Optoelectronic semiconductor chip, method for producing an optoelectronic semiconductor chip, conversion element and phosphor for a conversion element
View Patent ↗An optoelectronic semiconductor chip having a semiconductor body ( 1 ) that is suitable for emitting electromagnetic radiation in a first wavelength range from a radiation exit face ( 3 ) is specified. Furthermore, the semiconductor chip comprises a ceramic or monocrystalline conversion platelet ( 6 ) that is suitable for converting electromagnetic radiation in the first wavelength range into electromagnetic radiation in a second wavelength range, which is different from the first wavelength range, and a wavelength-converting joining layer ( 7 ) that connects the conversion platelet ( 6 ) to the radiation exit face ( 3 ), wherein the wavelength-converting joining layer ( 7 ) has luminescent material particles ( 4 ) that are suitable for converting radiation in the first wavelength range into radiation in a third wavelength range, which is different from the first wavelength range and the second wavelength range. The wavelength-converting joining layer ( 7 ) furthermore has a thickness of no more than 30 micrometers. A method for fabricating an optoelectronic semiconductor chip, a further semiconductor chip, conversion element and luminescent material are specified.
1. An optoelectronic semiconductor chip comprising:
a semiconductor body suitable for emitting electromagnetic radiation in a first wavelength region from a radiation exit surface;
a ceramic or monocrystalline conversion plate suitable for converting electromagnetic radiation in the first wavelength region into electromagnetic radiation in a second wavelength region, which differs from the first wavelength region; and
a wavelength-converting joining layer that bonds the conversion plate to the radiation exit surface,
wherein the wavelength-converting joining layer comprises phosphor particles which are suitable for converting radiation in the first wavelength region into radiation in a third wavelength region, which differs from the first wavelength region and from the second wavelength region,
wherein the phosphor particles have the general chemical formula Sr x Ca 1-x AlSiN 3 :Eu, where 0.8<x<1, where between 0.1% and 5% of the Sr, Ca and/or Sr/Ca lattice sites are replaced by Eu, and where in X-ray crystallography, the phosphor exhibits in the orthorhombic description a reflex having the Miller index 1 2 1,
wherein the wavelength-converting joining layer has a thickness between at least 5 micrometers and at most 30 micrometers; and
wherein the concentration of the phosphor particles in the wavelength-converting joining layer is between 50 wt % and 70 wt %.
2. The optoelectronic semiconductor chip as claimed in the claim 1 , wherein the wavelength-converting joining layer has a maximum thickness of 10 micrometers.
3. The optoelectronic semiconductor chip as claimed in claim 1 , wherein the radiation in the first wavelength region is blue light, the radiation in the second wavelength region is green or green-yellow light, and the radiation in the third wavelength region is red light.
4. The optoelectronic semiconductor chip as claimed in claim 1 , wherein the phosphor particles are doped with europium as activator, where the concentration of the europium equals at least 1 mol %.
5. The optoelectronic semiconductor chip as claimed in claim 1 , wherein phosphor particles are doped with europium as activator, where the concentration of the europium equals at least 1 mol %, and
wherein and the wavelength-converting joining layer has a maximum thickness of 15 micrometers.
6. The optoelectronic semiconductor chip as claimed in claim 1 , which emits mixed-color radiation composed of radiation in the first, the second and the third wavelength region, wherein a color location of the mixed-color radiation lies in the warm-white region.
7. An optoelectronic semiconductor chip comprising:
a semiconductor body suitable for emitting electromagnetic radiation in a first wavelength region from a radiation exit surface;
a ceramic or monocrystalline conversion plate suitable for converting electromagnetic radiation in the first wavelength region into electromagnetic radiation in a second wavelength region, which differs from the first wavelength region; and
a wavelength-converting joining layer that bonds the conversion plate to the radiation exit surface,
wherein the wavelength-converting joining layer comprises phosphor particles which are suitable for converting radiation in the first wavelength region into radiation in a third wavelength region, which differs from the first wavelength region and from the second wavelength region,
wherein the wavelength-converting joining layer has a thickness between at least 5 micrometers and at most 30 micrometers, and
wherein the phosphor particles have the general chemical formula Sr x Ca 1-x AlSiN 3 :Eu, where 0.8<x<1, where between 0.1% and 5% of the Sr, Ca and/or Sr/Ca lattice sites are replaced by Eu, and where in X-ray crystallography, the phosphor exhibits in the orthorhombic description a reflex having the Miller index 1 2 1, where the concentration of the europium equals at least 1 mol %, and
wherein the concentration of the phosphor particles in the wavelength-converting joining layer is between 50 wt % and 70 wt %.
8. The optoelectronic semiconductor chip according to claim 1 , wherein the phosphor particles are doped with europium as activator, where the concentration of the europium is at least 3 mol %.
9. The optoelectronic semiconductor chip according to claim 7 , wherein the phosphor particles are doped with europium as activator, where the concentration of the europium is at least 3 mol %.