylic resin.
8. The adhesive composition of claim 1 , wherein a content of the ultraviolet blocking agent containing a benzotriazole group is 0.5 to 5 parts by weight based on 100 parts by weight of the acrylic resin.
9. An adhesive film for a touch panel, comprising a cured product of the adhesive composition for a touch panel according to claim 1 .
10. The adhesive film of claim 9 , wherein the cured product is prepared by thermally curing the adhesive composition for a touch panel at 70° C. to 120° C. for 0.5 minute to 5 minutes, and then aging the adhesive composition at 30° C. to 60° C. for 1 day to 3 days.
11. The adhesive film of claim 9 , wherein the cured product has a density of 1 g/cm 3 to 1.5 g/cm 3 .
12. The adhesive film of claim 9 , wherein the adhesive film has a light transmittance of less than 10% at a wavelength of 380 nm or less.
13. The adhesive film of claim 9 , wherein the adhesive film has a bubble generation rate of 5 ea./cm 2 or less after the adhesive film is left to stand under conditions of a temperature of 85° C. and a relative humidity of 85% for 200 to 500 hours.