Negative-electrode active material for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery
The initial charge/discharge efficiency and cycle characteristics of a non-aqueous electrolyte secondary battery that contains a silicon material as a negative-electrode active material are improved. A negative-electrode active material particle ( 10 ) according to an embodiment contains a base particle ( 13 ), which includes a lithium silicate phase ( 11 ) represented by Li 2z SiO (2+z) {0<z<2} and silicon particles ( 12 ) dispersed in the lithium silicate phase ( 11 ). The symmetry determined by an image analysis of a backscattered electron image of a cross section of the base particle ( 13 ) is 1.5 or less. The symmetry refers to the ratio (b/a) of the half width at half maximum b of a peak on the high-gray-scale side to the half width at half maximum a of the peak on the low-gray-scale side in a histogram of color distinction based on 256 gray levels for each pixel of the backscattered electron image.
1. A negative-electrode active material for a non-aqueous electrolyte secondary battery, comprising:
a base particle, which includes
a lithium silicate phase represented by Li 2z SiO (2+z) {0<z<2} including Li 2 Si 2 O 5 and
silicon particles dispersed in the lithium silicate phase,
wherein a symmetry determined by an image analysis of a backscattered electron image of a cross section of the base particle is 1.5 or less, and
the symmetry refers to a ratio (b/a) of a half width at half maximum b of a peak on a high-gray-scale side to a half width at half maximum a of the peak on a low-gray-scale side in a histogram of color distinction based on 256 gray levels for each pixel of the backscattered electron image,
wherein a half-width of a diffraction peak attributed to a (111) plane in an XRD pattern obtained by XRD measurement of the Li 2 Si 2 O 5 lithium silicate phase is in a range from 0.431° to 0.55°,
wherein the negative-electrode active material for a non-aqueous electrolyte secondary battery after charging and discharging contains no Li 4 SiO 4 .
2. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein a Si (111) plane has a higher diffraction peak intensity than a (111) plane of a lithium silicate in an XRD pattern obtained by XRD measurement.
3. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 2 , wherein no diffraction peak of SiO 2 is observed at 2θ=25 degrees in the XRD pattern.
4. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 3 , wherein the lithium silicate phase is composed mainly of Li 2 Si 2 O 5 .
5. A non-aqueous electrolyte secondary battery comprising: a negative electrode containing the negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 4 ; a positive electrode; and a non-aqueous electrolyte.
6. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 2 , wherein the lithium silicate phase is composed mainly of Li 2 Si 2 O 5 .
7. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein no diffraction peak of SiO 2 is observed at 2θ=25 degrees in a XRD pattern obtained by XRD measurement.
8. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 7 , wherein the lithium silicate phase is composed mainly of Li 2 Si 2 O 5 .
9. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium silicate phase is composed mainly of Li 2 Si 2 O 5 .
10. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein a diffraction peak of a (111) plane of a lithium silicate in an XRD pattern obtained by XRD measurement has a half-width of 0.05 degrees or more.
11. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium silicate phase is composed mainly of Li 2 SiO 3 , and a diffraction peak of a (111) plane of the Li 2 SiO 3 in a XRD pattern obtained by XRD measurement has a half-width of 0.10 degrees or more.
12. The negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium silicate phase and the silicon particles constitute a base particle, and the base particle is covered with an electrically conductive layer.
13. A non-aqueous electrolyte secondary battery comprising: a negative electrode containing the negative-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 ; a positive electrode; and a non-aqueous electrolyte.
14. A negative-electrode active material for a non-aqueous electrolyte secondary battery, comprising:
a lithium silicate phase represented by Li 2z SiO (2+z) {0<z<2} and
silicon particles dispersed in the lithium silicate phase,
wherein a symmetry determined by an image analysis of a backscattered electron image of a cross section of the base particle is 1.5 or less, and
the symmetry refers to a ratio (b/a) of a half width at half maximum b of a peak on a high-gray-scale side to a half width at half maximum a of the peak on a low-gray-scale side in a histogram of color distinction based on 256 gray levels for each pixel of the backscattered electron image,
wherein the negative-electrode active material for a non-aqueous electrolyte secondary battery after charging and discharging contains no Li 4 SiO 4 ,
wherein the lithium silicate phase contains Li 2 Si 2 O 5 at 80% or more by mass of the total mass of the lithium silicate phase.