Production method and production apparatus of electrode for secondary battery, electrode for secondary battery, and secondary battery
An electrode for a secondary battery including an electrode laminated assembly that has a configuration in which electrodes and a separator are laminated, includes current collector 3 and active material layer 2 formed on a surface of current collector 3 . Active material layer 2 includes a thick-layer portion and a thin-layer portion that is positioned at an edge portion of the active material layer and that is smaller in thickness than the thick-layer portion, and is formed by discharging slurry containing an active material from discharge port 12 a of die head 12 toward the surface of current collector 3 , the slurry being supplied to die head 12 through coating valve 13 . At the time of the formation of the thin-layer portion of active material layer 2 , the slurry supplied through coating valve 13 having a smaller opening amount than at the time of the formation of the thick-layer portion is discharged toward current collector 3 from discharge port 12 a that is closer to current collector 3 than at the time of the formation of the thick-layer portion.
1. A production method of an electrode for a secondary battery, the secondary battery including an electrode laminated assembly that has a configuration in which electrodes and a separator are laminated, wherein
said electrode includes a current collector and an active material layer formed on a surface of said current collector,
said active material layer includes a thick-layer portion and a thin-layer portion that is positioned at an edge portion of said active material layer and that is smaller in thickness than the thick-layer portion, and is formed by discharging slurry containing an active material from a discharge port of a die head toward the surface of said current collector, the slurry being supplied to said die head through a coating valve, and
at the time of forming the thin-layer portion of said active material layer, the slurry supplied through said coating valve having a smaller opening than at the time of forming the thick-layer portion is discharged toward said current collector from the discharge port that is closer to said current collector than at the time of forming the thick-layer portion.
2. The production method of the electrode for the secondary battery according to claim 1 , wherein at the start of the formation of said active material layer, the thin-layer portion is formed by discharging a small amount of the slurry supplied through said coating valve which is open to a small degree, toward said current collector, from the discharge port with a small interval from said current collector, and after the formation of the thin-layer portion, the thick-layer portion is formed by increasing the interval between the discharge port and said current collector, degree to which said coating valve is open is increased, and then discharging a large amount of the slurry supplied through said coating valve, toward said current collector.
3. The production method of the electrode for the secondary battery according to claim 2 , wherein after the formation of the thin-layer portion, the interval between the discharge port and said current collector is increased and then the degree to which said coating valve is open is increased.
4. The production method of the electrode for the secondary battery according to claim 1 , wherein said coating valve includes a valve seat that has a through-hole, and a valve plug that can abut on the valve seat and that can move away from the valve seat, and at the time of the formation of the thin-layer portion of said active material layer, the degree to which said coating valve is open is decreased by decreasing the interval between the valve plug and the valve seat.
5. The production method of the electrode for the secondary battery according to claim 1 , wherein
in a state where said coating valve is closed and the slurry is not discharged from said die head, said coating valve is open, and the discharge of the slurry from said die head to said current collector is started, and
after a predetermined time has elapsed since the start of the opening of said coating valve, said die head start to move so as to be away from said current collector.
6. The production method of the electrode for the secondary battery according to claim 5 , wherein the thin-layer portion is formed in a period after said coating valve starts to open and before said die head starts to move so as to be away from said current collector.
7. A production method of an electrode for a secondary battery, the secondary battery including an electrode laminated assembly that has a configuration in which electrodes and a separator are laminated, wherein
said electrode includes a current collector and an active material layer formed on a surface of said current collector,
said active material layer includes a thick-layer portion and a thin-layer portion that is positioned at an edge portion of said active material layer and that is smaller in thickness than the thick-layer portion, and is formed by discharging slurry containing an active material from a discharge port of a die head toward the surface of said current collector, the slurry being supplied to said die head through a coating valve, and
at the time of forming the thin-layer portion of said active material layer, a smaller amount of slurry, than at the amount applied when the thick-layer portion is formed, is discharged toward said current collector from the discharge port that is closer to said current collector than at the time of the formation of the thick-layer portion by changing an angle of said die head to said current collector.
8. The production method of the electrode for the secondary battery according to claim 7 , wherein said die head is provided so as to be able to be turned, and an interval between the discharge port and said current collector is increased by turning said die head in transitional time from the formation of the thin-layer portion to the formation of the thick-layer portion.
9. The production method of the electrode for the secondary battery according to claim 8 , wherein
in a state where said coating valve is closed and the slurry is not discharged from said die head, said coating valve is opened and the discharge of the slurry from said die head to said current collector is started, and
after a predetermined time has elapsed since the start of the opening of said coating valve, said die head starts to be turned.
10. The production method of the electrode for the secondary battery according to claim 9 , wherein the thin-layer portion is formed in a period after said coating valve starts to open and before said die head starts to be turned.
11. The production method of the electrode for the secondary battery according to claim 1 , wherein said coating valve is closed during formation of a non-application portion where said active material layer is not present on the surface of said current collector.
12. The production method of the electrode for the secondary battery according to claim 1 , wherein a length of a transition portion is 1 mm or less, the transition portion being positioned between the thin-layer portion and the thick-layer portion.