Secondary battery having improved output characteristics
View Patent ↗A secondary battery having improved output characteristics is disclosed. The secondary battery according to the present invention accommodates a cell assembly including a plurality of cells connected in parallel, and an electrolyte together in one package, in which positive electrodes of a plurality of central cells disposed at a central part of the cell assembly have a loading energy density higher than that of positive electrodes of a plurality of side cells disposed at a side part, and the positive electrodes of the central cells have positive electrode material coating layers formed at surfaces thereof, which are thicker than those formed at surfaces of the positive electrodes of the side cells. Preferably, the total resistance of the side cells is lower than the total resistance of the central cells.
1. A secondary battery comprising a cell assembly including a plurality of cells connected in parallel and an electrolyte within one single package,
wherein positive electrodes of a plurality of central cells disposed at a central part of the cell assembly have a greater loading energy density than positive electrodes of a plurality of side cells disposed at a side part,
wherein the positive electrodes of the central cells have a thicker positive electrode material coating layer formed on surfaces of the positive electrodes than the positive electrodes of the side cells, and
wherein an outermost electrode of the plurality of central cells comprises an electrode plate and an inner coating layer disposed toward a center of the cell assembly and an outer coating layer disposed toward the side cells, the inner coating layer and the outer coating layer respectively coated on both surfaces of the electrode plate, and the inner coating layer is thicker than the outer coating layer.
2. The secondary battery of claim 1 , wherein a total resistance of the side cells is less than a total resistance of the central cells.
3. The secondary battery of claim 1 , wherein the positive electrodes of the central cells have a loading energy density of 3.9-4.1 mAh/cm 2 , and the positive electrodes of the side cells have a loading energy density of 1.6-1.8 mAh/cm 2 .
4. The secondary battery of claim 1 , wherein a first positive electrode material coating layer formed on the positive electrodes of the central cells and a second positive electrode material coating layer formed on the positive electrodes of the side cells comprise positive electrode material particles with the same chemical composition and average particle diameter.
5. The secondary battery of claim 1 , wherein a first positive electrode material coating layer formed on the positive electrodes of the central cells and a second positive electrode material coating layer formed on the positive electrodes of the side cells comprise the same content of a conductive material.
6. The secondary battery of claim 1 , wherein a first positive electrode material coating layer formed on the positive electrodes of the central cells and a second positive electrode material coating layer formed on the positive electrodes of the side cells comprise positive electrode material particles with different chemical compositions from each other.
7. The secondary battery of claim 1 , wherein the positive electrodes of the central cells comprise a first positive electrode material coating layer containing first positive electrode material particles and a conductive material,
the positive electrodes of the side cells comprise a second positive electrode material coating layer containing second positive electrode material particles and a conductive material, and
an average particle diameter of the first positive electrode material particles is greater than an average particle diameter of the second positive electrode material particles.
8. The secondary battery of claim 1 , wherein the positive electrodes of the central cells comprise a first positive electrode material coating layer containing first positive electrode material particles and a conductive material,
the positive electrodes of the side cells comprise a second positive electrode material coating layer containing second positive electrode material particles and a conductive material, and
the second positive electrode material coating layer contains more conductive material than the first positive electrode material coating layer.
9. The secondary battery of claim 1 , wherein the central cells comprise a positive electrode, a negative electrode, and a first separator with porosity interposed therebetween,
the side cells comprise a positive electrode, a negative electrode, and a second separator with porosity interposed therebetween,
and a resistance of the second separator is lower than that of the first separator.
10. The secondary battery of claim 1 , wherein the outermost electrode is a negative electrode disposed at the outermost of the central cells.
11. The secondary battery of claim 1 , wherein the outermost electrode is a positive electrode disposed at the outermost of the central cells.
12. The secondary battery of claim 1 , wherein the package is a pouch package.