IP Library Granted Patent US 10,113,102
Granted Patent B2
US 10,113,102 · App. 15/527,147 · Granted Oct 30, 2018

Activity enhanced scale dispersant for treating inorganic sulfide scales

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Quick Facts
Patent No.
US 10,113,102
App. No.
15/527,147
Granted
Oct 30, 2018
Kind
B2
Abstract

Processes and compositions to control inorganic sulfide scale formations in oilfield applications, including flow lines, wellbores, and subterranean formations. One example involves providing a treatment fluid comprising: a base fluid, a scale inhibitor, and a water clarifying agent; introducing the treatment fluid into a target region, wherein an inorganic cation and a sulfide anion are present in the target region; allowing the inorganic cation and the sulfide anion to form a sulfide precipitate; and using the treatment fluid to remove at least a portion of the sulfide precipitate from the target region.

Claims (30)

1. A method comprising:

providing a treatment fluid comprising:

a base fluid,

a scale inhibitor, wherein the scale inhibitor comprises a phosphonate, and

a water clarifying agent, wherein the water clarifying agent comprises at least one compound selected from the group consisting of: a polyDADMAC, a DADMAC acrylamide copolymer, and any combination thereof;

introducing the treatment fluid into a target region, wherein an inorganic cation and a sulfide anion are present in the target region;

allowing the inorganic cation and the sulfide anion to form a sulfide precipitate; and

using the treatment fluid to remove at least a portion of the sulfide precipitate from the target region.

2. The method of claim 1 wherein the inorganic cation is a metal cation.

3. The method of claim 2 wherein the metal cation comprises at least one metal cation selected from the group consisting of: iron, zinc, lead, and any combination thereof.

4. The method of claim 1 wherein the target region is a portion of a wellbore.

5. The method of claim 4 wherein the treatment fluid is a consolidation fluid, a drilling fluid, a fracturing fluid, a completion fluid, a workover fluid, a packer fluid, a spacer fluid, or any combination thereof.

6. The method of claim 4 wherein the treatment fluid is introduced into the portion of the wellbore in a continuous injection.

7. The method of claim 4 wherein the treatment fluid is introduced into the portion of the wellbore using a pump.

8. A method comprising:

providing a treatment fluid comprising a base fluid, a scale inhibitor comprising a phosphonate, and a water clarifying agent comprising least one compound selected from the group consisting of: a polyDADMAC, a DADMAC acrylamide copolymer, and any combination thereof;

introducing the treatment fluid into a portion of a wellbore, wherein an inorganic cation and a sulfide anion are present in the wellbore;

allowing the inorganic cation and the sulfide anion to form a sulfide precipitate; and

using the treatment fluid to remove at least a portion of the sulfide precipitate from the wellbore.

9. The method of claim 8 wherein the inorganic cation is a metal cation.

10. The method of claim 9 wherein the metal cation comprises at least one metal cation selected from the group consisting of: iron, zinc, lead, and any combination thereof.

11. The method of claim 8 wherein the treatment fluid is a consolidation fluid, a drilling fluid, a fracturing fluid, a completion fluid, a workover fluid, a packer fluid, a spacer fluid, or any combination thereof.

12. The method of claim 8 wherein the treatment fluid is introduced into the portion of the wellbore in a continuous injection.

13. The method of claim 8 wherein the treatment fluid is introduced into the portion of the wellbore using a pump.

14. A composition comprising:

a base fluid;

a scale inhibitor, wherein the scale inhibitor comprises a phosphonate;

a water clarifying agent, wherein the water clarifying agent comprises at least one compound selected from the group consisting of: a polyDADMAC, a DADMAC acrylamide copolymer, and any combination thereof; and

a sulfide precipitate.

15. The composition of claim 14 wherein the sulfide precipitate comprises at least one compound selected from the group consisting of: iron sulfide, zinc sulfide, lead sulfide, and any combination thereof.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2021
From: MULTI-CHEM GROUP, LLC
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 056681/0849 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 16, 2017
From: PENG, YANG; YUE, ZHIWEI; FAN, CHUNFANG; HAZLEWOOD, JOHNATHAN SCOTT
To: MULTI-CHEM GROUP, LLC
Reel/Frame 042393/0598 →
Cited By (2)
US 12,275,890 US 12,571,110