Separator for lead-acid battery, and lead-acid battery
To provide a convenient and effective method for suppressing the penetration of dendrite over the microporous film mainly containing the base portion, which occupies the most part of the entire separator (total area), rather than the peculiar concept (resulting in a difficult measure), in which only the pore structure of the rib portion is densified or contracted for suppressing dendrite from penetrating through the rib portion. A separator for a lead-acid battery, containing a microporous film obtained in such a manner that a raw material composition mainly containing a polyolefin resin, silica powder, and a plasticizer is melt-kneaded and formed into a film, from which the plasticizer is entirely or partially removed, the raw material composition containing glass flakes having an average particle diameter of from 20 to 800 μm and an average thickness of 0.2 to 8 μm and having no self-film formability in an amount of from 2 to 15% by weight based on a total amount of the silica powder and the glass flakes, the glass flakes in the microporous film being disposed in such a manner that a plane direction thereof is substantially oriented in a plane direction of the microporous film, a value of (the content of the glass flakes in the microporous film)/(the average thickness of the glass flakes in the microporous film) being 1 or more.
1. A separator for a lead-acid battery, comprising:
a microporous film having a base thickness of from 0.1 to 0.3 mm, an average pore diameter (mercury intrusion method) of from 0.01 to 0.5 μm, a maximum pore diameter (mercury intrusion method) of from 0.3 to 1.0 μm, and a porosity (mercury intrusion method) of from 50 to 90% by volume,
wherein the micoporous film is obtained by melt-kneading and forming into a film a raw material composition mainly containing a polyolefin resin, silica powder, and a plasticizer and further containing glass flakes having an average particle diameter of from 20 to 800 μm and an average thickness of 0.2 to 8 μm in an amount of from 2 to 15% by weight based on a total amount of the silica powder and the glass flakes, and a silane coupling agent (solid content) in a content of from 0 to 3% by weight, such that the plasticizer is entirely or partially removed from the film,
wherein the glass flakes have no self-film formability, wherein self-film formability is the property that when only the glass flakes are dispersed in water to form a dispersion liquid having an appropriate concentration, which is coated on a surface of a base material having smoothness and then solidified by drying, the glass flakes form a film by themselves,
wherein the microporous film has a total content of the polyolefin resin, the silica powder, the plasticizer, and the glass flakes of 90% by weight or more, a content of the polyolefin resin of from 20 to 60% by weight, a content of the silica powder of from 40 to 80% by weight, and a content of the plasticizer of from 0 to 30% by weight, and an amount of the glass flakes therein being from 2 to 15% by weight based on a total amount of the silica powder and the glass flakes,
the glass flakes in the microporous film have an average thickness of from 0.2 to 8μm,
the glass flake particles in the microporous film that have a particle diameter of 10 μm or more are disposed in such a manner that a plane direction thereof is substantially oriented in a plane direction of the microporous film, and
a value of (the content of the glass flakes in the microporous film (% by weight))/(the average thickness of the glass flakes in the microporous film (μm)) is 1(%/μm) or more.
2. The separator for a lead-acid battery according to claim 1 , wherein the value of (the content of the glass flakes in the microporous film (% by weight))/(the average thickness of the glass flakes in the microporous film (μm)) is 2(%/μm) or more.
3. The separator for a lead-acid battery according to claim 1 , wherein 80% or more of the particles that have a particle diameter of 10 μm or more of the glass flakes in the microporous film are disposed in such a manner that a plane direction thereof forms 20° or less with respect to the plane direction of the microporous film.
4. The separator for a lead-acid battery according to claim 1 , wherein the raw material composition contains the silane coupling agent (solid content) in a content of from 0.1% by weight or more.
5. The separator for a lead-acid battery according to claim 1 , wherein the glass flakes in the raw material composition and the microporous film have an average thickness of 2 μm or less, the amount of the glass flakes in the raw material composition is from 2 to 8% by weight based on the total amount of the silica powder and the glass flakes, the amount of the glass flakes in the microporous film is from 2 to 8% by weight based on the total amount of the silica powder and the glass flakes, and the value of (the content of the glass flakes in the microporous film (% by weight))/(the average thickness of the glass flakes in the microporous film (μm)) is 10(%/μm) or less.
6. A lead-acid battery comprising the separator according to claim 1 .