Polymerizable compound and optically anisotropic body

1. A compound represented by General Formula (I) below,

wherein, P represents a polymerizable group selected from the group consisting of groups represented by Formulae (P-1) to (P-20) below,

S represents an alkylene group having 1 to 20 carbon atoms and in which one —CH 2 — group or two or more —CH 2 — groups that are not adjacent to one another may be each independently replaced with —COO—, —OCO—, —OCO—O—, —CO—NH— or —NH—CO;

X represents —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —SCH 2 —, —CH 2 S—, —CF 2 O—, —OCF 2 —, —CF 2 S—, —SCF 2 —, —COO—CH 2 CH 2 —, —OCO—CH 2 CH 2 —, —CH 2 CH 2 —COO—, —CH 2 CH 2 —OCO—, —COO—CH 2 —, —OCO—CH 2 —, —CH 2 —COO—, —CH 2 —OCO—, —N═N—, —CH═N—N═CH—, or a single bond and, when a plurality of X groups are present, they may be identical to or different from one another in which P—(S—X) k — does not include an —O—O— bond;

A 1 and A 2 each independently represent a 1,4-phenylene group, a 1,4-cyclohexylene group, a pyridine-2,5-diyl group, a pyrimidine-2,5-diyl group, a naphthalene-2,6-diyl group, a naphthalene-1,4-diyl group, a tetrahydronaphthalene-2,6-diyl group, a decahydronaphthalene-2,6-diyl group, or a 1,3-dioxane-2,5-diyl group, the above groups may be optionally substituted with one or more L substituents, and, when a plurality of A 1 groups and/or a plurality of A 2 groups are present, they may be identical to or different from one another;

L represents a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a pentafluorosulfanyl group, a nitro group, an isocyano group, an amino group, a hydroxyl group, a mercapto group, a methylamino group, a dimethylamino group, a diethylamino group, a diisopropylamino group, a trimethylsilyl group, a dimethylsilyl group, a thioisocyano group, or a linear or branched alkyl group having 1 to 20 carbon atoms in which one —CH 2 — group or two or more —CH 2 — groups that are not adjacent to one another may be each independently replaced with —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, when a plurality of L substituents are present, they may be identical to or different from one another, and some hydrogen atoms included in the alkyl group may be replaced with fluorine atoms;

Z 1 and Z 2 each independently represent —O—, —S—, —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —OCO—NH—, —NH—COO—, —NH—CO—NH—, —NH—O—, —O—NH—, —SCH 2 —, —CH 2 S—, —CF 2 O—, —OCF 2 —, —CF 2 S—, —SCF 2 —, —COO—CH 2 CH 2 —, —OCO—CH 2 CH 2 —, —CH 2 CH 2 —COO—, —CH 2 CH 2 —OCO—, —COO—CH 2 —, —OCO—CH 2 —, —CH 2 —COO—, —CH 2 —OCO—, —N═N—, —CH═N—, —N═CH—, —CH═N—N═CH—, or a single bond, and, when a plurality of Z 1 groups and/or a plurality of Z 2 groups are present, they may be identical to or different from one another;

M represents a group selected from Formulae (M-1) to (M-8) below,

the above groups may be optionally substituted with one or more L M substituents, L M represents a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a pentafluorosulfanyl group, a nitro group, a cyano group, an isocyano group, an amino group, a hydroxyl group, a mercapto group, a methylamino group, a dimethylamino group, a diethylamino group, a diisopropylamino group, a trimethylsilyl group, a dimethylsilyl group, a thioisocyano group, or a linear or branched alkyl group having 1 to 20 carbon atoms in which one —CH 2 — group or two or more —CH 2 — groups that are not adjacent to one another may be each independently replaced with —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, some hydrogen atoms included in the alkyl group may be replaced with fluorine atoms, and, when a plurality of L M substituents are present, they may be identical to or different from one another;

R 1 represents a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a pentafluorosulfanyl group, a cyano group, a nitro group, an isocyano group, a thioisocyano group, or a linear or branched alkyl group having 1 to 20 carbon atoms in which one —CH 2 — group or two or more —CH 2 — groups that are not adjacent to one another may be each independently replaced with —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, and some hydrogen atoms included in the alkyl group may be replaced with fluorine atoms;

G represents a group selected from Formulae (G-1) and (G-2) below,

wherein, R 2 represents a hydrogen atom or a linear or branched alkyl group having 1 to 20 carbon atoms in which one —CH 2 — group or two or more —CH 2 — groups that are not adjacent to one another may be each independently replaced with —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, or —NH—CO—, and some hydrogen atoms included in the alkyl group may be replaced with fluorine atoms;

W 1 represents a group having 2 to 30 carbon atoms, the group including at least one aromatic group, the group may be optionally substituted with one or more L W substituents, L W represents a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a pentafluorosulfanyl group, a nitro group, a cyano group, an isocyano group, an amino group, a hydroxyl group, a mercapto group, a methylamino group, a dimethylamino group, a diethylamino group, a diisopropylamino group, a trimethylsilyl group, a dimethylsilyl group, a thioisocyano group, or a linear or branched alkyl group having 1 to 20 carbon atoms in which one —CH 2 — group or two or more —CH 2 — groups that are not adjacent to one another may be each independently replaced with —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, or —NH—CO—, some hydrogen atoms included in the alkyl group may be replaced with fluorine atoms, and, when a plurality of L W substituents are present, they may be identical to or different from one another;

W 2 represents a linear or branched alkyl group having 1 to 20 carbon atoms, the group may be optionally substituted with one or more L W substituents; and

k represents an integer of 0 or 1, m1 and m2 each independently represent an integer of 0 to 4, and m1+m2 is an integer of 1 to 5.

2. The compound according to claim 1 , wherein, in General Formula (I), S independently represents an alkylene group having 1 to 20 carbon atoms in which one —CH 2 — group or two or more —CH 2 — groups that are not adjacent to one another may be each independently replaced with —O—, —COO—, —OCO—, —OCO—O—, —CO—NH—, —NH—CO—, or —C≡C—.

3. The compound according to claim 1 , wherein, in General Formula (I), a total number of π electrons included in W 1 and W 2 is 4 to 24.

4. The compound according to claim 1 , wherein, in General Formula (I), the group represented by W 1 is a group represented by any one of Formulae (W-1) to (W-19) below,

wherein, the above groups may have a bond at any position;

Q 1 represents —O—, —S—, —NR 3 — (where R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms), or —CO—; —CH═ groups included in the aromatic groups may be each independently replaced with an —N═ group;

—CH 2 — groups included in the aromatic groups may be each independently replaced with —O—, —S—, —NR 4 — (where R 4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms), or —CO— providing that an —O—O— bond is not included; the above groups may be optionally substituted with one or more L W substituents; two or more groups selected from the above groups may be linked to one another with a single bond to form another group; and the above groups may form a ring structure constituted by W 1 and W 2 .

5. The compound according to claim 1 selected from General Formulae (I-A) to (I-D) below,

wherein, P, S, X, k, M, G, and R 1 represent the same things as those defined in General Formula (I); A 11 and A 12 each independently represent the same things as A 1 of General Formula (I); Z 11 and Z 12 each independently represent the same things as Z 1 of General Formula (I); A 21 and A 22 each independently represent the same things as A 2 of General Formula (I); and Z 21 and Z 22 each independently represent the same things as Z 2 of General Formula (I).

6. A composition comprising the compound according to claim 1 .

7. A liquid crystal composition comprising the compound according to claim 1 .

8. A polymer produced by polymerizing the composition according to claim 6 .

9. An optically anisotropic body comprising the polymer according to claim 8 .

10. A resin comprising the compound according to claim 1 .

11. The compound represented by General Formula (I) according to claim 1 selected from the group consisting of the compounds represented by Formulae (I-13), (I-15), (I-19), (I-21), (I-22), (I-23), (I-26), (I-27), (I-31), (I-37), (I-41), (I-42), (I-52), (I-54), (I-56), (I-65), (I-66), (I-67), (I-70), (I-76), (I-77), (I-80), (I-81), (I-83), (I-88), (I-92), (I-101), (I-102), (I-115), (I-117) and (I-118).

12. The compound represented by General Formula (I) according to claim 11 selected from the group consisting of the compounds represented by Formulae (I-117) and (I-118).