Thermoelectric composite material and method for preparing thermoelectric composite material
The present invention relates to a thermoelectric composite material and a method for preparing a thermoelectric composite material. Specifically, the invention relates to a thermoelectric composite material in which graphene oxide attached with conductive metal nanoparticles is dispersed in a thermoelectric material and a method for preparing a thermoelectric composite powder comprising the steps of: growing conductive metal nanoparticles on the surface of graphene oxide (step 1); and introducing the graphene oxide attached with the conductive metal nanoparticles prepared in step 1 into a thermoelectric material precursor solution, followed by heat treatment (step 2).
1. A thermoelectric composite material comprising:
a functionalized graphene oxide including conductive metal nanoparticles on a surface of the functionalized graphene oxide, the functionalized graphene oxide being dispersed in a thermoelectric material.
2. The thermoelectric composite material according to claim 1 , wherein the metal of the conductive metal nanoparticles is one or more metals selected from the group consisting of silver, copper, gold, platinum, and nickel.
3. The thermoelectric composite material according to claim 1 , wherein the thermoelectric material is one or more compounds selected from the group consisting of Bi—Te compounds, Sb—Te compounds, Bi—Sb—Te compounds, Co—Sb compounds, Pd—Te compounds, Ge—Tb compounds, Si—Ge compounds, and Sm—Co compounds.
4. The thermoelectric composite material according to claim 1 , wherein the graphene oxide including conductive metal nanoparticles on the surface of the graphene oxide is prepared by growing the conductive metal nanoparticles on the surface of the graphene oxide after a functionalization of the graphene oxide.
5. The thermoelectric composite material according to claim 1 , wherein a dimensionless figure-of-merit (ZT) of the thermoelectric composite material is improved at least as much as 1.2 times ˜2.0 times by that of the thermoelectric material in a temperature range of −20˜200° C.
6. A method for preparing a thermoelectric composite powder comprising the following steps:
growing conductive metal nanoparticles on a surface of a functionalized graphene oxide (step 1); and
introducing the functionalized graphene oxide including the conductive metal nanoparticles on the surface of the functionalized graphene oxide prepared in step 1 into a thermoelectric material precursor solution, followed by a heat treatment (step 2), the functionalized graphene oxide being dispersed in the thermoelectric material.
7. The method for preparing the thermoelectric composite powder according to claim 6 , wherein the metal of the conductive metal nanoparticles is one or more metals selected from the group consisting of silver, copper, gold, platinum, and nickel.
8. The method for preparing the thermoelectric composite powder according to claim 6 , wherein the surface of the functionalized graphene oxide of step 1 is attached with a functional group by one or more methods selected from the group consisting of ultrasonic process, acid treatment, and chemical treatment.
9. The method for preparing the thermoelectric composite powder according to claim 6 , wherein the growing of the conductive metal nanoparticles in step 1 is achieved by heat-treating a conductive metal nanoparticle precursor at 50 ˜150° C. in a basic solution (pH 8 ˜10).
10. The method for preparing the thermoelectric composite powder according to claim 6 , wherein the thermoelectric material precursor solution of step 2 contains one or more thermoelectric material precursors selected from a group consisting of bismuth acetate, bismuth chloride, bismuth nitrate, tellurium chloride, selenium chloride, and antimony chloride.
11. The method for preparing the thermoelectric composite powder according to claim 6 , wherein the thermoelectric material precursor solution of step 2 contains a surfactant and a reducing solvent.
12. The method for preparing the thermoelectric composite powder according to claim 11 , wherein the surfactant is one or more materials selected from the group consisting of oleylamine (OLA), trioctylphosphine (TOP), and oleic acid.
13. The method for preparing the thermoelectric composite powder according to claim 11 , wherein the reducing solvent is l-dodecanethiol.
14. The method for preparing the thermoelectric composite powder according to claim 6 , wherein the functionalized graphene oxide including the conductive metal nanoparticles on the surface of the functionalized graphene oxide of step 2 is introduced in the thermoelectric material precursor solution at a concentration of 0.02 weight% ˜5 weight% of the solution.
15. The method for preparing the thermoelectric composite powder according to claim 6 , wherein the heat treatment in step 2 is performed at 90 ˜250° C. for 1˜3 hours.
16. A method for preparing a thermoelectric composite powder comprising the following steps:
growing conductive metal nanoparticles on a surface of a functionalized graphene oxide (step 1); and
mixing mechanically the functionalized graphene oxide including the conductive metal nanoparticles on the surface of the functionalized graphene oxide prepared in step 1 with a thermoelectric material powder (step 2), the functionalized graphene oxide being dispersed in the thermoelectric material.