Silicon-based negative electrode active material and method for preparing the same
A negative electrode active material of the present invention includes a core containing silicon-based nanoparticles and polymer carbides distributed on the nanoparticles, wherein the core has a size of 30-300 nm, and such a negative electrode active material is prepared using a method including dispersing a suspension in which silicon-based nanoparticles and water-soluble polymer are added to a solvent using ultrasonic waves; and preparing a core including the silicon-based nanoparticles having the polymer carbides on the surface by carbonizing the water-soluble polymer. As a result, a negative electrode active material having a significantly low volume expansion rate compared with general non-carbon-based negative electrode active materials, and having excellent electric conductivity may be provided.
1. A negative electrode active material comprising:
silicon-based nanoparticles; and
a carbonized water-soluble polymer on the silicon-based nanoparticle,
wherein the silicon-based nanoparticle having the carbonized water-soluble polymer thereon has a diameter in the range of 30 nm to 800 nm,
wherein the carbonized water-soluble polymer is included in 3% by weight to 20% by weight with respect to a total weight of the silicon-based nanoparticles,
wherein the silicon-based nanoparticles include any one material selected from the group consisting of SiO, SiM and a combination thereof, and M includes any one selected from the group consisting of Ni, Co, B, Cr, Cu, Fe, Mn, Ti, Y and a combination thereof,
wherein the carbonized water-soluble polymer is prepared by carbonizing a water-soluble polymer having a weight average molecular weight of 90,000 to 2,000,000,
wherein the water-soluble polymer is carboxymethylcellulose (CMC).
2. The negative electrode active material of claim 1 , wherein the silicon-based nanoparticles include an oxidized film on the surface.
3. A method for preparing the negative electrode active material of claim 1 comprising:
dispersing a suspension in which the silicon-based nanoparticles and the water-soluble polymer are added to a solvent using ultrasonic waves; and
forming the carbonized water-soluble polymer on the surface of the silicon-based nanoparticles by carbonizing the water-soluble polymer.
4. The method of claim 3 , wherein the carbonization is carried out in a two-step process including a low-temperature carbonization process and a high-temperature carbonization process.
5. The method of claim 4 , wherein the low-temperature carbonization process is carried out using a spray drying apparatus, and includes injecting the suspension into a chamber inside a spray drying apparatus, and spray drying the suspension in the chamber.
6. The method of claim 5 , wherein the spray drying apparatus includes any one selected from the group consisting of an ultrasonic wave spray drying apparatus, an air nozzle spray drying apparatus, an ultrasonic wave nozzle spray drying apparatus, a filter expansion aerosol generator, an electrostatic spray drying apparatus and a combination thereof.
7. The method of claim 4 , wherein the low-temperature carbonization process is carried out at a temperature of 80° C. to 300° C.
8. The method of claim 4 , wherein the high-temperature carbonization process is heat treatment carried out at a temperature of 800° C. to 1100° C.
9. The method of claim 3 , wherein the solvent includes any one selected from the group consisting of water, acetone and a combination thereof.