Negative-electrode active material for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery
A negative-electrode active material for a non-aqueous electrolyte secondary battery containing a silicon material, wherein the negative-electrode active material can constitute a non-aqueous electrolyte secondary battery having high charge capacity, high initial charge/discharge efficiency, and good cycle characteristics. A negative-electrode active material particle according to an embodiment includes a lithium silicate phase represented by Li 2z SiO (2+z) {0<z<2} and particles dispersed in the lithium silicate phase. Each of the particles includes a silicon core particle and a surface layer formed of an iron alloy containing Si (FeSi alloy). In an XRD pattern of the negative-electrode active material particle obtained by XRD measurement, a diffraction peak of the FeSi alloy at 2θ=approximately 45 degrees has a half-width of 0.40 degrees or more, and a diffraction peak of a Si (111) plane at 2θ=approximately 28 degrees has a half-width of 0.40 degrees or more.
1. A negative-electrode active material for a non-aqueous electrolyte secondary battery, comprising:
a lithium silicate phase represented by Li 2z SiO (2+z) {0<z<2}; and
particles dispersed in the lithium silicate phase, the particles containing a silicon (Si) core particle and a surface layer formed of an iron alloy containing Si (FeSi alloy),
wherein in an XRD pattern obtained by XRD measurement, a diffraction peak of the FeSi alloy at 2θ=approximately 45 degrees has a half-width of 0.40 degrees or more, and a diffraction peak of a Si (111) plane at 2θ=approximately 28 degrees has a half-width of 0.40 degrees or more.
2. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein a diffraction peak of a (111) plane of a lithium silicate in the XRD pattern has a half-width of 0.05 degrees or more.
3. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 wherein the metal particles are composed mainly of Fe.
4. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the metal or alloy constituting the metal particles forms an alloy with at least one of Si and a lithium silicate.
5. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the metal particles constitute 0.01% to 20% by mass of a total mass of a base particle composed of the lithium silicate phase, the silicon particles, and the metal particles.
6. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein no SiO 2 peak is observed at 2θ=25 degrees in an XRD pattern obtained by XRD measurement.
7. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the metal particles have an average particle size of 100 nm or less.
8. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the silicon particles have an average particle size of 200 nm or less before initial charging.
9. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium silicate phase, the silicon particles, and the metal particles constitute a base particle, and the base particle is covered with an electrically conductive layer.
10. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium silicate phase is composed mainly of Li 2 SiO 3 .
11. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium silicate phase is composed mainly of Li 2 Si 2 O 5 .
12. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the negative-electrode active material for a non-aqueous electrolyte secondary battery after charging and discharging contains no Li 4 SiO 4 .
13. A non-aqueous electrolyte secondary battery comprising: a negative electrode containing the negative-electrode active material according to claim 1 ;
a positive electrode; and
a non-aqueous electrolyte.