Methods of sulfurizing metal containing particles

1. A method of sulfurizing a bed of metal containing particles in the absence of hydrogen gas, the method comprising:

(a) obtaining a vertical reactor comprising a bed of metal containing particles;

(b) introducing a gaseous stream comprising hydrogen sulfide and inert gas into an inlet positioned at the bottom portion of the reactor;

(c) contacting the bed of metal containing particles with the gaseous stream comprising hydrogen sulfide and inert gas under at ambient pressure to 195 kPa, and in the absence of hydrogen gas to produce sulfided metal containing particles, wherein 10% up to 90% of the bed of metal containing particles is converted into the sulfided metal containing particles;

(d) removing any unreacted hydrogen sulfide and inert gas at an outlet positioned above the inlet;

(e) removing up to 50% of the sulfided metal containing particles from the bottom portion of the reactor; and

(f) adding metal containing particles to the bed,

wherein the bed of metal containing particles remains substantially stationary during step (c), and

wherein the method is performed off-site.

2. The method of claim 1 , wherein a majority of the produced sulfided metal containing particles are positioned closer to the gas inlet when compared to the outlet of the reactor.

3. The method of claim 1 , wherein at least 2 cycles of steps (c) and (d) are performed.

4. The method of claim 1 , wherein more than 50% of the metal containing particles are converted into the sulfide metal containing particles.

5. The method of claim 1 , further comprising:

(i) discontinuing step (f);

(ii) performing step (c) and (d); and

(iii) removing substantially all of the sulfide metal containing particles from the bottom portion of the reactor, wherein 90% or more of the removed metal containing particles are converted into the sulfide metal containing particles.

6. The method of claim 1 , wherein the particles are not mixed during step (c).

7. The method of claim 1 , wherein step (c) is performed at a temperature of 250° C. or less.

8. The method of claim 1 , wherein the metal containing particles comprise a Group VIII metal or metal oxide thereof.

9. The method of claim 1 , wherein the metal containing particles comprise a Group IB metal or metal oxide thereof.

10. The method of claim 1 , wherein the metal containing particles in step (a) are particles that have not previously been sulfided, are particles that need to be re-sulfided, or are a combination thereof.

11. The method of claim 1 , wherein the gaseous stream comprises 1 to 20 vol. % of hydrogen sulfide.

12. The method of claim 1 , wherein the metal containing particles in the bed remain substantially stationary during step (c).